Speleothem Paleoclimatology for the Caribbean, Central America, and North America

Speleothem oxygen isotope records from the Caribbean, Central, and North America reveal climatic controls that include orbital variation, deglacial forcing related to ocean circulation and ice sheet retreat, and the influence of local and remote sea surface temperature variations. Here, we review these records and the global climate teleconnections they suggest following the recent publication of the Speleothem Isotopes Synthesis and Analysis (SISAL) database. We find that low-latitude records generally reflect changes in precipitation, whereas higher latitude records are sensitive to temperature and moisture source variability. Tropical records suggest precipitation variability is forced by orbital precession and North Atlantic Ocean circulation driven changes in atmospheric convection on long timescales, and tropical sea surface temperature variations on short timescales. On millennial timescales, precipitation seasonality in southwestern North America is related to North Atlantic climate variability. Great Basin speleothem records are closely linked with changes in Northern Hemisphere summer insolation. Although speleothems have revealed these critical global climate teleconnections, the paucity of continuous records precludes our ability to investigate climate drivers from the whole of Central and North America for the Pleistocene through modern. This underscores the need to improve spatial and temporal coverage of speleothem records across this climatically variable region

Charcoal analysis for temperature reconstruction with infrared spectroscopy

The duration and maximum combustion temperature of vegetation fires are important fire properties with implications for ecology, hydrology, hazard potential, and many other processes. Directly measuring maximum combustion temperature during vegetation fires is difficult. However, chemical transformations associated with temperature are reflected in the chemical properties of charcoals (a by-product of fire). Therefore, charcoal could be used indirectly to determine the maximum combustion temperature of vegetation fires with application to palaeoecological charcoal records. To evaluate the reliability of charcoal chemistry as an indicator of maximum combustion temperature, we studied the chemical properties of charcoal formed through two laboratory methods at measured temperatures. Using a muffle furnace, we generated charcoal from the woody material of ten different tree and shrub species at seven distinct peak temperatures (from 200°C to 800°C in 100°C increments). Additionally, we simulated more natural combustion conditions by burning woody material and leaves of four tree species in a combustion facility instrumented with thermocouples, including thermocouples inside and outside of tree branches. Charcoal samples generated in these controlled settings were analyzed using Fourier Transform Infrared (FTIR) spectroscopy to characterize their chemical properties. The Modern Analogue Technique (MAT) was employed on FTIR spectra of muffle furnace charcoal to assess the accuracy of inferring maximum pyrolysis temperature. The MAT model temperature matching accuracy improved from 46% for all analogues to 81% when including ±100°C. Furthermore, we used MAT to compare charcoal created in the combustion facility with muffle furnace charcoal. Our findings indicate that the spectra of charcoals generated in a combustion facility can be accurately matched with muffle furnace-created charcoals of similar temperatures using MAT, and the accuracy improved when comparing the maximum pyrolysis temperature from muffle furnace charcoal with the maximum inner temperature of the combustion facility charcoal. This suggests that charcoal produced in a muffle furnace may be representative of the inner maximum temperatures for vegetation fire-produced charcoals

Effective Engagement While Scaling Up: Lessons from a Citizen Science Program Transitioning from Single- to Multi-Region Scale

Engagement strategies are central to the success of community and citizen science (CCS) initiatives; however, relatively little has been written on approaches that support project growth. Here, we assess the four components of the Mountain Rain or Snow engagement strategy (recruitment, training, activation, and retention) as the project transitioned from one region to four to increase participation in documenting precipitation phase. To scale up, we replicated the structure from our single-region effort in new regions while using place-based text messaging with observers across broad geographic areas and a localized approach to building partnerships. We use two sources of data—a participant feedback survey of 443 respondents and participant analytics of 877 new sign-ups and 13,017 observations submitted during the study—to evaluate success relative to project goals established at the outset of the expansion process. The Mountain Rain or Snow engagement strategy met project-wide goals for growing our observer network, for data collection, and for maintaining observer satisfaction with communication tools. We did not meet region-level goals for recruitment and activation in one location. Diverse partnerships and approaches to amplification supported recruitment success for this project. Survey data show that 85% of respondents found our novel approach to training helpful, and 82% found activation text messages helpful to understand when and how to participate. Feedback on communication preferences show that there was unmet demand for text messaging. Our evaluation found that a consistent structure across regions coupled with place-based messaging enhanced engagement while scaling up

Improved estimates of preindustrial biomass burning reduce the magnitude of aerosol climate forcing in the Southern Hemisphere.

Fire plays a pivotal role in shaping terrestrial ecosystems and the chemical composition of the atmosphere and thus influences Earth's climate. The trend and magnitude of fire activity over the past few centuries are controversial, which hinders understanding of preindustrial to present-day aerosol radiative forcing. Here, we present evidence from records of 14 Antarctic ice cores and 1 central Andean ice core, suggesting that historical fire activity in the Southern Hemisphere (SH) exceeded present-day levels. To understand this observation, we use a global fire model to show that overall SH fire emissions could have declined by 30% over the 20th century, possibly because of the rapid expansion of land use for agriculture and animal production in middle to high latitudes. Radiative forcing calculations suggest that the decreasing trend in SH fire emissions over the past century largely compensates for the cooling effect of increasing aerosols from fossil fuel and biofuel sources

Improved estimates of preindustrial biomass burning reduce the magnitude of aerosol climate forcing in the Southern Hemisphere.

