Stabilizing the forming process in unipolar resistance switching using an improved compliance current limiter

The high reset current IR in unipolar resistance switching now poses major obstacles to practical applications in memory devices. In particular, the first IR-value after the forming process is so high that the capacitors sometimes do not exhibit reliable unipolar resistance switching. We found that the compliance current Icomp is a critical parameter for reducing IR-values. We therefore introduced an improved, simple, easy to use Icomp-limiter that stabilizes the forming process by drastically decreasing current overflow, in order to precisely control the Icomp- and subsequent IR-values.Comment: 15 pages, 4 figure

A Markov Chain Monte Carlo Algorithm for analysis of low signal-to-noise CMB data

We present a new Monte Carlo Markov Chain algorithm for CMB analysis in the low signal-to-noise regime. This method builds on and complements the previously described CMB Gibbs sampler, and effectively solves the low signal-to-noise inefficiency problem of the direct Gibbs sampler. The new algorithm is a simple Metropolis-Hastings sampler with a general proposal rule for the power spectrum, C_l, followed by a particular deterministic rescaling operation of the sky signal. The acceptance probability for this joint move depends on the sky map only through the difference of chi-squared between the original and proposed sky sample, which is close to unity in the low signal-to-noise regime. The algorithm is completed by alternating this move with a standard Gibbs move. Together, these two proposals constitute a computationally efficient algorithm for mapping out the full joint CMB posterior, both in the high and low signal-to-noise regimes.Comment: Submitted to Ap

A critical reflection on the use of focus groups as a research method: lessons from trying to hear the voices of NGO beneficiaries in Ghana

The focus group method has been used extensively in social science research in order to gain a deep understanding of participant perceptions of specific topics of interest. However, the method has rarely been used in the social accounting and accountability literature. This paper reviews and critically reflects on the key characteristics of the method drawing on a research project examining NGO (non-governmental organisation) beneficiary perspectives on the accountability processes employed by NGOs in Ghana. It offers insights and future research suggestions that might encourage greater use of the method by social accounting and accountability researchers

The nature of alkanethiol self-assembled monolayer adsorption on sputtered gold substrates

A detailed study of the self-assembly and coverage by 1-nonanethiol of sputtered Au surfaces using molecular resolution atomic force microscopy (AFM) and scanning tunneling microscopy (STM) is presented. The monolayer self-assembles on a smooth Au surface composed predominantly of {111} oriented grains. The domains of the alkanethiol monolayer are observed with sizes typically of 5-25 nm, and multiple molecular domains can exist within one Au grain. STM imaging shows that the (4 × 2) superlattice structure is observed as a (3 × 2√3) structure when imaged under noncontact AFM conditions. The 1-nonanethiol molecules reside in the threefold hollow sites of the Au{111} lattice and aligned along its lattice vectors. The self-assembled monolayer (SAM) contains many nonuniformities such as pinholes, domain boundaries, and monatomic depressions which are present in the Au surface prior to SAM adsorption. The detailed observations demonstrate limitations to the application of 1-nonanethiol as a resist in atomic nanolithography experiments to feature sizes of ∼20 nm

Non-Perturbative Tachyon Potential from the Wilsonian Renormalization Group

The derivative expansion of the Wilsonian renormalization group generates additional terms in the effective beta-functions not present in the perturbative approach. Applied to the nonlinear sigma model, to lowest order the vanishing of the beta-function for the tachyon field generates an equation analogous to that found in open string field theory. Although the nonlinear term depends on the cut-off function, this arbitrariness can be removed by a rescaling of the tachyon field.Comment: 6 pages, further references adde

Bayesian analysis of the low-resolution polarized 3-year WMAP sky maps

We apply a previously developed Gibbs sampling framework to the foreground corrected 3-yr WMAP polarization data and compute the power spectrum and residual foreground template amplitude posterior distributions. We first analyze the co-added Q- and V-band data, and compare our results to the likelihood code published by the WMAP team. We find good agreement, and thus verify the numerics and data processing steps of both approaches. However, we also analyze the Q- and V-bands separately, allowing for non-zero EB cross-correlations and including two individual foreground template amplitudes tracing synchrotron and dust emission. In these analyses, we find tentative evidence of systematics: The foreground tracers correlate with each of the Q- and V-band sky maps individually, although not with the co-added QV map; there is a noticeable negative EB cross-correlation at l <~ 16 in the V-band map; and finally, when relaxing the constraints on EB and BB, noticeable differences are observed between the marginalized band powers in the Q- and V-bands. Further studies of these features are imperative, given the importance of the low-l EE spectrum on the optical depth of reionization tau and the spectral index of scalar perturbations n_s.Comment: 5 pages, 4 figures, submitted to ApJ

