74 research outputs found
Current state of the Prunetalia spinosae communities in the centre and south of the Iberian Peninsula (Spain, Portugal)
This paper re-examines the Rhamno-Prunetea class in the centre and south of the Iberian Peninsula, especially
in Andalusia. The paper also deals with the alliances Pruno-Rubion ulmifolii Lonicero-Berberidion hispanicae in the
south of the Iberian Peninsula, and Berberidion vulgaris (Berberidenion seroi) in the area of Cuenca. Our analysis of
225 relevés arranged in 22 phytosociological tables helped us to re-organize the available information and subsequently
propose three associations and two subassociations: Clematido vitalbae-Rosetum micranthae nova; Berberido hispanicae-
Buxetum sempervirentis nova; Roso siculae-Berberidetum hispanicae Mota nova subas. prunetosum ramburii Mota
nova; Lonicero arboreae-Rhamnetum cathartici Martínez-Parras and Molero 1983 subas. prunetosum ranburii nova. As
a result of the study, a total of 18 syntaxa with the rank of association and four with the rank of subassociation are proposed
for the south of the Iberian Peninsula
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Predicting Cu and Zn sorption capacity of biochar from feedstock C/N ratio and pyrolysis temperature
Biochars have been proposed for remediation of metal-contaminated water due to their low cost, high surface area and high sorption capacity for metals. However, there is a lack of understanding over how feedstock material and pyrolysis conditions contribute to the metal sorption capacity of biochar. We produced biochars from 10 different organic materials by pyrolysing at 450 °C and a further 10 biochars from cedar wood by pyrolysing at 50 °C intervals (250–700 °C). Batch sorption experiments were conducted to derive the maximum Cu and Zn sorption capacity of each biochar. The results revealed an exponential relationship between Cu and Zn sorption capacity and the feedstock C/N ratio and a sigmoidal relationship between the pyrolysis temperature and the maximum Cu and Zn sorption capacity. FTIR analysis revealed that as temperature increased, the abundance of functional groups reduced. We conclude that the high sorption capacity of high temperature biochars is due to an electrostatic attraction between positively charged Cu and Zn ions and delocalised pi-electrons on the greater surface area of these biochars. These findings demonstrate a method for predicting the maximum sorption capacity of a biochar based on the feedstock C/N ratio and the pyrolysis temperature
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Effect of biochar on micronutrient availability and uptake into leafy greens in two urban tropical soils with contrasting soil pH
Biochars have been proposed as a novel biotechnology to increase crop yields in acidic soils due to a liming effect. However, the application of biochar to soils with a neutral soil pH is less likely to improve yield. A rise in pH typically increases the availability of macronutrients (e.g. PO43-, NO3-) but biochar is known to immobilize some elements due to a pH increase and adsorption on the biochar surface. Therefore, biochar application may reduce the uptake of important micronutrients (e.g. Cu, Fe, and Zn) into the edible portions of food crops. Before recommending indiscriminate biochar application to tropical soils, an understanding of the potentially negative impacts of biochar application to contrasting soil types should be fully appreciated to prevent unintended consequences. Our aim was to determine the impact of biochar amendment to an acidic soil and a neutral soil on micronutrient availability and uptake into leafy greens. We produced biochars from 3 different organic feedstock materials (corn cobs, rice husk and teak sawdust) and applied these in pot experiments to an acidic tropical soil (pH 4.5) and a neutral tropical soil (pH 6.9) collected from urban farms in Tamale and Kumasi, respectively, in Ghana. We grew leafy greens (Amaranthus, Corchorus, and Lettuce) and measured their growth and the uptake of Cu, Fe, and Zn , alongside supporting measurements of soil pH and micronutrient availability in the soil. We also measured water soluble Cu, Fe, and Zn in the soils amended with biochars pyrolyzed at different temperatures. The corn cobs biochar increased soil pH and considerably increased plant growth in the acidic soil from Tamale. In the neutral soil from Kumasi we found that, while corn cob biochar increased soil pH, rice husk biochar decreased soil pH. Furthermore, corn cob biochar considerably reduced plant growth in the neutral soil. The concentration of micronutrients in the edible portions of leafy greens was not greatly affected by biochar application, but the total uptake (i.e. concentration multiplied by biomass) of micronutrients into leaves was generally increased by biochar application in the acidic (Tamale) soil and application of the corn cob biochar generally decreased total uptake of micronutrients in the neutral (Kumasi) soil. Our results highlight the need for site-specific information on biochar feedstock and soil pH prior to recommending biochar application to tropical urban soils so that the benefits can be optimized and unintended consequences can be prevented
Magnetoplasmonics: Combining Magnetic and Plasmonic Functionalities
Comunicación presentada en el 3rd European Workshop on Self Organized Nanomagnets, celebrado en Guadarrama del 16 al 20 de abril de 2012.Nanosystems
with
combined
magnetic
and
plasmonic
functionalities
have
in
recent
years
become
an
active
topic
of
research.
