2,015 research outputs found
4-(Methylsulfonyl)piperazin-1-ium chloride
In the title molecular salt, C5H13N2O2S+·Cl−, the complete cation is generated by crystallographic mirror symmetry, with both N atoms, the S atom and one C atom lying on the reflecting plane. The chloride ion also lies on the mirror plane. The piperazinium ring adopts a chair conformation and the N—S bond adopts an equatorial orientation. In the crystal structure, the component ions are linked into a three-dimensional framework by intermolecular N—H⋯Cl and C—H⋯Cl hydrogen bonds
Heat conductivity of the spin-Peierls compounds TiOCl and TiOBr
We report experimental results on the heat conductivity \kappa of the S=1/2
spin chain compounds TiOBr and TiOCl for temperatures 5K<T<300K and magnetic
fields up to 14. Surprisingly, we find no evidence of a significant magnetic
contribution to \kappa, which is in stark contrast to recent results on S=1/2
spin chain cuprates. Despite this unexpected result, the thus predominantly
phononic heat conductivity of these spin-Peierls compounds exhibits a very
unusual behavior. In particular, we observe strong anomalies at the phase
transitions Tc1 and Tc2. Moreover, we find an overall but anisotropic
suppression of \kappa in the intermediate phase which extends even to
temperatures higher than Tc2. An external magnetic field causes a slight
downshift of the transition at Tc1 and enhances the suppression of \kappa up to
Tc2. We interprete our findings in terms of strong spin-phonon coupling and
phonon scattering arising from spin-driven lattice distortions.Comment: 6 pages, 3 figure
Adsorption in non interconnected pores open at one or at both ends: A reconsideration of the origin of the hysteresis phenomenon
We report on an experimental study of adsorption isotherme of nitrogen onto
porous silicon with non interconnected pores open at one or at both ends in
order to check for the first time the old (1938) but always current idea based
on Cohan's description which suggests that the adsorption of gaz should occur
reversibly in the first case and irreversibly in the second one. Hysteresis
loops, the shape of which is usually associated to interconnections in porous
media, are observed whether the pores are open at one or at both ends in
contradiction with Cohan's model.Comment: 5 pages, 4 EPS figure
HST PanCET program: A Cloudy Atmosphere for the promising JWST target WASP-101b
We present results from the first observations of the Hubble Space Telescope
(HST) Panchromatic Comparative Exoplanet Treasury (PanCET) program for
WASP-101b, a highly inflated hot Jupiter and one of the community targets
proposed for the James Webb Space Telescope (JWST) Early Release Science (ERS)
program. From a single HST Wide Field Camera 3 (WFC3) observation, we find that
the near-infrared transmission spectrum of WASP-101b contains no significant
HO absorption features and we rule out a clear atmosphere at 13{\sigma}.
Therefore, WASP-101b is not an optimum target for a JWST ERS program aimed at
observing strong molecular transmission features. We compare WASP-101b to the
well studied and nearly identical hot Jupiter WASP-31b. These twin planets show
similar temperature-pressure profiles and atmospheric features in the
near-infrared. We suggest exoplanets in the same parameter space as WASP-101b
and WASP-31b will also exhibit cloudy transmission spectral features. For
future HST exoplanet studies, our analysis also suggests that a lower count
limit needs to be exceeded per pixel on the detector in order to avoid unwanted
instrumental systematics.Comment: 7 pages, 4 figures, 1 table, Accepted to ApJ
The use of measured genotype information in the analysis of quantitative phenotypes in man.