Formation of nanoporous InP by electrochemical anodization

Porous InP layers can be formed electrochemically on (100) oriented n- InP substrates in aqueous KOH. A nanoporous layer is obtained underneath a dense near-surface layer and the pores appear to propagate from holes through the near-surface layer. In the early stages of the anodization transmission electron microscopy (TEM) clearly shows individual porous domains which appear to have a square-based pyramidal shape. Each domain appears to develop from an individual surface pit which forms a channel through this near-surface layer. We suggest that the pyramidal structure arises as a result of preferential pore propagation along the directions. AFM measurements show that the density of surface pits increases with time. Each of these pits acts as a source for a pyramidal porous domain. When the domains grow, the current density increases correspondingly. Eventually, the domains meet forming a continuous porous layer, the interface between the porous and bulk InP becomes relatively flat and its total effective surface area decreases resulting in a decrease in the current density. Numerical models of this process have been developed. Current-time curves at constant potential exhibit a peak and porous layers are observed to form beneath the electrode surface. The density of pits formed on the surface increases with time and approaches a plateau value

Observation of HCN hyperfine line anomalies towards low- and high-mass star-forming cores

HCN is becoming a popular choice of molecule for studying star formation in both low- and high-mass regions and for other astrophysical sources from comets to high-redshift galaxies. However, a major and often overlooked difficulty with HCN is that it can exhibit non-local thermodynamic equilibrium (non-LTE) behaviour in its hyperfine line structure. Individual hyperfine lines can be strongly boosted or suppressed. In low-mass star-forming cloud observations, this could possibly lead to large errors in the calculation of opacity and excitation temperature, while in massive star-forming clouds, where the hyperfine lines are blended due to turbulent broadening, errors will arise in infall measurements that are based on the separation of the peaks in a self-absorbed profile. The underlying line shape cannot be known for certain if hyperfine anomalies are present. We present a first observational investigation of these anomalies across a range of conditions and transitions by carrying out a survey of low-mass starless cores (in Taurus & Ophiuchus) and high-mass protostellar objects (in the G333 giant molecular cloud) using hydrogen cyanide (HCN) J=1-0 and J=3-2 emission lines. We quantify the degree of anomaly in these two rotational levels by considering ratios of individual hyperfine lines compared to LTE values. We find that all the cores observed show some degree of anomaly while many of the lines are severely anomalous. We conclude that HCN hyperfine anomalies are common in both lines in both low-mass and high-mass protostellar objects, and we discuss the differing hypotheses for the generation of the anomalies. In light of the results, we favour a line overlap effect for the origins of the anomalies. We discuss the implications for the use of HCN as a dynamical tracer and suggest in particular that the J=1-0, F=0-1 hyperfine line should be avoided in quantitative calculations.Comment: 17 pages, 8 figure

Pitting and porous layer formation on n-InP anodes

Surface pitting occurs when InP electrodes are anodized in KOH electrolytes at concentrations in the range 2 - 5 mol dm-3. The process has been investigated using atomic force microscopy (AFM) and the results correlated with cross-sectional transmission electron microscopy (TEM) and electroanalytical measurements. AFM measurements show that pitting of the surface occurs and the density of pits is observed to increase with time under both potentiodynamic and potentiostatic conditions. This indicates a progressive pit nucleation process and implies that the development of porous domains beneath the surface is also progressive in nature. Evidence for this is seen in plan view TEM images in which individual domains are seen to be at different stages of development. Analysis of the cyclic voltammograms of InP electrodes in 5 mol dm-3 KOH indicates that, above a critical potential for pit formation, the anodic current is predominantly time dependent and there is little differential dependence of the current on potential. Thus, pores continue to grow with time when the potential is high enough to maintain depletion layer breakdown conditions

A mechanistic study of anodic formation of porous InP

When porous InP is anodically formed in KOH electrolytes, a thin layer ~40 nm in thickness, close to the surface, appears to be unmodified. We have investigated the earlier stages of the anodic formation of porous InP in 5 mol dm-3 KOH. TEM clearly shows individual porous domains which appear triangular in cross-section and square in plan view. The crosssections also show that the domains are separated from the surface by a ~40 nm thick, dense InP layer. It is concluded that the porous domains have a square-based pyramidal shape and that each one develops from an individual surface pit which forms a channel through this near-surface layer. We suggest that the pyramidal structure arises as a result of preferential pore propagation along the directions. AFM measurements show that the density of surface pits increases with time. Each of these pits acts as a source for a pyramidal porous domain, and these domains eventually form a continuous porous layer. This implies that the development of porous domains beneath the surface is also progressive in nature. Evidence for this was seen in plan view TEM images. Merging of domains continues to occur at potentials more anodic than the peak potential, where the current is observed to decrease. When the domains grow, the current density increases correspondingly. Eventually, domains meet, the interface between the porous and bulk InP becomes relatively flat and its total effective surface area decreases resulting in a decrease in the current density. Quantitative models of this process are being developed