Impact of substrate defects on the equilibrium one-dimensional island size distribution

As long as only first-neighbour interactions are considered, equilibrium island size distributions of monoatomic islands in one dimension follow an exponential law regardless of the strength and the repulsive or attractive character of the adsorbate–adsorbate interactions. However, one- dimensional atomic wires obtained via nucleation at the step edges have a monomodal island size distribution. In this paper, we present a simple one- dimensional Monte Carlo model that shows how the monomodal distribution observed experimentally can be obtained by including surface defects that only suppress the interaction between two successive adsorbates.Fil: Mirabella, D. A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Aldao, Celso Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentin

Los ferroviarios y el primer peronismo. Reflexiones teóricas en torno a los conceptos de identificación política e institucionalidad populista

The article analyzes the way in which the railway workers, nucleated in the Railway Union, develop the identification process with the first Peronism. Two theoretical issues are central to the analysis. The first is to define, within the framework of the process of forming a new political identity, how to articulate a sedimented identity (railway identity) and institutionally mediated, with the nascent Peronism. The second is, after describing the subjective link between the “railway us” and the union institution, to develop and analyze the specific characteristics of the institutionality that derives from this particular link, at the moment of articulating with the nascent Peronist identity. As a result, a definition of populist institutionality is tested and the hypothesis that this institutionality characterizes the process of institutionalization of political-union relations that is consolidated in this period is elaborated.El artículo analiza el modo en que los trabajadores ferroviarios, nucleados en la Unión Ferroviaria, desarrollan el proceso de identificación con el primer peronismo. Dos cuestiones teóricas son centrales para el análisis. La primera es definir, en el marco del proceso de formación de una nueva identidad política, como se articula una identidad sedimentada (identidad ferroviaria) y mediada institucionalmente, con el naciente peronismo. La segunda es, luego de describir el vínculo subjetivo entre el “nosotros ferroviario” y la institución sindical, desarrollar y analizar las características específicas de la institucionalidad que deriva de este particular vínculo, al momento de articularse con la naciente identidad peronista. Como resultado, se ensaya una definición de institucionalidad populista y se elabora la hipótesis de que, esta institucionalidad, caracteriza el proceso de institucionalización de las relaciones político-sindicales que se consolida en este período

Schiavi, Marcos (2013), El poder sindical en la Argentina peronista (1946-1955).

Reseña de  El poder sindical en la Argentina peronista (1946-1955)

The hinge morphology of SnO2 as multifunctional semiconductor: What we can learn from simulations, theory, and experiments

Our interaction with materials occurs through their surfaces whose properties are strongly dependent on morphology, structure, and atomic arrangement. Unfortunately, obtaining a detailed correlation between the surface morphology with its properties is not straightforward. SnO2 is a multifunctional semiconductor ceramic that is exploited in several technological devices from sensor to energy storage, water splitting, and solar to fuel photocatalysis. This work focused on the structural, energetic, and electronic properties of low and high index surfaces of SnO2 semiconductor and assessed the morphology-dependent process via first-principles calculations, at the density functional theory level. Importantly, our explicitly dynamic approach elucidates the atomic arrangements and stability of the exposed surfaces to provide a close match between experimental field emission scanning electron microscopy images and computational simulation. These findings can potentially set a foundation for establishing synthesis techniques for drive the morphology evolution through the control of temperature/pressure, and/or based on surface interactions of the selective adsorption of solvents/surfactants.This work was supported by Generalitat Valenciana, Universitat Jaume I, and São Paulo Research Foundation (FAPESP, grant number 2013/07296-2 and 2022/08048-1). A.F.G. acknowledges the Generalitat Valenciana (Conselleria de Innovación, Universidades, Ciencia y Sociedad Digital) for the postdoctoral contract (CIAPOS/2021/106) and Universitat Jaume I for the funding though its Research Stay Grants (E-2022-05). J.A. acknowledges Universitat Jaume I (project UJI-B2019-30), and Generalitat Valenciana (Conselleria de Innovación, Universidades, Ciencia y Sociedad Digital – project CIAICO/2021/122) for financially supporting this research

Thinking about feeling: using trait emotional intelligence in understanding the associations between early maladaptive schemas and coping styles

Objectives: Maladaptive interpersonal schemas can trigger distressing emotions and drive dysfunctional behaviour that leads to difficulties in interpersonal relationships and perpetuates the original maladaptive schemas. This study sought to identify patterns of association between trait emotional intelligence (TEI), early maladaptive schemas (EMS), and coping styles in a non‐clinical sample. Emotionality profiles were hypothesized to be associated with EMS severity and poorer coping, as early experiences can shape an individual's self‐perceptions through reinforcement by maladaptive responses. Design: Cross‐sectional study with 142 undergraduate students. Methods: We obtained self‐reports of TEI, coping styles, and EMS. Results: Disengagement coping was strongly correlated with EMS severity (r = .565, p < .01). TEI was negatively correlated with EMS (r = −.660, p < .01) and Disengagement (r = −.405, p < .01). Emotionality, Impaired Autonomy, and Overvigilance partially mediated the relationship between Disconnection and Emotion‐Focused Disengagement. Self‐Control fully mediated the relationship between Impaired Limits and Problem‐Focused Disengagement. Conclusions: The findings suggest that lower TEI is associated with the likelihood for maladaptive coping in response to EMS. The preference for certain coping styles associated with a particular domain of EMS may be explained by an individual's perceived metacognitive ability to regulate their stress and emotions. When individuals’ needs for love, safety, and acceptance from others are not met, there might be poorer perceived self‐efficacies in Emotionality and the tendency to cope through emotional avoidance. Individuals with difficulties establishing internal limits are more likely to respond with problem avoidance, possibly due to deficient distress tolerance. Longitudinal studies with a clinical population are warranted to replicate these findings

