Functional carbon nanotubes for photonic applications

Carbon nanomaterials are an active frontier of research in current nanotechnology. Single wall Carbon Nanotube (SWNT) is a unique material which has already found several applications in photonics, electronics, sensors and drug delivery. This thesis presents a summary of the author’s research on functionalisation of SWNTs, a study of their optical properties, and potential for an application in laser physics. The first significant result is a breakthrough in controlling the size of SWNT bundles by varying the salt concentrations in N-methyl 2-pyrrolidone (NMP) through a salting out effect. The addition of Sodium iodide leads to self-assembly of CNTs into recognizable bundles. Furthermore, a stable dispersion can be made via addition polyvinylpyrrolidone (PVP) polymer to SWNTs-NMP dispersion, which indicates a promising direction for SWNT bundle engineering in organic solvents. The second set of experiments are concerned with enhancement of photoluminescence (PL), through the formation of novel macromolecular complexes of SWNTs with polymethine dyes with emission from enhanced nanotubes in the range of dye excitation. The effect appears to originate from exciton energy transfer within the solution. Thirdly, SWNT base-saturable absorbers (SA) were developed and applied to mode locking of fibre lasers. SWNT-based SAs were applied in both composite and liquid dispersion forms and achieved stable ultrashort generation at 1000nm, 1550nm, and 1800 nm for Ytterbium, Erbium and Thulium-doped fibre laser respectively. The work presented here demonstrates several innovative approaches for development of rapid functionalised SWNT-based dispersions and composites with potential for application in various photonic devices at low cost

Polarization insensitive in-fiber mode-locker based on carbon nanotube with N-methyl-2-pryrrolidone solvent filled fiber microchamber

We report an in-fiber laser mode locker based on carbon nanotube with n-methyl-2-pryrrolidone solvent filled in-fiber microchamber. Symmetrically femtosecond laser fabricated in-fiber microchamber with randomly oriented nanotubes assures polarization insensitive oscillation of laser mode locking. The proposed and demonstrated passively mode locked fiber laser shows higher energy soliton output. The laser has an output power of ∼29 mW (corresponding to 11 nJ energy). It shows stable soliton output with a repetition rate of ∼2.3 MHz and pulse width of ∼3.37 ps

High power Q-switched thulium doped fibre laser using carbon nanotube polymer composite saturable absorber

We have proposed and demonstrated a Q-switched Thulium doped fibre laser (TDFL) with a ‘Yin-Yang’ all-fibre cavity scheme based on a combination of nonlinear optical loop mirror (NOLM) and nonlinear amplified loop mirror (NALM). Unidirectional lasing operation has been achieved without any intracavity isolator. By using a carbon nanotube polymer composite based saturable absorber (SA), we demonstrated the laser output power of ~197 mW and pulse energy of 1.7 μJ. To the best of our knowledge, this is the highest output power from a nanotube polymer composite SA based Q-switched Thulium doped fibre laser

Isolator-free switchable uni- and bidirectional hybrid mode-locked erbium-doped fiber laser

An Erbium-doped fibre ring laser hybrid mode-locked with single-wall carbon nanotubes (SWNT) and nonlinear polarisation evolution (NPE) without an optical isolator has been investigated for various cavity conditions. Precise control of the state of polarisation (SOP) in the cavity ensures different losses for counter-propagating optical fields. As the result, the laser operates in quasi-unidirectional regime in both clockwise (CW) and counter-clockwise (CCW) directions with the emission strengths difference of the directions of 22 dB. Furthermore, by adjusting the net birefringence in the cavity, the laser can operate in a bidirectional generation. In this case, a laser pumped with 75 mW power at 980 nm generates almost identical 790 and 570 fs soliton pulses with an average power of 1.17 and 1.11 mW. The operation stability and pulse quality of the soliton pulses in both unidirectional regimes are highly competitive with those generated in conventional ring fibre lasers with isolator in the cavity. Demonstrated bidirectional laser operation can find vital applications in gyroscopes or precision rotation sensing technologies

High-sensitivity refractive index sensor based on large-angle tilted fiber grating with carbon nanotube deposition

This paper presents a highly sensitive ambient refractive index (RI) sensor based on 81° tilted fiber grating (81°-TFG) structure UV-inscribed in standard telecom fiber (62.5μm cladding radius) with carbon nanotube (CNT) overlay deposition. The sensing mechanism is based on the ability of CNT to induce change in transmitted optical power and the high sensitivity of 81°-TFG to ambient refractive index. The thin CNT film with high refractive index enhances the cladding modes of the TFG, resulting in the significant interaction between the propagating light and the surrounding medium. Consequently, the surrounding RI change will induce not only the resonant wavelength shift but also the power intensity change of the attenuation band in the transmission spectrum. Result shows that the change in transmitted optical power produces a corresponding linear reduction in intensity with increment in RI values. The sample shows high sensitivities of ∼207.38nm/RIU, ∼241.79nm/RIU at RI range 1.344-1.374 and ∼113.09nm/RIU, ∼144.40nm/RIU at RI range 1.374-1.392 (for X-pol and Y-pol respectively). It also shows power intensity sensitivity of ∼ 65.728dBm/RIU and ∼ 45.898 (for X-pol and Y-pol respectively). The low thermal sensitivity property of the 81°-TFG offers reduction in thermal cross-sensitivity and enhances specificity of the sensor

Localized surface plasmon fiber device coated with carbon nanotubes for the specific detection of CO2

