Improving the recovery of monthly regional water storage using one year simulated observations of two pairs of GRACE-type satellite gravimetry constellation

Increasing the spatial sampling isotropy is a major issue in designing future missions dedicated to continue the task of the Gravity Recovery And Climate Experiment (GRACE) mission. From various possible future satellite gravimetry scenarios, the two-pair multi-orbit satellite configuration (Bender-type in the sequence), consisting of a coupled semi-polar pair (the same as GRACE) and an inclined pair of satellites seems to be an optimal mission choice. This contribution examines the performance of a Bender-type scenario at altitudes of 335 km and 352 km and inclinations of 89° and 63°, respectively, for improving the regional recovery of hydrological signals. To this end, we created one full year of simulated observations of the GRACE and Bender-type configurations. Our investigations include: 1) evaluating the feasible spatial resolution for the recovery of terrestrial water storage (TWS) changes in the presence of realistic instrumental noise and errors in the background models; 2) assessing the influence of aliasing errors in the TWS recovery and its separation from instrumental noise and introduced hydrological signals; and 3) analyzing the regional quality of the gravity-derived TWS results by assessing water storage changes over the 33 world major river basins. From our simulations, the Bender-derived spectral error curves indicate that, in spite of the instrumental noise, aliasing errors still contaminate the gravity fields above geopotential spherical harmonic coefficient (SHC) degree and order (d/o) 80 till 100. Regarding to the TWS recovery, we found notable improvements for the Bender-type configuration results in medium and small-scale basins, such as the Brahmaputra, Euphrates, Ganges, Indus, Mekong basins in Asia and the Yellow and Orange basins in South Africa. These results were achieved without applying post-processing, which was unachievable using simulations of one pair of GRACE-like configuration. Comparing the magnitudes of errors in the Bender-derived solutions with those of GRACE indicate that the accuracy derived from the Bender-type fields is about two times better than that of GRACE, specifically at medium spatial resolutions of 250 km (SHC d/o 80). We truncated the TWS recovery up to SHC d/o 80 in the spectral domain, whereas all comparisons are demonstrated in the spatial domain after a truncation of the solutions and WGHM field at d/o 60, since beyond this range; a relatively strong instrumental and aliasing errors contaminate the solutions. Our numerical results indicate that the spatial resolution of the Bender-type TWS recovery can be even higher for the basins with strong temporal water storage variations such as the Amazon basin. Short wavelength mass variations in basins with relatively weaker temporal TWS magnitude, such as the Murray basin, might still need the application of a filter with small averaging kernel

Class Balanced Similarity-Based Instance Transfer Learning for Botnet Family Classification

The use of Transfer Learning algorithms for enhancing the performance of machine learning algorithms has gained attention over the last decade. In this paper we introduce an extension and evaluation of our novel approach Similarity Based Instance Transfer Learning (SBIT). The extended version is denoted Class Balanced SBIT (or CB-SBIT for short) because it ensures the dataset resulting after instance transfer does not contain class imbalance. We compare the performance of CB-SBIT against the original SBIT algorithm. In addition, we compare its performance against that of the classical Synthetic Minority Over-sampling Technique (SMOTE) using network tra ffic data. We also compare the performance of CB-SBIT against the performance of the open source transfer learning algorithm TransferBoost using text data. Our results show that CB-SBIT outperforms the original SBIT and SMOTE using varying sizes of network tra ffic data but falls short when compared to TransferBoost using text data

PLC Virtualization and Software Defined Architectures in Industrial Control Systems

Today’s automation systems are going through a transition called Industry 4.0, referring to the Fourth Industrial Revolution. New concepts, such as cyber-physical systems, mi-croservices and Smart Factory are introduced. This brings up the question of how some of these new technologies can be utilized in Industrial Control Systems. Machines and production lines are nowadays controlled by hardware PLCs and this is considered as a state-of-the-art solution. However, the market demands are continuously increasing and pushing the industry e.g. to lower the operational costs and to develop more agile solutions. Industry 4.0 provides promising approaches to take a step forward and consider PLC virtualization. The purpose of this thesis was to evaluate PLC virtualization possibilities using different Software Defined Architectures. Requirements and benefits of different solutions were evaluated. The major objective of the case study was to compare container- and hypervisor-based virtualization solutions using Docker and KVM. The case study provides a modular and scalable IIoT solution in which a virtual PLC takes over the control instead of a hardware PLC. Node-RED was used as a runtime environment and an I/O-module was needed to set up a control loop test. Response time of the control loop was measured by capturing Modbus traffic with tcpdump. Multiple iterations were performed to show minimum, maximum, average, median and 90th pctl. latencies. The results indicate that the container-based solution has a smaller overhead than the hypervisor-based solution and it has a very little overhead in general. Peak latencies are a concern and even the average latencies show that this solution would not be suitable for any hard real-time or safety-related applications. Further investigation on the topic would be needed to estimate the actual potential of PLC virtualization on hard real-time applications. First of all, a more powerful hardware PC would be needed to perform such tests. Secondly, a faster industrial protocol than Modbus TCP/IP would be required. Perhaps another kind of approach would be needed to overcome the issues that were experienced in this case study. It would be interesting to test a direct communication between virtual PLC and I/O and use Node-RED nodes for example to trigger inputs. Anyhow, it seems that container-based solution is holding much promise as a virtualization approach