In
these
new
stn-lctures,
know
as
magneto-plasmonics,
magnetic
and
plasmonic
properties
are
interlwined,
allowing
for
example
plasmonic
properties
to
become
tunable
upon
de
application
of
a
magnetic
field
(active
plasmonics),
or
the
Magneto*Optical
(MO)
effects
to
be
largely
increased
by
plasmon
resonance
excitation,
as
a
consequence
of
the
enhancement
of
the
electromagnetic
(EM)
field
in
the
MO
active
component
of
the
structure.
ln
this
last
case,
the
study
of
the
enhanced
MO
activity
in
structures
with
subwavelength
dimensions
is
especially
interesting
since
they
may
be
viewed
as
nanoantennas
in
the
visible
range
with
MO
functionalities.
The
light
harvesting
properties
of
these
systems
upon
plasmon
resonance
excitation
bring
as
a
consequence
an
enhanced
EM
field
in
its
interior,
and
more
interestingly
in
the
region
where
the
MO
active
component
is
present.
At
this
stage,
optimizing
the
EM
field
distribution
within
the
structure
by
maximizing
it
in
the
MO
components
region
while
simultaneously
minimizingit
in
all
the
other,
non
MO
active,
lossy
components,
will
allow
for
the
development
of
novel
systems
with
even
larger
MO
activity
with
reduced
optical
losses .Peer Reviewe
Influence of Menstrual Cycle Length and Age at Menarche on Symptoms, Cognition, Social Cognition, and Metacognition in Patients with First-Episode Psychosis
Altres ajuts: PERIS call (grant no. SLT006/17/00231); the Progress and Health Foundation of the Andalusian Regional Ministry of Health (grant no. PI-0634/2011 and PI-0193/2014); Obra Social La Caixa (RecerCaixa call 2013); CERCA Programme/Generalitat de Catalunya; Obra Social Sant Joan de Déu (BML); and FI19/00062 (Ayudas para la Contratación de Personal Predoctoral).A protective effect has traditionally been attributed to estrogen in psychotic disorders. The aim of this study was to investigate cumulative lifetime estrogen by assessing the menstrual cycle length, age at menarche, and years of difference between the onset of psychotic symptoms and the age of menarche, measuring their effects on symptoms, cognition, social cognition, and metacognition. As it was not possible to directly measure cumulative estrogen levels over the lifetime of a patient, the study sample was composed of 42 women with first-episode psychosis; estrogen levels were inferred by the menstrual cycle length, age at menarche, and years of difference between the onset of psychotic symptoms and menarche. All patients were assessed with a battery of questionnaires using the BDI, PSYRATS, PANSS, STROOP, TAVEC, WSCT, IPSAQ, and BCIS questionnaires. The results related to menstrual cycle length showed a relationship with memory; specifically, shorter cycles with semantic strategies (p = 0.046) and longer cycles with serial strategies in the short term (p = 0.005) as well as in the long term (p = 0.031). The results also showed a relationship with perseverative errors (p = 0.035) and self-certainty (p = 0.049). Only personalized bias (p = 0.030) was found to be significant in relation to the age at menarche. When analyzing the differences in years of difference between the age at menarche and the onset of psychotic symptoms, the results indicated lower scores in women with a smaller difference between both events in memory (short-term (p = 0.050), long-term (p = 0.024), intrusions (p = 0.013), and recognition (p = 0.043)) and non-perseverative errors (p = 0.024). No relationship was found between symptoms and menstrual characteristics. The investigatory outcomes seem to indicate a relationship between estrogen cumulative effects and the memory domain. More in-depth investigations in the field are necessary in order to improve personalized treatment in women with psychosis
Optimizing light harvesting for high magneto-optical performance in metal and metal-dielectric magnetoplasmonic nanodiscs
Póster presentado en Nanolight, celebrado en Benasque (España).Magnetoplasmonics deals with the study of materials and/or phenomena involving both plasmonic and magneto-optical (MO) properties. A two-way path connects both properties: the MO response of the system can be modified by the presence of plasmon resonances and the plasmons properties can be modulated by means of an applied
magnetic field. Here we focus on the first path, in particular on the MO activity enhancement in nano-discs due to the excitation of localized surface plasmons (LSP).EU (NMP3-SL-2008-214107-Nanomagma), Spanish Ministry (“FUNCOAT” CONSOLIDER INGENIO 2010 CSD2008-00023, MAGPLAS MAT2008-06765-C02-01/NAN, PLASMAR MAT2010-10123-E, and MAPS MAT2011-29194-C02-01), Comunidad de Madrid (“NANOBIOMAGNET”, S2009/MAT-1726 and >MICROSERES-CM”, S2009/TIC-1476), and CSIC/FSE (JAE-Doc fellowship for D. Meneses-Rodríguez, and JAE-Predoc fellowship for E. Ferreiro-Vila).Peer Reviewe
Comprehensive cross-platform comparison of methods for non-invasive EGFR mutation testing : results of the RING observational trial.
