6,599 research outputs found
Liquid drops on a surface: using density functional theory to calculate the binding potential and drop profiles and comparing with results from mesoscopic modelling
The contribution to the free energy for a film of liquid of thickness on
a solid surface, due to the interactions between the solid-liquid and
liquid-gas interfaces is given by the binding potential, . The precise
form of determines whether or not the liquid wets the surface. Note that
differentiating gives the Derjaguin or disjoining pressure. We develop a
microscopic density functional theory (DFT) based method for calculating
, allowing us to relate the form of to the nature of the molecular
interactions in the system. We present results based on using a simple lattice
gas model, to demonstrate the procedure. In order to describe the static and
dynamic behaviour of non-uniform liquid films and drops on surfaces, a
mesoscopic free energy based on is often used. We calculate such
equilibrium film height profiles and also directly calculate using DFT the
corresponding density profiles for liquid drops on surfaces. Comparing
quantities such as the contact angle and also the shape of the drops, we find
good agreement between the two methods. We also study in detail the effect on
of truncating the range of the dispersion forces, both those between the
fluid molecules and those between the fluid and wall. We find that truncating
can have a significant effect on and the associated wetting behaviour of
the fluid.Comment: 16 pages, 13 fig
An introduction to inhomogeneous liquids, density functional theory, and the wetting transition
Classical density functional theory (DFT) is a statistical mechanical theory for calculating the density profiles of the molecules in a liquid. It is widely used, for example, to study the density distribution of the molecules near a confining wall, the interfacial tension, wetting behavior, and many other properties of nonuniform liquids. DFT can, however, be somewhat daunting to students entering the field because of the many connections to other areas of liquid-state science that are required and used to develop the theories. Here, we give an introduction to some of the key ideas, based on a lattice-gas (Ising) model fluid. This approach builds on knowledge covered in most undergraduate statistical mechanics and thermodynamics courses, so students can quickly get to the stage of calculating density profiles, etc., for themselves. We derive a simple DFT for the lattice gas and present some typical results that can readily be calculated using the theory
Influence of the fluid structure on the binding potential: comparing liquid drop profiles from density functional theory with results from mesoscopic theory
For a film of liquid on a solid surface, the binding potential gives the free energy as a function of the film thickness and also the closely related structural disjoining pressure . The wetting behaviour of the liquid is encoded in the binding potential and the equilibrium film thickness corresponds to the value at the minimum of . Here, the method we developed in [J. Chem. Phys. 142, 074702 (2015)], and applied with a simple discrete lattice-gas model, is used with continuum density functional theory (DFT) to calculate the binding potential for a Lennard-Jones fluid and other simple liquids. The DFT used is based on fundamental measure theory and so incorporates the influence of the layered packing of molecules at the surface and the corresponding oscillatory density profile. The binding potential is frequently input in mesoscale models from which liquid drop shapes and even dynamics can be calculated. Here we show that the equilibrium droplet profiles calculated using the mesoscale theory are in good agreement with the profiles calculated directly from the microscopic DFT. For liquids composed of particles where the range of the attraction is much less than the diameter of the particles, we find that at low temperatures decays in an oscillatory fashion with increasing , leading to highly structured terraced liquid droplets
Liquid drops on a surface: using density functional theory to calculate the binding potential and drop profiles and comparing with results from mesoscopic modelling
The contribution to the free energy for a film of liquid of thickness h on a solid surface due to the interactions between the solid-liquid and liquid-gas interfaces is given by the binding potential, g(h). The precise form of g(h) determines whether or not the liquid wets the surface. Note that differentiating g(h) gives the Derjaguin or disjoining pressure. We develop a microscopic density functional theory (DFT) based method for calculating g(h), allowing us to relate the form of g(h) to the nature of the molecular interactions in the system. We present results based on using a simple lattice gas model, to demonstrate the procedure. In order to describe the static and dynamic behaviour of non-uniform liquid films and drops on surfaces, a mesoscopic free energy based on g(h) is often used. We calculate such equilibrium film height profiles and also directly calculate using DFT the corresponding density profiles for liquid drops on surfaces. Comparing quantities such as the contact angle and also the shape of the drops, we find good agreement between the two methods. We also study in detail the effect on g(h) of truncating the range of the dispersion forces, both those between the fluid molecules and those between the fluid and wall. We find that truncating can have a significant effect on g(h) and the associated wetting behaviour of the fluid
New Evidence for Efficient Collisionless Heating of Electrons at the Reverse Shock of a Young Supernova Remnant