Mechanical behavior of asphalt mixtures containing silica gels as warm additives

This paper presents the results of a study of some compounds capable of absorbing water into their structure (silica gel), as potential foaming binders. Asphalt mixtures were manufactured at different manufacturing and compaction temperatures, using four different silica gels. Static and dynamic tests were carried out to determine their behavior in asphalt mixtures. The results were compared with those obtained using hot-mix asphalt and warm-mix asphalt manufactured with zeolite. The lab results showed a similar behavior of asphalt mixtures containing either silica gel or zeolite.The research presented herein was sponsored by the Research Office of Universidad de La Frontera (DIUFRO) under the project number DI15-0089

Anticholinesterase and Antioxidant Activities of Spilanthes filicaulis Whole Plant Extracts for the Management of Alzheimer’s Disease

Background: Spilanthes filicaulis is a tropical herb implicated as a memory enhancer in ethnomedicine. Objective: The study investigated acetyl/butyryl cholinesterase inhibitory and antioxidant activities of different extracts of S. filicaulis whole plant and correlated them to its phytochemical constituents. Methods: The powdered whole plant was successively extracted with n-hexane, ethyl acetate and methanol. Acetyl cholinesterase (AChE) and Butyryl cholinesterase (BuChE) inhibitory activity were evaluated by Ellman colorimetry assay. Antioxidant activity was tested using 1, 1-diphenyl-2-picrylhydrazyl (DPPH) radical scavenging, ferric reducing power and nitric oxide scavenging assays. Total phenolic, flavonoid and tannin were estimated using standard methods. Correlation was determined using Quest Graph™ Regression Calculator. Results: Various extracts exhibited concentration-dependent AChE and BuChE inhibitory activity with ethyl acetate extract being the highest with IC50 of 0.77 μg/mL and 0.92 μg/mL for AChE and BuChE respectively. The ethyl acetate extract also showed the highest reducing power when compared with the other extracts. The methanol extract had slightly higher phenolic and flavonoid content and showed the highest DPPH radical scavenging effect. DPPH scavenging, AChE and BuChE inhibition had high correlation with the total flavonoid content with R2 values of 1.00, 0.800 and 0.992 respectively while nitric oxide scavenging had high correlation with phenolics and tannins with R2 = 0.942 and 0.806 respectively. Conclusion: These results show that the extracts of the whole plant of S. filicaulis possess significant AChE/BuChE inhibitory and antioxidant properties, mostly due to its flavonoid content, suggesting the possible use of the plant in neurodegenerative diseases such as AD

Physicochemical, structural and combustion analyses to estimate the solid fuel efficacy of hydrochar developed by co-hydrothermal carbonization of food and municipal wastes

The application of a char derived from fruit peel waste and other municipal wastes as solid fuel depends on its physico-chemical properties. In this work, fruit peel waste (FW) along their mixture with facial tissue waste (FT) and wrapping paper waste (WP) as well as their respective hydrochars (FWHC, FTHC, and WPHC) produced via hydrothermal carbonization (HTC) was characterized in detail to ascertain their applicability as solid fuel. Moreover, the elemental O contents for FTHC and WPHC were about 12.8 and 5.1% respectively higher than FWHC. Heating value analysis indicated that WPHC had the highest HHV of 5164 kcal/kg. Combustion kinetic studies, carried out by thermogravimetric technique, revealed that about 33.78 kJ/mol of energy was required to generate a combustion reaction for WP, higher than the energy required to ignite WPHC (28.2 kJ/mol). The regression coefficient (R2) values were higher than 0.94, indicating that the Arrhenius equation could be used to model the sample combustion process. Overall, the study showed that Co-HTC of FW with paper-based municipal waste such FT and WP is an effective method of converting FW to a cleaner hydrochar (HC) with high calorific value and less sulphur content. Graphical abstract: [Figure not available: see fulltext.].This research was funded by National Plan for Science, Technology and Innovation (MAARIFAH), King Abdulaziz City for Science and Technology and Kingdom of Saudi Arabia, Award Number 14-ENV665-02

Towards understanding the magnetism of Os(iv) complexes: an ab initio insight

10.1039/d1dt01558cDALTON TRANSACTIONS503612537-1254