3,036 research outputs found
Spreading of Latex Particles on a Substrate
We have investigated both experimentally and theoretically the spreading
behavior of latex particles deposited on solid substrates. These particles,
which are composed of cross-linked polymer chains, have an intrinsic elastic
modulus. We show that the elasticity must be considered to account for the
observed contact angle between the particle and the solid substrate, as
measured through atomic force microscopy techniques. In particular, the work of
adhesion computed within our model can be significantly larger than that from
the classical Dupr\'{e} formula.Comment: 7 pages, 7 figures, to appear in Europhys. Let
Shock waves in transonic channel flows at moderate Reynolds numbers
Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/76375/1/AIAA-9312-844.pd
Deformation of a nearly hemispherical conducting drop due to an electric field: theory and experiment
We consider, both theoretically and experimentally, the deformation due to an electric field of a pinned nearly-hemispherical static sessile drop of an ionic fluid with a high conductivity resting on the lower substrate of a parallel plate capacitor. Using both numerical and asymptotic approaches we find solutions to the coupled electrostatic and augmented Young–Laplace equations which agree very well with the experimental results. Our asymptotic solution for the drop interface extends previous work in two ways, namely to drops that have zero-field contact angles that are not exactly π/2 and to higher order in the applied electric field, and provides useful predictive equations for the changes in the height, contact angle and pressure as functions of the zero-field contact angle, drop radius, surface tension and applied electric field. The asymptotic solution requires some numerical computations, and so a surprisingly accurate approximate analytical asymptotic solution is also obtained
Where we are on : addendum to "Global neutrino data and recent reactor fluxes: status of three-flavour oscillation parameters"
In this addendum to arXiv:1103.0734 we consider the recent results from
long-baseline searches at the T2K and MINOS experiments and
investigate their implications for the mixing angle and the
leptonic Dirac CP phase . By combining the indication for a
non-zero value of coming from T2K data with global neutrino
oscillation data we obtain a significance for of about
with best fit points for normal
(inverted) neutrino mass ordering. These results depend somewhat on assumptions
concerning the analysis of reactor neutrino data.Comment: 5 pages, 2 figures and 1 tabl
The Ammount of Interstellar Carbon Locked in Solid Hydrogenated Amorphous Carbon
We review the literature and present new experimental data to determine the
amount of carbon likely to be locked in form of solid hydrogenated amorphous
carbon (HAC) grains. We conclude on the basis of a thorough analysis of the
intrinsic strength of the C-H stretching band at 3.4 micron that between 10 and
80 ppM H of carbon is in the form of HAC grains. We show that it is necessary
to know the level of hydrogenation (H/C) of the interstellar HAC to determine
more precisely the amount of carbon it ties up. We present optical constants,
photoluminescence spectroscopy, and IR absorption spectroscopy for a particular
HAC sample that is shown to have a 3.4 micron absorption feature that is
quantatively consistent with that observed in the diffuse interstellar medium.Comment: This paper is 14 pages long with 5 figures and will appear in the 1
December 1999 issue of Ap
Direct calculation of the hard-sphere crystal/melt interfacial free energy
We present a direct calculation by molecular-dynamics computer simulation of
the crystal/melt interfacial free energy, , for a system of hard
spheres of diameter . The calculation is performed by thermodynamic
integration along a reversible path defined by cleaving, using specially
constructed movable hard-sphere walls, separate bulk crystal and fluid systems,
which are then merged to form an interface. We find the interfacial free energy
to be slightly anisotropic with = 0.62, 0.64 and
0.58 for the (100), (110) and (111) fcc crystal/fluid
interfaces, respectively. These values are consistent with earlier density
functional calculations and recent experiments measuring the crystal nucleation
rates from colloidal fluids of polystyrene spheres that have been interpreted
[Marr and Gast, Langmuir {\bf 10}, 1348 (1994)] to give an estimate of
for the hard-sphere system of , slightly lower
than the directly determined value reported here.Comment: 4 pages, 4 figures, submitted to Physical Review Letter
Effect of Particle Size on Droplet Infiltration into Hydrophobic Porous Media As a Model of Water Repellent Soil
The wettability of soil is of great importance for plants and soil biota, and in determining the risk for preferential flow, surface runoff, flooding,and soil erosion. The molarity of ethanol droplet (MED) test is widely used for quantifying the severity of water repellency in soils that show reduced wettability and is assumed to be independent of soil particle size. The minimum ethanol concentration at which droplet penetration occurs within a short time (≤10 s) provides an estimate of the initial advancing contact angle at which spontaneous wetting is expected. In this study, we test the assumption of particle size independence using a simple model of soil, represented by layers of small (0.2–2 mm) diameter beads that predict the effect of changing bead radius in the top layer on capillary driven imbibition. Experimental results using a three-layer bead system show broad agreement with the model and demonstrate a dependence of the MED test on particle size. The results show that the critical initial advancing contact angle for penetration can be considerably less than 90° and varies with particle size, demonstrating that a key assumption currently used in the MED testing of soil is not necessarily valid
Calculation of the interfacial free energy of a fluid at a static wall by Gibbs–Cahn integration
This is the publisher's version, also available electronically from http://scitation.aip.org/content/aip/journal/jcp/132/20/10.1063/1.3428383.The interface between a fluid and a static wall is a useful model for a chemically heterogeneous solid-liquid interface. In this work, we outline the calculation of the wall-fluid interfacial free energy(γwf) for such systems using molecular simulation combined with adsorptionequations based on Cahn’s extension of the surface thermodynamics of Gibbs. As an example, we integrate such an adsorptionequation to obtain γwf as a function of pressure for a hard-sphere fluid at a hard wall. The results so obtained are shown to be in excellent agreement in both magnitude and precision with previous calculations of this quantity, but are obtained with significantly lower computational effort
Radiolysis of NaCl at high and low temperatures: development of size distribution of bubbles and colloids
New experimental results are presented on low temperature irradiation (18 °C) of rock-salt samples which had been exposed to initial doses up to 320 GRad at 100 °C. Differential scanning calorimetry (DSC) shows that the latent heat of melting (LHM) of sodium colloids decreases during subsequent low-temperature irradiation, whereas the stored energy (SE) increases slowly, indicating that the process of radiolysis continues. The decrease of the LHM is due to dissolution of large colloids, because the intensities of the melting peaks decrease during the second stage irradiation at low temperature. The model is formulated to describe the nucleation kinetics and the evolution of the size distribution of chlorine precipitates and sodium colloids in NaCl under high dose irradiation. It is shown that the mechanism of dissolution of large Na colloids during low temperature irradiation can be related to melting of sodium colloids.
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