Late Quaternary micropalaeontological record of a semi-enclosed marine basin, North Evoikos, central Aegean Sea

North Evoikos Gulf constitutes a deep (450 m) semi-enclosed basin in east-central Greece connected to the Aegean Sea via a 42-m sill to the north and a 40-m wide, 8-m deep channel to the south. Six gravity cores retrieved from different physiographic settings of the Gulf were analyzed for their benthic foraminiferal content, in order to reconstruct the local and regional palaeoenvironmental changes. Species Correspondence Analysis separates the foraminifera into 4 clusters: Cluster 1 is composed of Agglutinated species, Elphidium spp. and Ammonia beccarii; Cluster 2 is exclusively composed of Bulimina marginata; Cluster 3 consists of Bolivina spathulata and Bulimina costata and finally Cluster 4 comprises the 10 remaining species: Cibicides lobatulus, Cibicidoides pachyderma, Bulimina aculeata, Cancris oblonga, Melonis barleeanum, Chilostomella oolina, Cassidulina laevigata, Hyalinea balthica and Miliolidae. These clusters represent four distinct foraminiferal biofacies and are interpreted as reflecting different ecological conditions: Biofacies p-H corresponds to the proximal part of the shelf and it is characterised by the absence of foraminifera, skeletal debris and abundant peloids. Its topmost part shows an erosional surface, aged 32.4 ka, characterised by shell debris, and the appearance of few shallow marine benthic foraminifera. Biofacies Ia and Ib consist of a low-diversity Holocene assemblage which is mainly dominated by Textularia spp. and Elphidium spp., reflecting a low-energy restricted lagoon and the deeper water assemblage of B. marginata and H. balthica (Biofacies Ib) as well as by a mollusc assemblage dominated by Corbula gibba. These biofacies are only present in the mid-shelf setting. Biofacies II (Cluster 3: B. spathulataeB. costata) shows a possible positive correlation with nutrient contents and it exhibits a complementary pattern of distribution with Biofacies III (Cluster 4: B. marginata). Two main palaeoenvironmental settings were recognized: a) In the first setting dominated by Biofacies Ia and Ib, the succession of the benthic faunas is mainly controlled by the ongoing sea level rise; b) in the second setting, the species typical of shelf environment (C. laevigataeH. balthica) give way to opportunistic species (B. spathulata) and species that are more resistant to bottom water changes (B. marginata). This pattern is attributed to variations in the food chain and oxygenation. North Evoikos Gulf during the Uppermost Quaternary reflects a passive response to a globally fluctuating sea level that was not significantly modified by dramatic tectonic processes. Therefore, its palaeoceanographic evolution is primarily driven by climatic (eustatic) processes and accurately depicts local conditions

Multiphase Diagenetic Processes and Their Impact on Reservoir Character of the Late Triassic (Rhaetian) Kingriali Formation, Upper Indus Basin, Pakistan

Multiple episodes of dolomitization of the shallow marine carbonates of the Late Kingriali Formation resulted in regional scale mappable dolostone geobodies in the Kohat and Potwar sub-basins. With the exception of few unaltered patches of the host limestone, more than 90% of the carbonates of the studied formation are diagenetically altered by replacive dolomites with associated dolomite cementation. Petrographical and geochemical data interpretation reveals that during the initial stage of dolomitization, the precursor limestone was significantly modified by the fabric-retentive replacive dolomite (RD-I) and produced bulk dolostones with non-planar-a to planar-s crystals. Neomorphic recrystallization (RD-II) was observed as an overgrowth of the already formed RD-I dolomite crystals during progressive dolomitization. The seawater at shallow depths is enriched with Fe-ions due to its interaction with Fe-rich beds within the studied formation. The modified seawater actively participated in the formation of ferroan replacive dolomites (RD-III). Stable isotopic composition of the unaltered Echinoderm plates, calcite cement (CC-I), and RD-I demonstrates signatures of δ18O and δ13C within the limit of late Triassic marine seawater or modified seawater. Depletion in the stable oxygen isotopic composition (from −0.99‰ to −3.75‰ V-PDB) demonstrates that RD-II and RD-III were formed in a sequence with progressively higher temperature fluids than normal seawater. Precipitation of dolomite cements as cavity filling rhombs (DC-I) and crystal overgrowth (DC-II) with highly depleted δ18O values (−5.44‰ to −7.45‰ V-PDB) illustrates dolomite cementation at higher temperatures and greater depths. The highly depleted values of δ18O (up to −9.16‰ V-PDB) and (up to 0.42‰ V-PDB) for δ13C of saddle dolomite (SD-I) indicate the precipitation of SD-I as a cavity filling dolomite at considerable depth. Calcite cementation and calcitization actively participated in the early, middle, and late diagenetic modifications as interpreted from their petrographic and stable isotopic studies. Porosity enhancement is clearly demonstrated by dissolution, stylolization, fracturing, and replacement dolomitization. Dolomite and calcite cementation had a negative impact on the reservoir character and occluded the dolostone porosity to a greater extent. © 2022 by the authors.</p

