2,331 research outputs found

    Ion Exchange for Nutrient Recovery Coupled with Biosolids-Derived Biochar Pretreatment to Remove Micropollutants

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    Wastewater, especially anaerobic treatment effluent, contains high ammonia nitrogen (NH4-N) and inorganic orthophosphate (PO4-P), which necessitate additional treatment to meet stringent discharge regulations. Ion exchange regeneration is a process that can be adopted for not only removing but also recovering nutrients. However, recovering nutrients by ion exchange from nutrient-rich effluents that also contain micropollutants (which typically pass through anaerobic treatment as well) may result in subsequent problems, since micropollutants could end up in ion exchange effluent, regenerant, or recovered fertilizer products. Micropollutant removal by a nonselective adsorbent, such as biosolids-derived biochar, before nutrient recovery processes would mitigate potential risks. The objective of this research was to evaluate the capability of biosolids-derived biochar as a pretreatment step for separating micropollutants from nutrient-rich water before ion exchange for nutrient recovery. In the presence of ammonium and phosphate, both pristine and regenerated biosolids-derived biochar could effectively adsorb triclosan (TCS) and estradiol (E2), and to a lesser extent, sulfamethoxazole (SMX) in batch sorption experiments. On the other hand, nutrient ions were not effectively adsorbed by biosolids-derived biochar. A continuous flow-through system consisting of columns in series filled with biochar, LayneRT, and then clinoptilolite was operated to test selective removal of micropollutants and nutrients in a flow-through system. The biochar column achieved more than 80% removal of influent TCS and E2, thereby reducing the chances of micropollutants being adsorbed by ion exchangers. Sulfamethoxazole removal through the biochar column was only 50%, indicating that biosolids-derived biochar would have to be optimized in the future for hydrophilic micropollutant removal. Influent nutrients were not effectively removed by the biochar column, but were captured in their respective selective ion exchanger columns. This research revealed that biosolids-derived biochar could be employed before ion exchange resins for removal of micropollutants from nutrient-rich water

    ARRAY TOMOGRAPHY:15 YEARS OF SYNAPTIC ANALYSIS

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    Synapses are minuscule, intricate structures crucial for the correct communication between neurons. In the 125 years since the term synapse was first coined, we have advanced a long way when it comes to our understanding of how they work and what they do. Most of the fundamental discoveries have been invariably linked to advances in technology. However, due to their size, delicate structural integrity and their sheer number, our knowledge of synaptic biology has remained somewhat elusive and their role in neurodegenerative diseases still remains largely unknown. Here, we briefly discuss some of the imaging technologies used to study synapses and focus on the utility of the high-resolution imaging technique array tomography (AT). We introduce the AT technique and highlight some of the ways it is utilised with a particular focus on its power for analysing synaptic composition and pathology in human post-mortem tissue. We also discuss some of the benefits and drawbacks of techniques for imaging synapses and highlight some recent advances in the study of form and function by combining physiology and high-resolution synaptic imaging

    WeMO effects on the amount and the chemistry of winter precipitation in the north-eastern Iberian Peninsula

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    The cluster classification of provenances at a site in the NE Iberian Peninsula indicated that in the period of extended winter (December to March, DJFM) fast Atlantic air flows correspond to positive WeMO index (WeMOi), while negative WeMOi are associated to Mediterranean circulations. The amount of winter precipitation was inversely correlated with winter WeMOi. Wet deposition fluxes of marine-derived (Na+, Mg2+ and Cl) and anthropogenic-derived (NO3 and K+) ions were significantly (and negatively) related to winter WeMOi. The negative phase of WeMO causes the entry of air masses from the Mediterranean into the Iberian Peninsula, that are enriched with marine ions. For NO3 this result suggests the advection over the Mediterranean of polluted air masses from southern Europe and the scavenging and deposition of this pollution by rain during WeMO negative phases. This will carry long-range pollutants to the NE Iberian Peninsula, but local pollutants may also contribute, as precipitation events from the Mediterranean (associated to negative WeMOi) may incorporate local anthropogenic emissions that build up during the winter anticyclonic episodes typical of the region.Postprint (published version

    Visual search task immediate training effects on task-related functional connectivity

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    This is a pre-print of an article published in [ Brain Imaging and Behavior. The final authenticated version is available online at: https://doi.org/10.1007/s11682-018-9993-yBrain plasticity occurs over the course of the human lifetime. Learning and training modify our neuronal synapses and adapt our brain activity, from priming effects in modal areas to higher-order changes in the association cortex. The current state of the art suggests that learning and training effects might induce large-scale brain connectivity changes. Here, we used task-fMRI data and graph-based approaches to study the immediate brain changes in functional connections associated with training on a visual search task, and the individual differences in learning were studied by means of brain-behavior correlations. In a previous work, we found that trained participants improved their response speed on a visual search task by 31%, whereas the control group hardly changed. In the present study, we showed that trained individuals changed regional connections (local links) in cortical areas devoted to the specific visual search processes and to areas that support information integration, and largely modified distributed connections (distant links) linking primary visual areas to specific attentional and cognitive control areas. In addition, we found that the individuals with the most enhanced connectivity in the dorsolateral prefrontal cortex performed the task faster after training. The observed behavioral and brain connectivity findings expand our understanding of large-scale dynamic readjustment of the human brain after learning experiences

    Brain networks involved in accented speech processing

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    We investigated the neural correlates of accented speech processing (ASP) with an fMRI study that overcame prior limitations in this line of research: we preserved intelligibility by using two regional accents that differ in prosody but only mildly in phonetics (Latin American and Castilian Spanish), and we used independent component analysis to identify brain networks as opposed to isolated regions. ASP engaged a speech perception network composed primarily of structures related with the processing of prosody (cerebellum, putamen, and thalamus). This network also included anterior fronto-temporal areas associated with lexical-semantic processing and a portion of the inferior frontal gyrus linked to executive control. ASP also recruited domain-general executive control networks related with cognitive demands (dorsal attentional and default mode networks) and the processing of salient events (salience network). Finally, the reward network showed a preference for the native accent, presumably revealing people's sense of social belonging

    The role of African dust in the formation of Quaternary soils on Mallorca, Spain and implications for the genesis of Red Mediterranean soils

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    African dust additions explain the origin of terra rossa soils that are common on the carbonate-platform island of Mallorca, Spain. Mineralogical and geochemical analyses indicate that Quaternary carbonate eolianites on Mallorca have a very high purity, usually composed of more than 90% carbonate minerals (calcite, dolomite, and aragonite). In contrast, terra rossa soils developed on these eolianites have lower carbonate contents and contain higher concentrations of quartz and other silicates. Analyses of immobile trace elements indicate that the non-carbonate fractions of the eolianites have distinctive Zr/Hf, La/Yb, Cr/Sc and Th/Ta values that differ from the superjacent terra rossa soils. These observations indicate that even if suf!cient dissolution of the eolianite had taken place to create the soils by residual accumulation, immobile element ratios in the soils require an external source. However, Zr/Hf, La/Yb, Cr/Sc and Th/Ta values in the soils fall within the range of values for these element ratios in African dust collected on Barbados and mainland Spain. We conclude that the silicate fractions of terra rossa soils on Mallorca are derived mainly, though not wholly, from far-traveled African dust, and this process may explain the origin of other terra rossa soils found in southern Europe
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