Rocket- and aircraft-borne trace gas measurements in the winter polar stratosphere

In January and February 1987 stratospheric rocket- and aircraft-borne trace gas measurements were done in the North Polar region using ACIMS (Active Chemical Ionization Mass Spectrometry) and PACIMS (PAssive Chemical Ionization Mass Spectrometry) instruments. The rocket was launched at ESRANGE (European Sounding Rocket Launching Range) (68 N, 21 E, Northern Sweden) and the twin-jet research aircraft operated by the DFVLR (Deutsche Forschungs- und Versuchs-anstalt fuer Luft- und Raumfahrt), and equipped with a mass spectrometer laboratory was stationed at Kiruna airport. Various stratospheric trace gases were measured including nitric acid, sulfuric acid, non-methane hydrocarbons (acetone, hydrogen cyanide, acetonitrile, methanol etc.), and ambient cluster ions. The experimental data is presented and possible implications for polar stratospheric ozone discussed

Noisy Optimization: Convergence with a Fixed Number of Resamplings

It is known that evolution strategies in continuous domains might not converge in the presence of noise. It is also known that, under mild assumptions, and using an increasing number of resamplings, one can mitigate the effect of additive noise and recover convergence. We show new sufficient conditions for the convergence of an evolutionary algorithm with constant number of resamplings; in particular, we get fast rates (log-linear convergence) provided that the variance decreases around the optimum slightly faster than in the so-called multiplicative noise model. Keywords: Noisy optimization, evolutionary algorithm, theory.Comment: EvoStar (2014

Collisional and viscous damping of MHD waves in partially ionized plasmas of the solar atmosphere

Magnetohydrodynamic (MHD) waves are widely considered as a possible source of heating for various parts of the outer solar atmosphere. Among the main energy dissipation mechanisms which convert the energy of damped MHD waves into thermal energy are collisional dissipation(resistivity) and viscosity. The presence of neutral atoms in the partially ionized plasmas of the solar photosphere, chromosphere and prominences enhances the efficiency of both these energy dissipation mechanisms. A comparative study of the efficiency of MHD wave damping in solar plasmas due to collisional and viscous energy dissipation mechanisms is presented here. The damping rates are taken from Braginskii 1965 and applied to the VAL C model of the quiet Sun (Vernazza et al. 1981). These estimations show which of the mechanisms are dominant in which regions. In general the correct description of MHD wave damping requires the consideration of all energy dissipation mechanisms via the inclusion of the appropriate terms in the generalized Ohm’s law, the momentum, energy and induction equations. Specific forms of the generalized Ohm’s Law and induction equation are presented that are suitable for regions of the solar atmosphere which are partially ionised

Comparison of Monomethylhydrazine/Hydroxypropylcellulose and Hydrocarbon/Silica Gels

Experimental studies have been performed to investigate rheology and droplet burning with different types of gelled propellants. Monomethylhydrazine has been gelled with organic hydroxypropylcellulose. JP-8 and RP-1 hydrocarbon gels have been produced with inorganic fumed silica particles. Rheological characterization showed the differences in terms of viscosity and yield stress behavior due to different types of gelling agents. Herschel-Bulkley and Carreau-Yasuda models have been used to characterize the gels with inorganic and organic gelling agents, respectively. First experiments with the Monomethylhydrazine/hydroxypropylcellulose gels showed a typical swelling process during combustion with a flexible viscous droplet surface. Contrary to that, the hydrocarbon/silica gels burned while a rigid silica structure was built, which remained unburned. Burning drop measurements have been compared to the d^2-squared law

Occurrence of Waterfowl Along a Proposed lmpoundment, the Saylorville Reservoir

Waterfowl were studied from early fall 1958 through spring 1959 along selected Des Moines River segments that will be affected by the Saylorville reservoir (now under construction). Periodic counts conducted during fall and spring yielded a total of 1,948 waterfowl (18 species) and 4 coots. During fall three species of geese (410) and five species of puddle ducks (302) were seen. Spring counts indicated 1,186 ducks of 14 species, including diving ducks (8%) and mergansers (11%). Four puddle duck species made up 74% of spring duck populations. Waterfowl per mile data were considered more valuable that waterfowl per hour data in developing usage patterns and indices. During fall a total of 169.2 miles were sampled, and waterfowl seen averaged 4.2 per mile. The following spring, along 45.0 river miles, an average of 23.0 waterfowl per mile was seen. Fall waterfowl densities varied greatly, with three peaks of waterfowl usage, but during spring, a single, rapid buildup followed by a decline in numbers occurred. Spring waterfowl- use days per mile (874) were over 10 times those of the previous fall (86.5). During fall 1958 (65 days), waterfowl- use days were calculated as 4,412 for the entire Saylorville project area (51 miles). Spring 1959 (40 days) waterfowl- use days totaled 44,574 for the same area. These data indicate considerably greater usage of the area by waterfowl than had previously been estimated