We have begun a measured genotype approach to the genetic analysis of lipid and lipoprotein variability. This approach enables one to simultaneously estimate the frequencies and effects of alleles at specific loci along with the residual polygenetic variance component. In this study we consider the contribution of three common alleles at the locus coding for apolipoprotein E to interindividual variation of total cholesterol, betalipoprotein, and triglyceride levels. A sample of 102 nuclear families consisting of 434 individuals was studied. The frequencies of the ε2, ε3, and ε4 alleles in this sample are 0·137,0·740, and 0·123, respectively. In separate analyses of cholesterol and betalipoprotein levels, a complete model that includes the effects of the six apo E genotypes, unmeasured polygenes, and individual specific environmental effects fits these data significantly better than a reduced model that does not include the effects of the apo E polymorphism or a reduced model that does not include the effects of polygenes. On the average the ε2 allele lowers total cholesterol and betalipoprotein levels by 0·425 mmol/l and 0·811 units, respectively. The ε4 allele is associated with an average increase of these phenotypes by 0·255 mmol/l and 0·628 units, respectively. Simultaneous estimates of the interindividual variability of total cholesterol levels attributable to the apo E polymorphism and to residual polygenic effects are 8% and 56%, respectively. For betalipoprotein levels, we simultaneously estimate these values to be 7% and 42%, respectively. A reduced model including the effects of polygenes but not the effects of the apo E polymorphism fitted the triglyceride data as well as the complete model. The estimate of the fraction of interindividual variability associated with polygenetic effects was 26.5%. We review our present understanding of the genetic architecture underlying variability of cholesterol levels in the population at large and infer that the majority of the genetic variability may be accounted for by polymorphic gene loci with moderate effects on cholesterol levels.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/65212/1/j.1469-1809.1987.tb00874.x.pd
Protein Encapsulation Using Complex Coacervates: What Nature Has to Teach Us
Protein encapsulation is a growing area of interest, particularly in the fields of food science and medicine. The sequestration of protein cargoes is achieved using a variety of methods, each with benefits and drawbacks. One of the most significant challenges associated with protein encapsulation is achieving high loading while maintaining protein viability. This difficulty is exacerbated because many encapsulant systems require the use of organic solvents. By contrast, nature has optimized strategies to compartmentalize and protect proteins inside the cell—a purely aqueous environment. Although the mechanisms whereby aspects of the cytosol is able to stabilize proteins are unknown, the crowded nature of many newly discovered, liquid phase separated “membraneless organelles” that achieve protein compartmentalization suggests that the material environment surrounding the protein may be critical in determining stability. Here, encapsulation strategies based on liquid–liquid phase separation, and complex coacervation in particular, which has many of the key features of the cytoplasm as a material, are reviewed. The literature on protein encapsulation via coacervation is also reviewed and the parameters relevant to creating protein‐containing coacervate formulations are discussed. Additionally, potential opportunities associated with the creation of tailored materials to better facilitate protein encapsulation and stabilization are highlighted
Possible detection of phase changes from the non-transiting planet HD 46375b by CoRoT
The present work deals with the detection of phase changes in an exoplanetary
system. HD 46375 is a solar analog known to host a non-transiting Saturn-mass
exoplanet with a 3.0236 day period. It was observed by the CoRoT satellite for
34 days during the fall of 2008. We attempt to identify at optical wavelengths,
the changing phases of the planet as it orbits its star. We then try to improve
the star model by means of a seismic analysis of the same light curve and the
use of ground-based spectropolarimetric observations. The data analysis relies
on the Fourier spectrum and the folding of the time series. We find evidence of
a sinusoidal signal compatible in terms of both amplitude and phase with light
reflected by the planet. Its relative amplitude is Delta Fp/F* = [13.0, 26.8]
ppm, implying an albedo A=[0.16, 0.33] or a dayside visible brightness
temperature Tb ~ [1880,2030] K by assuming a radius R=1.1 R_Jup and an
inclination i=45 deg. Its orbital phase differs from that of the
radial-velocity signal by at most 2 sigma_RV. However, the tiny planetary
signal is strongly blended by another signal, which we attribute to a telluric
signal with a 1 day period. We show that this signal is suppressed, but not
eliminated, when using the time series for HD 46179 from the same CoRoT run as
a reference. This detection of reflected light from a non-transiting planet
should be confirmable with a longer CoRoT observation of the same field. In any
case, it demonstrates that non-transiting planets can be characterized using
ultra-precise photometric lightcurves with present-day observations by CoRoT
and Kepler. The combined detection of solar-type oscillations on the same
targets (Gaulme et al. 2010a) highlights the overlap between exoplanetary
science and asteroseismology and shows the high potential of a mission such as
Plato.Comment: 4 pages, 6 figure
Cluster Dynamical Mean-field calculations for TiOCl
Based on a combination of cluster dynamical mean field theory (DMFT) and
density functional calculations, we calculated the angle-integrated spectral
density in the layered quantum magnet TiOCl. The agreement with recent
photoemission and oxygen K-edge X-ray absorption spectroscopy experiments is
found to be good. Th e improvement achieved with this calculation with respect
to previous single-site DMFT calculations is an indication of the correlated
nature and low-dimensionality of TiOCl.Comment: 9 pages, 3 figures, improved version as publishe
Manipulating the Tomonaga-Luttinger exponent by electric field modulation
We establish a theoretical framework for artificial control of the power-law
singularities in Tomonaga-Luttinger liquid states. The exponent governing the
power-law behaviors is found to increase significantly with an increase in the
amplitude of the periodic electric field modulation applied externally to the
system. This field-induced shift in the exponent indicates the tunability of
the transport properties of quasi-one-dimensional electron systems.Comment: 7 pages, 3 figure
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