Hydrous Carbonatitic Liquids Drive CO2 Recycling From Subducted Marls and Limestones

This research was supported by the Italian Ministry of Education, University, and Research (MIUR) program PRIN2017 and by the Deep Carbon Observatory (DCO). We are greatly indebted to Andrea Risplendente for careful examination of run charges at the Electron Microprobe.Pelagic limestones are subducted in a variety of subduction zones worldwide. Despite the geochemical relevance of systems enriched in CaCO3, previous experimental investigations mostly focused on carbonated pelites, with low Ca/(Ca+Mg+Fe) ratio. We present the compositions and the formation conditions of liquids in the model system CaO‐Al2O3‐SiO2‐H2O‐CO2 (CASHC), building on phase relationships in the subsystems CHC and CSHC, where a second critical endpoint was suggested at temperatures as low as 515 °C, and 3.2 GPa. Multianvil experiments were performed at 4.2 and 6.0 GPa on five bulk compositions at variable Ca/Si/Al ratios. H2O contents vary from 5.6 to 21 wt%. Aragonite + kyanite + vapor and minor lawsonite form at 700 °C, replaced by zoisite/grossular at 800 °C. Between 850 °C and 950 °C, a complex sequence of textural features is observed upon quenching of a single volatile‐rich liquid phase formed at run conditions. Precipitates include dendritic CaCO3, silicate glass, and Al‐rich whiskers. The bulk composition of such hydrous carbonatitic liquids is retrieved by image analysis on X‐ray maps, showing Ca/Si ratio increasing with pressure and temperature. Hydrous Ca‐carbonatitic liquids are efficient media for scavenging volatiles from subducted crustal material and for metasomatizing the mantle wedge.Ministry of Education, Universities and Research (MIUR)Deep Carbon Observatory (DCO

Subduction and Tectonics. Discussion on the Results of the IPOD Program in Active Margins

Since the advent of plate tectonics the active margins of the oceans have been studied according to a model whose basis is a piling up of imbrications of oceanic material units, in front of the upper plate, forming a great tectonic accretionary prism. This model is broadly the same for all the authors; it has been largely used for alpine-type or paleo-oceanic mountain chain, all around the world. The authors have directly taken part in the drillings on western and eastern Pacific active margins (Legs 60 and 67) and they have worked on the tectonics of alpine (paleo-oceanic) chains of the peri-mediterranean, peri-caribbean, and peripacific belts. They compare the geological data acumulated from these tow direct sources. The tectonic constraints constraints regime is specified and the consequences of the subduction are looked for. The notions of collison and obduction are discussed in relation to subduction and tectonics. Finally, an anlaysis of the temporal evolution of active margins and of chains, shows the necessity of thinking in terms of superimposed tectonics