Eco-biostratigraphic advances in late quaternary geochronology and palaeoclimate : the marginal Gulf of Mexico analogue

This study combines high-resolution planktonic foraminiferal eco-biostratigraphy and palaeoclimatic data from the high-sedimentation-rate core JPC-26 from the northwestern margin of the Gulf of Mexico (GoM). The eco-biozones recognized (GOMPFE1-12) being correlated with published Mg/Ca-based sea surface temperatures. This updated palaeoclimatic and stratigraphic reference record facilitates correlations with the Greenland ice core events and their climatic relationships, and also provides a solid stratigraphic framework for correlations with other palaeoclimatic and palaeoceanographic records in the circum-GOM/Caribbean region. This multidisciplinary approach underlines the utility of supporting conventional dating methodologies with different constraints, and further reveals a powerful tool for reliably correlating marine records between comparable deep-sea marginal settings and coeval sequences of this region

Evidence of Stable Foraminifera Biomineralization during the Last Two Climate Cycles in the Tropical Atlantic Ocean

Planktonic foraminiferal biomineralization intensity, reflected by the weight of their shell calcite mass, affects global carbonate deposition and is known to follow climatic cycles by being increased during glacial stages and decreased during interglacial stages. Here, we measure the dissolution state and the mass of the shells of the planktonic foraminifera species Globigerina bulloides from a Tropical Eastern North Atlantic site over the last two glacial–interglacial climatic transitions, and we report no major changes in plankton calcite production with the atmospheric pCO2 variations. We attribute this consistency in foraminifera calcification to the climatic and hydrological stability of the tropical regions. However, we recorded increased shell masses midway through the penultimate deglaciation (Termination II). In order to elucidate the cause of the increased shell weights, we performed δ18O, Mg/Ca, and μCT measurements on the same shells from a number of samples surrounding this event. Compared with the lighter ones, we find that the foraminifera of increased weight are internally contaminated by sediment infilling and that their shell masses respond to local surface seawater density changes.</jats:p

Evidence of stable foraminifera biomineralization during the last two climate cycles in the tropical Atlantic ocean

Unidad de excelencia María de Maeztu CEX2019-000940-MPlanktonic foraminiferal biomineralization intensity, reflected by the weight of their shell calcite mass, affects global carbonate deposition and is known to follow climatic cycles by being increased during glacial stages and decreased during interglacial stages. Here, we measure the dissolution state and the mass of the shells of the planktonic foraminifera species Globigerina bulloides from a Tropical Eastern North Atlantic site over the last two glacial-interglacial climatic transitions, and we report no major changes in plankton calcite production with the atmospheric pCO2 variations. We attribute this consistency in foraminifera calcification to the climatic and hydrological stability of the tropical regions. However, we recorded increased shell masses midway through the penultimate deglaciation (Termination II). In order to elucidate the cause of the increased shell weights, we performed δ18O, Mg/Ca, and μCT measurements on the same shells from a number of samples surrounding this event. Compared with the lighter ones, we find that the foraminifera of increased weight are internally contaminated by sediment infilling and that their shell masses respond to local surface seawater density changes

Influence of surface ocean density on planktonic foraminifera calcification.

This study provides evidence that ambient seawater density influences calcification and may account for the observed planktonic foraminifera shell mass increase during glacial times. Volumes of weighed fossil Globigerina bulloides shells were accurately determined using X-ray Computer Tomography and were combined with water density reconstructions from Mg/Ca and δ18O measurements to estimate the buoyancy force exerted on each shell. After assessment of dissolution effects, the resulting relationship between shell mass and buoyancy suggests that heavier shells would need to be precipitated in glacial climates in order for these organisms to remain at their optimum living depth, and counterbalance the increased buoyant force of a denser, glacial ocean. Furthermore, the reanalysis of bibliographic data allowed the determination of a relationship between G. bulloides shell mass and ocean density, which introduces implications of a negative feedback mechanism for the uptake of atmospheric CO2 by the oceans