We explored the potential of a carbon nanotube (CNT) coating working in conjunction with a recently developed localized surface plasmon (LSP) device (based upon a nanostructured thin film consisting of of nano-wires of platinum) with ultra-high sensitivity to changes in the surrounding index. The uncoated LSP sensor’s transmission resonances exhibited a refractive index sensitivity of Δλ/Δn ~ -6200nm/RIU and ΔΙ/Δn ~5900dB/RIU, which is the highest reported spectral sensitivity of a fiber optic sensor to bulk index changes within the gas regime. The complete device provides the first demonstration of the chemically specific gas sensing capabilities of CNTs utilizing their optical characteristics. This is proven by investigating the spectral response of the sensor before and after the adhesion of CNTs to alkane gases along with carbon dioxide. The device shows a distinctive spectral response in the presence of gaseous CO2 over and above what is expected from general changes in the bulk refractive index. This fiber device yielded a limit of detection of 150ppm for CO2 at a pressure of one atmosphere. Additionally the adhered CNTs actually reduce sensitivity of the device to changes in bulk refractive index of the surrounding medium. The polarization properties of the LSP sensor resonances are also investigated and it is shown that there is a reduction in the overall azimuthal polarization after the CNTs are applied. These optical devices offer a way of exploiting optically the chemical selectivity of carbon nanotubes, thus providing the potential for real-world applications in gas sensing in many inflammable and explosive environments

Poor fluorinated graphene sheets carboxymethylcellulose polymer composite mode locker for erbium doped fiber laser

We report poor fluorinated graphene sheets produced by thermal exfoliation embedding in carboxymethylcellulose polymer composite (GCMC) as an efficient mode locker for erbium doped fiber laser. Two GCMC mode lockers with different concentration have been fabricated. The GCMC based mode locked fiber laser shows stable soliton output pulse shaping with repetition rate of 28.5MHz and output power of 5.5 mW was achieved with the high concentration GCMC, while a slightly higher output power of 6.9 mW was obtained using the low concentration GCMC mode locker

Emergence of additional visible range photoluminescence due to aggregation of cyanine dye:astraphloxin on carbon nanotubes dispersed with anionic surfactant

Self-organization of organic molecules with carbon nanomaterials leads to formation of functionalized molecular nano-complexes with advanced features. We present a study of physical and chemical properties of carbon nanotube-surfactant-indocarbocyanine dye (astraphloxin) in water focusing on aggregation of the dye and resonant energy transfer from the dye to the nanotubes. Self-assembly of astraphloxin is evidenced in absorbance and photoluminescence depending dramatically on the concentrations of both the dye and surfactant in the mixtures. We observed an appearance of new photoluminescence peaks in visible range from the dye aggregates. The aggregates characterized with red shifted photoluminescence peaks at 595, 635 and 675 nm are formed mainly due to the presence of surfactant at the premicellar concentration. The energy transfer from the dye to the nanotubes amplifying near-infrared photoluminescence from the nanotubes is not affected by the aggregation of astraphloxin molecules providing important knowledge for further development of advanced molecular nano-complexes. The aggregation with the turned-on peaks and the energy transfer with amplified photoluminescence create powerful tools of visualization and/or detection of the nanotubes in visible and near-infrared spectral range, respectively, boosting its possible applications in sensors, energy generation/storage, and healthcare

Models for basic warp knitted fabrics Part II: single guide bar fabrics (closed-lap and open-lap)

Warp knitted fabrics are mainly used as household goods, technical textiles, medical textiles, etc. Modeling of these fabrics is necessary for predicting the desired technical or medical functions beforehand. In this context, the present series of papers is devoted to the modeling of basic warp knitted fabrics. In this, Part II of this series, models for single guide bar fabrics are created. There are mainly two types of single bar fabrics, namely closed-lap and open-lap single bar fabrics. Structures are also changed by having different lapping movements up to the five needle spaces. In this work, 1 and 1, 2 and 1, 3 and 1, 4 and 1 closed-lap and 1 and 1, 2 and 1, 3 and 1 open-lap single bar warp knitted fabrics are considered. During modeling, the loop leanings in the course-wise direction are considered, curvature equalities at the loop parts are attained as much as possible, two connected parabolas are taken as the fabric plane model of the loop connection part, loop heads are taken as parametric ellipses in two dimensions and the remaining loop parts are modeled by wrapping parabolic or cubic curves on imaginary cylindrical or conical objects. The models created are versatile and they can be changed and used for special cases. The models created are drawn to scale by using the 3DS-MAX computer graphical program. At first glance, it is seen that the shapes obtained by the models are similar to the ones that can be observed in real samples

Models for basic warp knitted fabrics Part III: the two guide bar fabrics (Double Tricot, Locknit, Reverse Locknit, Satin, Sharkskin)

Two guide bar warp knitted fabrics are used as technical textile applications nowadays. In this, Part III of these series of papers, models for basic two guide bar warp knitted fabrics are created and given based on Parts I and II. Modeling of warp knitted fabrics started in the 1960s with some basic geometrical models and it was continued with using Non Uniform Basis Spline (NURBS) curves and surfaces. There were discontinuities in the loop parts in early created geometrical models and the NURBS models needed some control points from some sources. In this work instead of using NURBS curves, modeling of warp knitted fabric is attempted by using known curves. During creation of the models, curvature equalities are attained as much as possible, loop connection parts are modeled by having two continuously connected parabolas for the Double Tricot fabric and the loop connection parts of the other two bar fabrics are obtained by applying a sinus square curve to the connection part of the Double Tricot fabric. The models created are versatile and they can be changed and used for special cases. Models created are drawn to scale by using the 3DS-Max Computer Graphical Program. At first glance, it is seen that the model shapes are similar to the real fabric structures, which can be observed on photographs of them