Observations of cosmic-ray modulations in the fall, 1984

Modulation of cosmic-ray energy spectrum was studied by using the Turku double neutron monitor. The multiplicity region of detected neutrons produced by cosmic ray hadrons in the monitor was divided into seven categories corresponding to mean energies 0.1, 0.3, 1.0, 3.2, 8.6, 21, and 94 GeV of hadrons at sea level. Based on 24-hour frequencies, a statistical analysis showed that modulation of the intensity in all categories occurred during several periods in the fall 1984. The magnitude of the variation was a few per cent

A facility for investigation of multiple hadrons at cosmic-ray energies

An experimental arrangement for studying multiple hadrons produced in high-energy hadron-nucleus interactions is under construction at the university of Turku. The method of investigation is based on the detection of hadrons arriving simultaneously at sea level over an area of a few square meters. The apparatus consists of a hadron spectrometer with position-sensitive detectors in connection with a small air shower array. The position resolution using streamer tube detectors will be about 10 mm. Energy spectra of hadrons or groups of simultaneous hadrons produced at primary energies below 10 to the 16th power eV can be measured in the energy range 1 to 2000 GeV

Spectral analysis of the Forbush decrease of 13 July 1982

The maximum entropy method has been applied in the spectral analysis of high-energy cosmic-ray intensity during the large Forbush event of July 13, 1982. An oscillation with period of about 2 hours and amplitude of 1 to 3% was found to be present during the decrease phase. This oscillation can be related to a similar periodicity in the magnetospheric field. However, the variation was not observed at all neutron monitor stations. In the beginning of the recovery phase, the intensity oscillated with a period of about 10 hours and amplitude of 3%

Investigation of cosmic rays in very short time scales

A fast databuffer system, where cosmic ray events in the Turku hadron spectrometer, including particle arrival times are recorded with time resolution of 100 ns was constructed. The databuffer can be read continuously by a microprocessor, which preanalyzes the data and transfers it to the main computer. The time span, that can be analyzed in every detail, is a few seconds. The high time resolution enables a study of time correlated groups of high energy particles. In addition the operational characteristics of the spectrometer can be monitored in detail

Kinetic regularities, catalyst deactivation and reactivation

Funding text 1 The research is funded from Ministry of Education and Science of the Russian Federation Program No. 075–03–2021–287/6 (Russia). Funding text 2 XPS measurements were carried out at the Central laboratories of Tomsk Polytechnic University (Analytical Center). HRTEM was carried out at the Innovation centre for Nanomaterials and Nanotechnologies of Tomsk Polytechnic University. The ICP-OES analysis was carried out using the core facilities of “Physics and Chemical methods of analysis” of Tomsk Polytechnic University. Fundação para a Ciência e a Tecnologia for Scientific Employment Stimulus Institutional Call (CEECINST/00102/2018), UIDB/50006/2020 and UIDP/50006/2020 (LAQV), UIDB/00100/2020 and UIDP/00100/2020 (Centro de Química Estrutural).Betulin, being a pentacyclic triterpene alcohol and an extractive from birch bark, along with its oxo-derivatives, has a broad range of physiological properties of interest for synthesis of pharmaceuticals. Instead of oxidizing betulin with strong and toxic oxidizing agents the present study shows a possibility of using liquid-phase oxidation of betulin with air over supported Ag NPs catalysts as an alternative method for synthesis of its oxo-derivatives. Based on catalytic studies, high resolution transmission electron microscopy, X-ray photoelectron spectroscopy and ultraviolet-visible diffuse reflectance spectroscopy, the evolution of the surface of nanosilver catalysts during the catalysis was demonstrated, as well as under the impact of reactant gas composition. The kinetic regularities and causes of deactivation of supported Ag NPs catalysts were revealed. An approach to the regeneration of silver catalysts was proposed. Kinetic analysis with numerical data fitting was performed resulting in an adequate description of the concentration dependencies.publishersversionpublishe

Infraestrutura verde e alterações climáticas: um contributo para a mitigação e adaptação do território às alterações climáticas