Experimental and ab Initio Studies of Deep-Bulk Traps in Doped Rare-Earth Oxide Thick Films

Lanthanum-doped CeO2 is a promising semiconductor for gas sensing. A combined study applying impedance spectroscopy and first-principles calculations was performed for pure and lanthanum-doped samples. The results showed a strong influence of the localized Ce 4f states on the electrical conduction processes and an electrical resistance increase as a function of the exposure to vacuum and air atmospheres. After its modification with a rare-earth element along with exposure to reducing and oxidizing atmospheres, the observed behavior suggested the presence of multitraps, which depended on the described equilibrium between the oxygen vacancies (Vo x ↔ VO· ↔ VO· ) in a disordered deep-bulk trap location. According to the DFT results, the multitraps were formed with the creation of an oxygen vacancy far from the doping atom. They were considered to be responsible for the phenomena modifying the Debye-like response. The transfer of electrons from Ce(III) to the adsorbed oxygen species, decreasing the number of electrons in the 4f state, reduced the electrical conductivity by the hopping frequency dependence of the total resistance and capacitances. This was probably due to the interactions between defective oxygen and metallic species.Fil: Silva Rosa Rocha, Leandro. Universidade Federal do São Carlos; BrasilFil: Schipani, Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Aldao, Celso Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Cabral, Luís A.. Universidade Federal do São Carlos; BrasilFil: Simoes, Alexandre Z.. Faculdade de Engenharia de Guaratinguetá, Unesp; BrasilFil: Macchi, Carlos Eugenio. Universidad Nacional del Centro de la Provincia de Buenos Aires.. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnologico Conicet - Tandil. Sede Tandil del Centro de Investigaciones En Fisica E Ingenieria del Centro de la Provincia de Buenos Aires.; ArgentinaFil: Marques, Gilmar Eugenio. Universidade Federal do São Carlos; BrasilFil: Ponce, Miguel Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Longo, Elson. Universidade Federal do São Carlos; Brasi

Unconventional MBE Strategies from Computer Simulations for Optimized Growth Conditions

We investigate the influence of step edge diffusion (SED) and desorption on Molecular Beam Epitaxy (MBE) using kinetic Monte-Carlo simulations of the solid-on-solid (SOS) model. Based on these investigations we propose two strategies to optimize MBE growth. The strategies are applicable in different growth regimes: During layer-by-layer growth one can exploit the presence of desorption in order to achieve smooth surfaces. By additional short high flux pulses of particles one can increase the growth rate and assist layer-by-layer growth. If, however, mounds are formed (non-layer-by-layer growth) the SED can be used to control size and shape of the three-dimensional structures. By controlled reduction of the flux with time we achieve a fast coarsening together with smooth step edges.Comment: 19 pages, 7 figures, submitted to Phys. Rev.

Towards the Physical Map of the Trypanosoma cruzi Nuclear Genome: Construction of YAC and BAC Libraries of the Reference Clone T. cruzi CL-Brener

Strategies to construct the physical map of the Trypanosoma cruzi nuclear genome have to capitalize on three main advantages of the parasite genome, namely (a) its small size, (b) the fact that all chromosomes can be defined, and many of them can be isolated by pulse field gel electrophoresis, and (c) the fact that simple Southern blots of electrophoretic karyotypes can be used to map sequence tagged sites and expressed sequence tags to chromosomal bands. A major drawback to cope with is the complexity of T. cruzi genetics, that hinders the construction of a comprehensive genetic map. As a first step towards physical mapping, we report the construction and partial characterization of a T. cruzi CL-Brener genomic library in yeast artificial chromosomes (YACs) that consists of 2,770 individual YACs with a mean insert size of 365 kb encompassing around 10 genomic equivalents. Two libraries in bacterial artificial chromosomes (BACs) have been constructed, BACI and BACII. Both libraries represent about three genome equivalents. A third BAC library (BAC III) is being constructed. YACs and BACs are invaluable tools for physical mapping. More generally, they have to be considered as a common resource for research in Chagas diseaseInstituto de Investigaciones en Ingeniería Genética y Biología MolecularEscola Paulista de MedicinaCBMUniversidade de São PauloUniversidade Federal do Rio de JaneiroIPBUniversidad Central de VenezuelaUSBInstituto Oswaldo CruzCEPHUNIFESP, EPMSciEL