4,166 research outputs found
Aperiodic invariant continua for surface homeomorphisms
We prove that if a homeomorphism of a closed orientable surface S has no
wandering points and leaves invariant a compact, connected set K which contains
no periodic points, then either K=S and S is a torus, or is the
intersection of a decreasing sequence of annuli. A version for non-orientable
surfaces is given.Comment: 8 pages, to appear in Mathematische Zeitschrif
Shuttle Mechanism for Charge Transfer in Coulomb Blockade Nanostructures
Room-temperature Coulomb blockade of charge transport through composite
nanostructures containing organic inter-links has recently been observed. A
pronounced charging effect in combination with the softness of the molecular
links implies that charge transfer gives rise to a significant deformation of
these structures. For a simple model system containing one nanoscale metallic
cluster connected by molecular links to two bulk metallic electrodes we show
that self-excitation of periodic cluster oscillations in conjunction with
sequential processes of cluster charging and decharging appears for a
sufficiently large bias voltage. This new `electron shuttle' mechanism of
discrete charge transfer gives rise to a current through the nanostructure,
which is proportional to the cluster vibration frequency.Comment: 4 pages, 4 figure
Inherent tracers for carbon capture and storage in sedimentary formations: composition and applications
Inherent tracers - the “natural” isotopic and trace gas composition of captured CO₂ streams – are potentially powerful tracers for use in CCS technology. This review outlines for the first time the expected carbon isotope and noble gas compositions of captured CO₂ streams from a range of feedstocks, CO₂-generating processes and carbon capture techniques. The C-isotope composition of captured CO₂ will be most strongly controlled by the feedstock, but significant isotope fractionation is possible during capture; noble gas concentrations will be controlled by the capture technique employed. Comparison with likely baseline data suggests that CO₂ generated from fossil fuel feedstocks will often have δ13C distinguishable from storage reservoir CO₂. Noble gases in amine-captured CO₂ streams are likely to be low concentration, with isotopic ratios dependant on the feedstock, but CO₂ captured from oxyfuel plants may be strongly enriched in Kr and Xe which are potentially valuable subsurface tracers. CO₂ streams derived from fossil fuels will have noble gas isotope ratios reflecting a radiogenic component that will be difficult to distinguish in the storage reservoir, but inheritance of radiogenic components will provide an easily recognisable signature in the case of any unplanned migration into shallow aquifers or to the surface
Phytosociological characterization of weeds as a function of residual herbicides applied to rice grown under sprinkler irrigation.
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Control of Jointvetch (Aeschynomene spp.), Establishment and Productivity of Rice as a Function of [Imazapic + Imazapyr] Doses.
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Exchange Interactions and High-Energy Spin States in Mn_12-acetate
We perform inelastic neutron scattering measurements on the molecular
nanomagnet Mn_12-acetate to measure the excitation spectrum up to 45meV (500K).
We isolate magnetic excitations in two groups at 5-6.5meV (60-75K) and
8-10.5meV (95-120K), with higher levels appearing only at 27meV (310K) and
31meV (360K). From a detailed characterization of the transition peaks we show
that all of the low-energy modes appear to be separate S = 9 excitations above
the S = 10 ground state, with the peak at 27meV (310K) corresponding to the
first S = 11 excitation. We consider a general model for the four exchange
interaction parameters of the molecule. The static susceptibility is computed
by high-temperature series expansion and the energy spectrum, matrix elements
and ground-state spin configuration by exact diagonalization. The theoretical
results are matched with experimental observation by inclusion of cluster
anisotropy parameters, revealing strong constraints on possible parameter sets.
We conclude that only a model with dominant exchange couplings J_1 ~ J_2 ~
5.5meV (65K) and small couplings J_3 ~ J_4 ~ 0.6meV (7K) is consistent with the
experimental data.Comment: 17 pages, 12 figure
Regulating human interventions in Colombian coastal areas: Implications for the environmental licensing procedure in middle-income countries
Although anthropogenic impacts could be assessed in any environment, coastal areas pose a particular challenge because of their special nature as the interface between land and sea. Therefore, this study evaluates the environmental regulatory framework for coastal interventions in Colombia, as an archetype of medium income countries (MICs), to derive implications for the environmental licensing procedure (ELP). The methods comprised two simultaneous pathways: a. An inventory of human interventions at the large scale area of the Colombian Caribbean Coast, with an estimation of the overall environmental impact; b. An analysis of the ELP in Colombia during the last 25 years. The study evidences several weaknesses, such as a consistent reduction in the number of works and activities covered in each new legislative. Moreover, the Colombian ELP currently regulates only four of the ten types of interventions with greater effect in its coastal zones. The discussions highlight some policy implications for the ELP in MICs, mainly based on how the impact of a type of intervention can be magnified in proportion to its frequency of occurrence, and the need to articulate instruments of environmental management and territorial planning. At last, the need to evolve the impact assessment of human interventions from environmental factors toward socio-natural processes is evidenced and further addressed, by the introduction of a susceptibility approach inspired on geomorphological processes. Overall, this study highlights important gaps of the Colombian ELP for coastal environments, which entails valuable lessons for MICs
Chirality in Bare and Passivated Gold Nanoclusters
Chiral structures have been found as the lowest-energy isomers of bare
(Au and Au_{28}(SCH_{16}_{38}(SCH_{3})_{24}) gold nanoclusters. The degree of chirality existing in
the chiral clusters was calculated using the Hausdorff chirality measure. We
found that the index of chirality is higher in the passivated clusters and
decreases with the cluster size. These results are consistent with the observed
chiroptical activity recently reported for glutahione-passivated gold
nanoclusters, and provide theoretical support for the existence of chirality in
these novel compounds.Comment: 5 pages, 1 figure. Submitted to PR
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