No projetado quadro de alterações climáticas são esperados impactos que passam pelo aumento generalizado da temperatura, maior ocorrência e intensidade de ondas de calor, maior reincidência de fenómenos de precipitação extrema e inerentes inundações, disrupção da produção agrícola, perda de biodiversidade, entre outros. As estratégias de mitigação das causas e de adaptação às consequências das alterações climáticas poderá passar pela valorização da Infraestrutura Verde, que desde o jardim ou parque urbano às áreas agrícolas e florestais, assume sérios benefícios às comunidades humanas, tais como a amenização do aumento de temperatura e diminuição do efeito de ilha de calor, redução do escoamento superficial com assinalável contribuição para a atenuação da intensidade de inundações, a possibilidade de produção agrícola de proximidade, o sequestro de gases de efeito de estufa, conexão entre habitats fragmentados, recreio e oportunidades de ecoturismo, entre demais. A presente comunicação intenta construir uma análise sólida, em literatura científica, no sentido de estudar, consubstanciadamente, os benefícios da Infraestrutura Verde e a necessidade da sua congruente gestão territorial.The projected climate change impacts for Europe are, mainly, the general increase in temperature, the higher occurrence and intensity of heat waves, higher occurrence of extreme precipitation events and associated flooding, disruption of agricultural production, the loss of biodiversity, among others. Strategies to mitigate the causes and adapt to the consequences of climate change may involve the enhancement of Green Infrastructure, which, from the garden or urban park to the agricultural and forestry areas, gives serious benefits to human communities, such as the reduction of temperature increase and heat island effect, decrease of runoff with remarkable contribution to the attenuation of the intensity of flooding, the possibility of local farming, sequestration of greenhouse gases, improvement of connectivity between fragmented habitats and the provision of alternative opportunities of recreation and ecotourism. This communication intends to build a solid analysis of the benefits of Green Infrastructure in the case of mitigation and adaptation to climate change

One-Pot Transformation of Citronellal to Menthol Over H-Beta Zeolite Supported Ni Catalyst: Effect of Catalyst Support Acidity and Ni Loading

Citronellal was converted to menthol in a one-pot approach using H-Beta zeolite-based Ni catalyst in a batch reactor at 80 °C, under 20 bar of total pressure. The effects of H-Beta acidity (H-Beta-25 with the molar ratio SiO2/Al2O3 = 25 and H-Beta-300 with SiO2/Al2O3 = 300) and Ni loading (5, 10 and 15 wt %) on the catalytic performance were investigated. Ni was impregnated on H-Beta support using the evaporation-impregnation method. The physico-chemical properties of the catalysts were characterized by XRD, SEM, TEM, ICP-OES, N2 physisorption, TPR, and pyridine adsorption–desorption FTIR techniques. Activity and selectivity of catalysts were strongly affected by the Brønsted and Lewis acid sites concentration and strength, Ni loading, its particle size and dispersion. A synergetic effect of appropriate acidity and suitable Ni loading in 15 wt.% Ni/H-Beta-25 catalyst led to the best performance giving 36% yield of menthols and 77% stereoselectivity to (±)-menthol isomer at 93% citronellal conversion. Moreover, the catalyst was successfully regenerated and reused giving similar activity, selectivity and stereoselectivity to the desired (±)-menthol isomer as the fresh one. Graphical Abstract: [Figure not available: see fulltext.

Reductive Amination of Ketones with Benzylamine Over Gold Supported on Different Oxides

Reductive amination of cyclohexanone with benzylamine was investigated at 100 °C under 30 bar hydrogen in toluene with five different gold catalysts prepared by deposition–precipitation method and supported on TiO2, La2O3/TiO2, CeO2/TiO2, La2O3 and CeO2. Size of metallic gold varied in the range of 2.6–3.6 nm. The best catalysts in reductive amination of cyclohexanone with benzylamine were 4 wt% Au/TiO2 and 4 wt% Au/CeO2/TiO2 giving 72% and 79% yield of the desired amine. The most acidic and basic catalysts were also unselective and exhibited low activity towards imine hydrogenation. The best catalyst 4 wt% Au/CeO2/TiO2 gave in reductive amination of propiophenone 56% selectivity to the corresponding amine at 20% conversion in 5 h.</p