Although collisionless shocks are ubiquitous in astrophysics, certain key
aspects of them are not well understood. In particular, the process known as
collisionless electron heating, whereby electrons are rapidly energized at the
shock front, is one of the main open issues in shock physics. Here we present
the first clear evidence for efficient collisionless electron heating at the
reverse shock of Tycho's supernova remnant (SNR), revealed by Fe-K diagnostics
using high-quality X-ray data obtained by the Suzaku satellite. We detect
K-beta (3p->1s) fluorescence emission from low-ionization Fe ejecta excited by
energetic thermal electrons at the reverse shock front, which peaks at a
smaller radius than Fe K-alpha (2p->1s) emission dominated by a relatively
highly-ionized component. Comparison with our hydrodynamical simulations
implies instantaneous electron heating to a temperature 1000 times higher than
expected from Coulomb collisions alone. The unique environment of the reverse
shock, which is propagating with a high Mach number into rarefied ejecta with a
low magnetic field strength, puts strong constraints on the physical mechanism
responsible for this heating, and favors a cross-shock potential created by
charge deflection at the shock front. Our sensitive observation also reveals
that the reverse shock radius of this SNR is about 10% smaller than the
previous measurement using the Fe K-alpha morphology from the Chandra
observations. Since strong Fe K-beta fluorescence is expected only from
low-ionization plasma where Fe ions still have many 3p electrons, this feature
is key to diagnosing the plasma state and distribution of the immediate
postshock ejecta in a young SNR.Comment: 7 pages, 9 figures, resubmitted to ApJ with minor changes following
the referee repor
The Relationship Between Molecular Gas, HI, and Star Formation in the Low-Mass, Low-Metallicity Magellanic Clouds
The Magellanic Clouds provide the only laboratory to study the effect of
metallicity and galaxy mass on molecular gas and star formation at high (~20
pc) resolution. We use the dust emission from HERITAGE Herschel data to map the
molecular gas in the Magellanic Clouds, avoiding the known biases of CO
emission as a tracer of H. Using our dust-based molecular gas estimates,
we find molecular gas depletion times of ~0.4 Gyr in the LMC and ~0.6 SMC at 1
kpc scales. These depletion times fall within the range found for normal disk
galaxies, but are shorter than the average value, which could be due to recent
bursts in star formation. We find no evidence for a strong intrinsic dependence
of the molecular gas depletion time on metallicity. We study the relationship
between gas and star formation rate across a range in size scales from 20 pc to
~1 kpc, including how the scatter in molecular gas depletion time changes with
size scale, and discuss the physical mechanisms driving the relationships. We
compare the metallicity-dependent star formation models of Ostriker, McKee, and
Leroy (2010) and Krumholz (2013) to our observations and find that they both
predict the trend in the data, suggesting that the inclusion of a diffuse
neutral medium is important at lower metallicity.Comment: 24 pages, 14 figures, accepted for publication in ApJ. FITS files of
the dust-based estimates of the H2 column densities for the LMC and SMC
(shown in Figures 2 and 3) will be available online through Ap
OGFOD1 catalyzes prolyl hydroxylation of RPS23 and is involved in translation control and stress granule formation
2-Oxoglutarate (2OG) and Fe(II)-dependent oxygenase domain-containing protein 1 (OGFOD1) is predicted to be a conserved 2OG oxygenase, the catalytic domain of which is related to hypoxia-inducible factor prolyl hydroxylases. OGFOD1 homologs in yeast are implicated in diverse cellular functions ranging from oxygen-dependent regulation of sterol response genes (Ofd1, Schizosaccharomyces pombe) to translation termination/mRNA polyadenylation (Tpa1p, Saccharomyces cerevisiae). However, neither the biochemical activity of OGFOD1 nor the identity of its substrate has been defined. Here we show that OGFOD1 is a prolyl hydroxylase that catalyzes the posttranslational hydroxylation of a highly conserved residue (Pro-62) in the small ribosomal protein S23 (RPS23). Unusually OGFOD1 retained a high affinity for, and forms a stable complex with, the hydroxylated RPS23 substrate. Knockdown or inactivation of OGFOD1 caused a cell type-dependent induction of stress granules, translational arrest, and growth impairment in a manner complemented by wild-type but not inactive OGFOD1. The work identifies a human prolyl hydroxylase with a role in translational regulation
Cross-clade simultaneous HIV drug resistance genotyping for reverse transcriptase, protease, and integrase inhibitor mutations by Illumina MiSeq
Mulat-estetiek: ’n Analise van Adam Small se dramas
Opsomming
In hierdie artikel word die dramakonvensies van Adam Small ondersoek met besondere
aandag aan perspektiewe op die mulat as ’n sosiale gegewe. Hierdie element bied ’n
gepaste invalshoek omdat dit enersyds ‘n verskynsel is wat Small in sy dramas en ander skryfwerk aansny en daar andersyds ’n uitgebreide literatuur bestaan waarin oor
die dramatiese, lewensbeskoulike en literêr-teoretiese inkleding daarvan besin word.
Die werk van onder andere Langston Hughes en Derek Walcott word ondersoek om ’n
leesstrategie te ontwikkel waarmee die Small-teks geanaliseer kan word.Web of Scienc
Inertia-Free Spacecraft Attitude Tracking with Disturbance Rejection and Almost Global Stabilization
Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/76737/1/AIAA-41565-705.pd
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