Control of sedimentation by active tectonics, glaciation and contourite-depositing currents in Endurance Basin, South Georgia

Endurance Basin is an elongate broadly WNW-ESE trending basin located on the northern margin of the Scotia Sea, adjacent to the southern margin of the South Georgia micro-continent. Bathymetric and TOPAS sub-bottom profile data acquired in 2010 by the British research ship RRS James Clark Ross map this basin and its sedimentology for the first time. Endurance Basin contains a number of sub-basins and a substantial glaciogenic fan. The northern margin of Endurance Basin is formed by a series of steep slopes and intervening troughs. These are interpreted as a left-stepping en echelon array of oblique, strike-slip faults whilst the sub-basins are separated by compressional dip-slip faults. It appears that South Georgia is moving NW with respect to the basin. We interpret five seismic facies from TOPAS data, which are associated with distinct sedimentologies. The most striking units in the basin fill are: substantial contourite drifts located in the NW of the basin and on its southern margin; and two distinct mass transport deposits that pond in the centre of the basin. Combined with the known regional oceanographic setting, the contourites provide evidence of broadly eastward flowing bottom currents, entering the basin from at least two locations. Although landslide scars are present on the steep northern basin margin, the imaged mass transport deposits are interpreted to have been sourced from the glaciogenic fan, located in the SE of the basin, and from a contourite unit located on the basin’s southern margin. Sediments from these events are transported at least 40 km. The contourite drift sequence is at least 100 m thick in the west of the basin and may contain a palaeoenvironmental archive of Antarctic Cirumpolar Current (ACC) flow and the climate of South Georgia extending to the Pliocene. Such an archive would allow reconstruction of ACC flow through the Pleistocene glaciations and provide a means of linking ocean circulation and climate records in the sub-Antarctic Polar Front region

Electrochemical Benzylic C(sp3)−H Acyloxylation

[Image: see text] The development of sustainable C(sp(3))–H functionalization methods is of great interest to the pharmaceutical and agrochemical industries. Anodic oxidation is an efficient means of producing benzylic cations that can undergo subsequent in situ nucleophilic attack to afford functionalized benzylic products. Herein, we demonstrate the suitability of carboxylic acids as nucleophiles to yield benzylic esters. This method employs a series of secondary benzylic substrates and functionalized carboxylic acids and is demonstrated on a gram scale in flow

Bathymetry and geological setting of the South Sandwich Islands volcanic arc

The South Sandwich Islands and associated seamounts constitute the volcanic arc of an active subduction system situated in the South Atlantic. We introduce a map of the bathymetry and geological setting of the South Sandwich Islands and the associated East Scotia Ridge back-arc spreading centre that consists of two sides: side 1, a regional overview of the volcanic arc, trench and back-arc, and side 2, detailed maps of the individual islands. Side 1 displays the bathymetry at scale 1:750 000 of the intra-oceanic, largely submarine South Sandwich arc, the back-arc system and other tectonic boundaries of the subduction system. Satellite images of the islands on side 2 are at scales of 1:50 000 and 1:25 000 with contours and main volcanological features indicated. These maps are the first detailed topological and bathymetric maps of the area. The islands are entirely volcanic in origin, and most have been volcanically or fumarolically active in historic times. Many of the islands are ice-covered, and the map forms a baseline for future glaciological changes caused by volcanic activities and climate change. The back-arc spreading centre consists of nine segments, most of which have rift-like morphologie

Growth and mass wasting of volcanic centers in the northern South Sandwich arc, South Atlantic, revealed by new multibeam mapping

New multibeam (swath) bathymetric sonar data acquired using an EM120 system on the RRS James Clark Ross, supplemented by sub-bottom profiling, reveals the underwater morphology of a not, vert, similar 12,000 km2 area in the northern part of the mainly submarine South Sandwich volcanic arc. The new data extend between 55° 45′S and 57° 20′S and include Protector Shoal and the areas around Zavodovski, Visokoi and the Candlemas islands groups. Each of these areas is a discrete volcanic center. The entirely submarine Protector Shoal area, close to the northern limit of the arc, forms a 55 km long east–west-trending seamount chain that is at least partly of silicic composition. The seamounts are comparable to small subaerial stratovolcanoes in size, with volumes up to 83 km3, indicating that they are the product of multiple eruptions over extended periods. Zavodovski, Visokoi and the Candlemas island group are the summits of three 3–3.5 km high volcanic edifices. The bathymetric data show evidence for relationships between constructional volcanic features, including migrating volcanic centers, structurally controlled constructional ridges, satellite lava flows and domes, and mass wasting of the edifices. Mass wasting takes place mainly by strong erosion at sea level, and dispersal of this material along chutes, probably as turbidity currents and other mass flows that deposit in extensive sediment wave fields. Large scale mass wasting structures include movement of unconsolidated debris in slides, slumps and debris avalanches. Volcanism is migrating westward relative to the underlying plate and major volcanoes are asymmetrical, being steep with abundant recent volcanism on their western flanks, and gently sloping with extinct, eroded volcanic sequences to their east. This is consistent with the calculated rate of subduction erosion of the fore-arc

InterPro in 2011: new developments in the family and domain prediction database

InterPro (http://www.ebi.ac.uk/interpro/) is a database that integrates diverse information about protein families, domains and functional sites, and makes it freely available to the public via Web-based interfaces and services. Central to the database are diagnostic models, known as signatures, against which protein sequences can be searched to determine their potential function. InterPro has utility in the large-scale analysis of whole genomes and meta-genomes, as well as in characterizing individual protein sequences. Herein we give an overview of new developments in the database and its associated software since 2009, including updates to database content, curation processes and Web and programmatic interface

Effects of antiplatelet therapy on stroke risk by brain imaging features of intracerebral haemorrhage and cerebral small vessel diseases: subgroup analyses of the RESTART randomised, open-label trial

Background Findings from the RESTART trial suggest that starting antiplatelet therapy might reduce the risk of recurrent symptomatic intracerebral haemorrhage compared with avoiding antiplatelet therapy. Brain imaging features of intracerebral haemorrhage and cerebral small vessel diseases (such as cerebral microbleeds) are associated with greater risks of recurrent intracerebral haemorrhage. We did subgroup analyses of the RESTART trial to explore whether these brain imaging features modify the effects of antiplatelet therapy