Abstract Several platforms for noninvasive EGFR testing are currently used in the clinical setting with sensitivities ranging from 30% to 100%. Prospective studies evaluating agreement and sources for discordant results remain lacking. Herein, seven methodologies including two next-generation sequencing (NGS)-based methods, three high-sensitivity PCR-based platforms, and two FDA-approved methods were compared using 72 plasma samples, from EGFR-mutant non-small-cell lung cancer (NSCLC) patients progressing on a first-line tyrosine kinase inhibitor (TKI). NGS platforms as well as high-sensitivity PCR-based methodologies showed excellent agreement for EGFR-sensitizing mutations (K = 0.80-0.89) and substantial agreement for T790M testing (K = 0.77 and 0.68, respectively). Mutant allele frequencies (MAFs) obtained by different quantitative methods showed an excellent reproducibility (intraclass correlation coefficients 0.86-0.98). Among other technical factors, discordant calls mostly occurred at mutant allele frequencies (MAFs) ≤ 0.5%. Agreement significantly improved when discarding samples with MAF ≤ 0.5%. EGFR mutations were detected at significantly lower MAFs in patients with brain metastases, suggesting that these patients risk for a false-positive result. Our results support the use of liquid biopsies for noninvasive EGFR testing and highlight the need to systematically report MAFs. Keywords: NGS; circulating free DNA; epidermal growth factor receptor; non-small-cell lung cancer; osimertinib; tyrosine kinase inhibitor
Role of age and comorbidities in mortality of patients with infective endocarditis
[Purpose]: The aim of this study was to analyse the characteristics of patients with IE in three groups of age and to assess the ability of age and the Charlson Comorbidity Index (CCI) to predict mortality.
[Methods]: Prospective cohort study of all patients with IE included in the GAMES Spanish database between 2008 and 2015.Patients were stratified into three age groups:<65 years,65 to 80 years,and ≥ 80 years.The area under the receiver-operating characteristic (AUROC) curve was calculated to quantify the diagnostic accuracy of the CCI to predict mortality risk.
[Results]: A total of 3120 patients with IE (1327 < 65 years;1291 65-80 years;502 ≥ 80 years) were enrolled.Fever and heart failure were the most common presentations of IE, with no differences among age groups.Patients ≥80 years who underwent surgery were significantly lower compared with other age groups (14.3%,65 years; 20.5%,65-79 years; 31.3%,≥80 years). In-hospital mortality was lower in the <65-year group (20.3%,<65 years;30.1%,65-79 years;34.7%,≥80 years;p < 0.001) as well as 1-year mortality (3.2%, <65 years; 5.5%, 65-80 years;7.6%,≥80 years; p = 0.003).Independent predictors of mortality were age ≥ 80 years (hazard ratio [HR]:2.78;95% confidence interval [CI]:2.32–3.34), CCI ≥ 3 (HR:1.62; 95% CI:1.39–1.88),and non-performed surgery (HR:1.64;95% CI:11.16–1.58).When the three age groups were compared,the AUROC curve for CCI was significantly larger for patients aged <65 years(p < 0.001) for both in-hospital and 1-year mortality.
[Conclusion]: There were no differences in the clinical presentation of IE between the groups. Age ≥ 80 years, high comorbidity (measured by CCI),and non-performance of surgery were independent predictors of mortality in patients with IE.CCI could help to identify those patients with IE and surgical indication who present a lower risk of in-hospital and 1-year mortality after surgery, especially in the <65-year group
El abrigo y la cueva de Benzú en la Prehistoria de Ceuta. Aproximación al estudio de las sociedades cazadoras-recolectoras y tribales comunitarias en el ámbito norteafricano del Estrecho de Gibraltar.
Extensa obra sobre los métodos, antecedentes y objetivos; observaciones preliminares y estudios anteriores, excavación y análisis de los resultados del Proyecto Benzú.Consejería de Educación, Cultura y Deporte de la Ciudad Autónoma de Ceuta.
Universidad Española de Educación a Distancia.
Universidad de Cádiz.419 página
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