Science Opportunities offered by Mercury's Ice-Bearing Polar Deposits

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Isotopic constraints on the source of Pluto's nitrogen and the history of atmospheric escape

International audienceThe origin and evolution of nitrogen in solar system bodies is an important question for understanding processes that took place during the formation of the planets and solar system bodies. Pluto has an atmosphere that is 99% molecular nitrogen, but it is unclear if this nitrogen is primordial or derived from ammonia in the protosolar nebula. The nitrogen isotope ratio is an important tracer of the origin of nitrogen on solar system bodies, and can be used at Pluto to determine the origin of its nitrogen. After evaluating the potential impact of escape and photochemistry on Pluto's nitrogen isotope ratio (N-14/N-15), we find that if Pluto's nitrogen originated as N-2 the current ratio in Pluto's atmosphere would be greater than 324 while it would be less than 157 if the source of Pluto's nitrogen were NH3. The New Horizons spacecraft successfully visited the Pluto system in July 2015 providing a potential opportunity to measure N-14/N-15 in N-2. (C) 2016 The Authors. Published by Elsevier Ltd

Surface Volatile Composition as Evidence for Hydrothermal Processes Lasting Longer in Triton’s Interior than Pluto’s

Ocean worlds, or icy bodies in the outer solar system that have or once had subsurface liquid water oceans, are among the most compelling topics of astrobiology. Typically, confirming the existence of a subsurface ocean requires close spacecraft observations. However, combining our understanding of the chemistry that takes place in a subsurface ocean with our knowledge of the building blocks that formed potential ocean worlds provides an opportunity to identify tracers of endogenic activity in the surface volatiles of Pluto and Triton. We show here that the current composition of the volatiles on the surfaces and in the atmospheres of Pluto and Triton are deficient in carbon, which can only be explained by the loss of CH _4 through a combination of aqueous chemistry and atmospheric processes. Furthermore, we find that the relative nitrogen and water abundances are within the range observed in building block analogs, comets, and chondrites. A lower limit for N/Ar in Pluto’s atmosphere also suggests source building blocks that have a cometary or chondritic composition, all pointing to an origin for their nitrogen as NH _3 or organics. Triton’s lower abundance of CH _4 compared to Pluto, and the detection of CO _2 at Triton but not at Pluto points to aqueous chemistry in a subsurface ocean that was more efficient at Triton than Pluto. These results have applications to other large Kuiper Belt objects as well as the assessment of formation locations and times for the four giant planets given future probe measurements of noble gas abundances and isotope ratios

Cold Traps of Hypervolatiles in the Protosolar Nebula at the Origin of the Peculiar Composition of Comet C/2016 R2 (PanSTARRS)

International audienceRecent observations of the long-period comet C/2016 R2 (PanSTARRS; hereafter R2) indicate an unusually high N2/CO abundance ratio, typically larger than ∼0.05, and at least 2–3 times higher than the one measured in 67P/Churyumov–Gerasimenko. Another striking compositional feature of this comet is its heavy depletion in H2O (H2O/CO ∼ 0.32%), compared to other comets. Here we investigate the formation circumstances of a generic comet whose composition reproduces these two key features. We first envisage the possibility that this comet agglomerated from clathrates, but we find that such a scenario does not explain the observed low water abundance. We then alternatively investigate the possibility that the building blocks of R2 agglomerated from grains and pebbles made of pure condensates via the use of a disk model describing the radial transport of volatiles. We show that N2/CO ratios reproducing the value estimated in this comet can be found in grains condensed in the vicinity of the CO and N2 ice lines. Moreover, high CO/H2O ratios (>100 times the initial gas-phase value) can be found in grains condensed in the vicinity of the CO ice line. If the building blocks of a comet assembled from such grains, they should present N2/CO and CO/H2O ratios consistent with the measurements made in R2's coma. Our scenario indicates that R2 formed in a colder environment than the other comets that share more usual compositions. Our model also explains the unusual composition of the interstellar comet 2l/Borisov

Tracing the Origins of the Ice Giants through Noble Gas Isotopic Composition

;The current composition of giant planet atmospheres provides information on how such planets formed, and on the origin of the solid building blocks that contributed to their formation. Noble gas abundances and their isotope ratios are among the most valuable pieces of evidence for tracing the origin of the materials from which the giant planets formed. In this review we first outline the current state of knowledge for heavy element abundances in the giant planets and explain what is currently understood about the reservoirs of icy building blocks that could have contributed to the formation of the Ice Giants. We then outline how noble gas isotope ratios have provided details on the original sources of noble gases in various materials throughout the solar system. We follow this with a discussion on how noble gases are trapped in ice and rock that later became the building blocks for the giant planets and how the heavy element abundances could have been locally enriched in the protosolar nebula. We then provide a review of the current state of knowledge of noble gas abundances and isotope ratios in various solar system reservoirs, and discuss measurements needed to understand the origin of the ice giants. Finally, we outline how formation and interior evolution will influence the noble gas abundances and isotope ratios observed in the ice giants today. Measurements that a future atmospheric probe will need to make include (1) the <sup>3</sup>He/<sup>4</sup>He isotope ratio to help constrain the protosolar D/H and <sup>3</sup>He/<sup>4</sup>He; (2) the <sup>20</sup>Ne/<sup>22</sup>Ne and <sup>21</sup>Ne/<sup>22</sup>Ne to separate primordial noble gas reservoirs similar to the approach used in studying meteorites; (3) the Kr/Ar and Xe/Ar to determine if the building blocks were Jupiter-like or similar to 67P/C-G and Chondrites; (4) the krypton isotope ratios for the first giant planet observations of these isotopes; and (5) the xenon isotopes for comparison with the wide range of values represented by solar system reservoirs.</p><p>Mandt, K. E., Mousis, O., Lunine, J., Marty, B., Smith, T., Luspay-Kuti, A., & Aguichine, A. (2020). Tracing the origins of the ice giants through noble gas isotopic composition. Space Science Reviews, 216(5), 1-37.</p&gt

