Using soft x-ray absorption spectroscopy and magnetic circular dichroism at
the Co-L2,3​ edge we reveal that the spin state transition in LaCoO3​
can be well described by a low-spin ground state and a triply-degenerate
high-spin first excited state. From the temperature dependence of the spectral
lineshapes we find that LaCoO3​ at finite temperatures is an inhomogeneous
mixed-spin-state system. Crucial is that the magnetic circular dichroism signal
in the paramagnetic state carries a large orbital momentum. This directly shows
that the currently accepted low-/intermediate-spin picture is at variance.
Parameters derived from these spectroscopies fully explain existing magnetic
susceptibility, electron spin resonance and inelastic neutron data