Uranium(III) coordination chemistry and oxidation in a flexible small-cavity macrocycle

U(III) complexes of the conformationally flexible, small-cavity macrocycle trans-calix[2]benzene[2]pyrrolide (L)2–, [U(L)X] (X = O-2,6-tBu2C6H3, N(SiMe3)2), have been synthesized from [U(L)BH4] and structurally characterized. These complexes show binding of the U(III) center in the bis(arene) pocket of the macrocycle, which flexes to accommodate the increase in the steric bulk of X, resulting in long U–X bonds to the ancillary ligands. Oxidation to the cationic U(IV) complex [U(L)X][B(C6F5)4] (X = BH4) results in ligand rearrangement to bind the smaller, harder cation in the bis(pyrrolide) pocket, in a conformation that has not been previously observed for (L)2–, with X located between the two ligand arene rings

Law and Quantitative Multivariate Analysis: An Encounter

This Article chronicles one attempt to blend the sophisticated science of statistics with the mysterious art of the law in an antitrust case. Once again, we hope to provide lawyers with an understanding of a tool which can be used in resolving complex factual questions wherever they arise, not merely in an antitrust context. Although the lawyer will not emerge from this encounter as an accomplished statistician or economist, he may be able to talk to his fellow social scientists and to achieve a more fruitful application of social science techniques to the law

Breaking proteins with mutations: threads and thresholds in evolution

A common high school science experiment involves anchoring one end of a rubber band to a desk and then attaching a small weight to the other end. The weight stretches the rubber band, and adding another weight causes the rubber band to dangle even lower. More weights can be added, and each one pulls the rubber band a little further towards the floor. Now, instead imagine attaching the weights to a thread. The thread stretches only slightly; so the first couple of weights have just a small effect. But if you add enough weights, the thread suddenly breaks and the weights fall to the floor. In the first case, each additional weight stretches the rubber band by the same amount, whereas in the second, it is the combination of several weights that breaks the thread. Mutating proteins is like adding weights, as mutations eventually ‘break’ the individual proteins, dragging down the fraction of proteins that still function (this fraction is the average fitness)

Analysis of Different Types of Regret in Continuous Noisy Optimization

The performance measure of an algorithm is a crucial part of its analysis. The performance can be determined by the study on the convergence rate of the algorithm in question. It is necessary to study some (hopefully convergent) sequence that will measure how "good" is the approximated optimum compared to the real optimum. The concept of Regret is widely used in the bandit literature for assessing the performance of an algorithm. The same concept is also used in the framework of optimization algorithms, sometimes under other names or without a specific name. And the numerical evaluation of convergence rate of noisy algorithms often involves approximations of regrets. We discuss here two types of approximations of Simple Regret used in practice for the evaluation of algorithms for noisy optimization. We use specific algorithms of different nature and the noisy sphere function to show the following results. The approximation of Simple Regret, termed here Approximate Simple Regret, used in some optimization testbeds, fails to estimate the Simple Regret convergence rate. We also discuss a recent new approximation of Simple Regret, that we term Robust Simple Regret, and show its advantages and disadvantages.Comment: Genetic and Evolutionary Computation Conference 2016, Jul 2016, Denver, United States. 201

Meanders and the Temperley-Lieb algebra

The statistics of meanders is studied in connection with the Temperley-Lieb algebra. Each (multi-component) meander corresponds to a pair of reduced elements of the algebra. The assignment of a weight $q$ per connected component of meander translates into a bilinear form on the algebra, with a Gram matrix encoding the fine structure of meander numbers. Here, we calculate the associated Gram determinant as a function of $q$, and make use of the orthogonalization process to derive alternative expressions for meander numbers as sums over correlated random walks.Comment: 85p, uuencoded, uses harvmac (l mode) and epsf, 88 figure