The presence of clathrates in comet 67P/Churyumov-Gerasimenko

International audienceCometary nuclei are considered to most closely reflect the composition of the building blocks of our solar system. As such, comets carry important information about the prevalent conditions in the solar nebula before and after planet formation. Recent measurements of the time variation of major and minor volatile species in the coma of the Jupiter family comet 67P/Churyumov-Gerasimenko (67P) by the ROSINA (Rosetta Orbiter Spectrometer for Ion and Neutral Analysis) instrument onboard Rosetta provide insight into the possible origin of this comet. The observed outgassing pattern indicates that the nucleus of 67P contains crystalline ice, clathrates, and other ices. The observed outgassing is not consistent with gas release from an amorphous ice phase with trapped volatile gases. If the building blocks of 67P were formed from crystalline ices and clathrates, then 67P would have agglomerated from ices that were condensed and altered in the protosolar nebula closer to the Sun instead of more pristine ices originating from the interstellar medium or the outskirts of the disc, where amorphous ice may dominate

Dual storage and release of molecular oxygen in comet 67P/Churyumov-Gerasimenko

All data processed as described above are included in the Article and Supplementary Information. The ROSINA/DFMS spectra used to derive count rates are available in the NASA Planetary DataSystem (https://pds-smallbodies.astro.umd.edu/data_sb/missions/rosetta/index.shtml) and ESA Planetary Science Archive (https://archives.esac.esa.int/psa/#!Table%20View/Rosetta=mission). Source data are provided with this paper.International audienceOne of the biggest surprises of the Rosetta mission was the detection of O-2 in the coma of 67P/Churyumov-Gerasimenko in remarkably high abundances. The measured levels of O-2 in the coma are generally assumed to reflect the overall abundance and chemical origin of cometary O-2 in the nucleus. Along with its strong association with H2O and weak association with CO and CO2, these measurements led to the consensus that the source and release of cometary O-2 are linked to H2O. We analysed ROSINA observations and found a previously unrecognized change in the correlations of O-2 with H2O, CO2 and CO that contradicts the prevailing notion that the release of O-2 is linked to H2O at all times. These findings can be explained by the presence of two distinct reservoirs of O-2: a pristine source in the deeper nucleus layers dating back to before nucleus formation, and an H2O-trapped secondary reservoir formed during the thermal evolution of the nucleus. These results imply that O-2 must have been incorporated into the nucleus in a solid and distinct phase during accretion in significantly lower abundances than previously assumed. Seasonal changes in the correlation between O-2 and H2O in comet 67P's coma are indicative of two reservoirs of molecular oxygen in the nucleus, a deeper primordial one and a surficial one, suggesting that the observed high abundance of O-2 and its association with H2O are not reflective of the original accretion source

Origin of the ices agglomerated by Comet 67P/Churyumov-Gerasimenko

International audienceThe nature of the icy material accreted by comets during their formation in the outer regions of the protosolar nebula is a major open question in planetary science. Some scenarios of comet formation predict that these bodies agglomerated from clathrates crystallized in the protosolar nebula. Concurrently, alternative scenarios suggest that comets accreted amorphous ice originating from the interstellar cloud. Here we show that the recent N2/CO and Ar/CO ratios measured in the coma of the Jupiter family comet 67P/Churyumov-Gerasimenko by the ROSINA instrument aboard the European Space Agency's Rosetta spacecraft can help disentangling between these two scenarios

Origin of the ices agglomerated by Comet 67P/Churyumov-Gerasimenko

International audienceThe nature of the icy material accreted by comets during their formation in the outer regions of the protosolar nebula is a major open question in planetary science. Some scenarios of comet formation predict that these bodies agglomerated from clathrates crystallized in the protosolar nebula. Concurrently, alternative scenarios suggest that comets accreted amorphous ice originating from the interstellar cloud. Here we show that the recent N2/CO and Ar/CO ratios measured in the coma of the Jupiter family comet 67P/Churyumov-Gerasimenko by the ROSINA instrument aboard the European Space Agency's Rosetta spacecraft can help disentangling between these two scenarios