Fire plays a pivotal role in shaping terrestrial ecosystems and the chemical composition of the atmosphere and thus influences Earth's climate. The trend and magnitude of fire activity over the past few centuries are controversial, which hinders understanding of preindustrial to present-day aerosol radiative forcing. Here, we present evidence from records of 14 Antarctic ice cores and 1 central Andean ice core, suggesting that historical fire activity in the Southern Hemisphere (SH) exceeded present-day levels. To understand this observation, we use a global fire model to show that overall SH fire emissions could have declined by 30% over the 20th century, possibly because of the rapid expansion of land use for agriculture and animal production in middle to high latitudes. Radiative forcing calculations suggest that the decreasing trend in SH fire emissions over the past century largely compensates for the cooling effect of increasing aerosols from fossil fuel and biofuel sources

Synchronous volcanic eruptions and abrupt climate change ∼17.7 ka plausibly linked by stratospheric ozone depletion.

Glacial-state greenhouse gas concentrations and Southern Hemisphere climate conditions persisted until ∼17.7 ka, when a nearly synchronous acceleration in deglaciation was recorded in paleoclimate proxies in large parts of the Southern Hemisphere, with many changes ascribed to a sudden poleward shift in the Southern Hemisphere westerlies and subsequent climate impacts. We used high-resolution chemical measurements in the West Antarctic Ice Sheet Divide, Byrd, and other ice cores to document a unique, ∼192-y series of halogen-rich volcanic eruptions exactly at the start of accelerated deglaciation, with tephra identifying the nearby Mount Takahe volcano as the source. Extensive fallout from these massive eruptions has been found >2,800 km from Mount Takahe. Sulfur isotope anomalies and marked decreases in ice core bromine consistent with increased surface UV radiation indicate that the eruptions led to stratospheric ozone depletion. Rather than a highly improbable coincidence, circulation and climate changes extending from the Antarctic Peninsula to the subtropics-similar to those associated with modern stratospheric ozone depletion over Antarctica-plausibly link the Mount Takahe eruptions to the onset of accelerated Southern Hemisphere deglaciation ∼17.7 ka

Pre-Columbian Fire Management Linked to Refractory Black Carbon Emissions in the Amazon

Anthropogenic climate change—combined with increased human-caused ignitions—is leading to increased wildfire frequency, carbon dioxide emissions, and refractory black carbon (rBC) aerosol emissions. This is particularly evident in the Amazon rainforest, where fire activity has been complicated by the synchronicity of natural and anthropogenic drivers of ecological change, coupled with spatial and temporal heterogeneity in past and present land use. One approach to elucidating these factors is through long-term regional fire histories. Using a novel method for rBC determinations, we measured an approximately 3500-year sediment core record from Lake Caranã in the eastern Amazon for rBC influx, a proxy of biomass burning and fossil fuel combustion. Through comparisons with previously published records from Lake Caranã and regional evidence, we distinguished between local and regional rBC emission sources demonstrating increased local emissions of rBC from ~1250 to 500 calendar years before present (cal yr BP), coinciding with increased local-scale fire management during the apex of pre-Columbian activity. This was followed by a regional decline in biomass burning coincident with European contact, pre-Columbian population decline, and regional fire suppression associated with the rubber boom (1850–1910 CE), supporting the minimal influence of climate on regional burning at this time. During the past century, rBC influx has rapidly increased. Our results can serve to validate rBC modeling results, aiding with future predictions of rBC emissions and associated impacts to the climate system

Four-fold Increase in Solar Forcing on Snow in Western U.S. Burned Forests Since 1999

Forest fires are increasing across the American West due to climate warming and fire suppression. Accelerated snow melt occurs in burned forests due to increased light transmission through the canopy and decreased snow albedo from deposition of light-absorbing impurities. Using satellite observations, we document up to an annual 9% growth in western forests burned since 1984, and 5 day earlier snow disappearance persisting for \u3e10 years following fire. Here, we show that black carbon and burned woody debris darkens the snowpack and lowers snow albedo for 15 winters following fire, using measurements of snow collected from seven forested sites that burned between 2002 and 2016. We estimate a 372 to 443% increase in solar energy absorbed by snowpacks occurred beneath charred forests over the past two decades, with enhanced post-fire radiative forcing in 2018 causing earlier melt and snow disappearance in \u3e 11% of forests in the western seasonal snow zone

Determining the Δ47 acid fractionation in dolomites

This paper reports the fractionation of Δ47 during the digestion of dolomite in phosphoric acid between 25°C and 90°C using five different samples, including three of Pliocene age from the Bahamas, one from the Jurassic in the Middle East, and one obtained from the National Institute of Standards (NIST 88b). The composition of the dolomites analyzed varied from Ca0.56Mg0.44CO3 to Ca0.50Mg0.50CO3. Fractionation values were also compared between the common acid bath and sealed vessel techniques at various temperatures. No statistically significant differences were observed either between these two methods or as a function of the dolomite’s stoichiometry. These data produce a difference in fractionation of 0.153±0.011‰ for dolomite samples digested at 90°C compared to those reacted at 25°C, a value higher and statistically different to previously published values. Utilization of this value in a study of dolomites from a core drilled on the island of San Salvador in the Bahamas yielded temperatures and δ18Ofluid values which agree with previous interpretations on the formation of these dolomites. Application of this value to other published studies produces lower estimates of temperature and δ18Ofluid values for the dolomitization process that are more consistent with the geologic models suggested for these studies