43 research outputs found

    Deformation bands and alteration in porous glass-rich volcaniclastics: Insights from Milos, Greece

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    Deformation bands in porous volcaniclastics are little studied structural heterogeneities despite their relevance for constraining the modalities of deformation development and related fluid-rock interactions in volcanic areas. We document a dense network of normal-sense Deformation Bands (Normal-sense Compactional Shear Bands (NCSBs) affecting upper Pliocene felsic glassy tuffites in Milos, Greece. NCSBs probably formed between 300 and 500 m of burial depth, in response to NE-SW directed extension which is related to volcanic rift development in the area. They accommodate mm-to m-shear-offsets, trend either N105 ± 10° or N070 ± 10°, and show mutual cross-cutting relations. The NCSB fault rock is made of ultracataclasite in which the cataclastic mechanisms have affected both the mineral fraction and the volcanic glass. Minerals are fractured along their cleavages whereas pumices are interestingly fractured along their vesicles. The development of chemical alteration (dissolution and cementation) essentially into the ultracataclasite is expressed through glass-hosted corrosion gulfs and smectites filling the intergranular porosity. These observations support that NCSBs preferentially retained water, have been the seat of greater fluid flow, and are the locus of ongoing phyllosilicate self-sealing in the vadose zone. A significant decrease (up to one order of magnitude) in porosity is measured within the studied NCSBs

    High-pressure drop rates in solid-state batch one-step scCO2 foaming of acrylic polymers: A way to stabilize the structure of micro-nano foams

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    One-step solid-state batch scCO2 foaming is used with the target of achieving acrylic polymer micro-nano foams. Foaming is triggered by an average pressure drop (APDR), covering two decades, from 0.3 to 30 MPa.s−1. This study principally addresses the combined beneficial effects of block copolymer addition (BCP, here denoted as MAM) and high APDR. Numerous subtle kinetic parameters actually interplay and compete in the production of the final foams. In particular, the material effective temperature, the effective glass transition temperature of the plasticized system and the instantaneous PDR are physical quantities each having their own kinetics during foaming. The resulting foam morphologies are quantified by SEM microscopy and image analysis. A high APDR and the presence of BCP are shown to play a key role in the final structure of the foams. Over the scrutinized range of saturation temperature (40 °C to 60 °C i.e. rather ‘low’ temperatures in the CO2 supercritical state), the APDR is the main factor for significantly reducing cell size and increasing nuclei density in foams from neat PMMA. In the block copolymer approach, increasing the APDR is of secondary importance as the targeted reduction of the porosity dimensions and augmentation of nuclei density are mostly the consequence of MAM presence. In this latter case, increasing the APDR still promotes the ‘efficiency’ of the BCP nucleants. A real efficient nucleation activity of MAM additive is observed at a very high APDR (30 MPa.s−1), leading to monomodal homogeneous distribution of tiny pores in nearly nanosized foams. At lower APDR, an interesting reproducible double porosity (foams containing intra-wall and inter-wall pores) is detected in PMMA/MAM systems. In such double porosity foams, benefits from the Knudsen effect achieved within well expanded local domains (showing micron-sized pores) may remain meaningful thanks to a locally poorly expanded nanoporous thick solid skeleton encapsulating these local domains. Thereby, the radiative thermal conduction can be minimized and does not override the conductive component at the sample scale. This work provides further insight on acrylic polymer BCP foams influenced by different kinetics

    Microbial and diagenetic steps leading to the mineralisation of Great Salt Lake microbialites.

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    12 pagesInternational audienceMicrobialites are widespread in modern and fossil hypersaline environments, where they provide a unique sedimentary archive. Authigenic mineral precipitation in modern microbialites results from a complex interplay between microbial metabolisms, organic matrices and environmental parameters. Here, we combined mineralogical and microscopic analyses with measurements of metabolic activity in order to characterise the mineralisation of microbial mats forming microbialites in the Great Salt Lake (Utah, USA). Our results show that the mineralisation process takes place in three steps progressing along geochemical gradients produced through microbial activity. First, a poorly crystallized Mg-Si phase precipitates on alveolar extracellular organic matrix due to a rise of the pH in the zone of active oxygenic photosynthesis. Second, aragonite patches nucleate in close proximity to sulfate reduction hotspots, as a result of the degradation of cyanobacteria and extracellular organic matrix mediated by, among others, sulfate reducing bacteria. A final step consists of partial replacement of aragonite by dolomite, possibly in neutral to slightly acidic porewater. This might occur due to dissolution-precipitation reactions when the most recalcitrant part of the organic matrix is degraded. The mineralisation pathways proposed here provide pivotal insight for the interpretation of microbial processes in past hypersaline environments

    Mesure en microscopie électronique et couplage Raman

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    La relación del coaching en el desempeño laboral de los colaboradores del área de créditos de la cooperativa de ahorro y crédito León XIII en la provincia de Virú- 2017

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    RESUMEN La presente investigación tuvo como propósito, determinar la relación que se dio, al realizar Coaching en el desempeño laboral de los colaboradores del área de créditos de la Cooperativa De Ahorro y Crédito León XIII de la ciudad de Virú en el año 2017. En el primer capítulo, se determinó la realidad problemática, la formulación del problema, la justificación, limitaciones y los objetivos que se pretenden alcanzar con el desarrollo de esta investigación. En el segundo capítulo, concerniente al marco teórico, se encuentran las conceptualizaciones del Coaching y el desempeño laboral, lo que sirvió como sustento para elaborar nuestros indicadores. En el tercer capítulo, se realiza la formulación de la hipótesis, así como la Operacionalización de las variables dependiente e independiente. En el cuarto capítulo se hace referencia al tipo de diseño de investigación, la unidad de estudio, la población y la muestra además de presentar las técnicas e instrumentos de recolección y análisis de datos. En quinto capítulo se presenta el desarrollo de la investigación, en el sexto capítulo se muestra los resultados de la investigación, en el séptimo y último capítulo, se presenta la discusión. Finalmente se presenta las conclusiones obtenidas, recomendaciones, referencias y anexos.ABSTRACT The purpose of this research was to determine the relation that was given when performing Coaching in the work performance of the credit area employees of the Leon XIII Savings and Credit Cooperative in the city of Virú in the year 2017. In the first chapter, the problematic reality, the formulation of the problem, the justification, limitations and the objectives that are intended to be reached with the development of this research were determined. In the second chapter, concerning the theoretical framework, are the conceptualizations of Coaching and work performance, which served as a basis for developing our indicators. In the third chapter, the formulation of the hypothesis is carried out, as well as the Operationalization of the dependent and independent variables. In the fourth chapter, reference is made to the type of research design, the study unit, the population and the sample, in addition to presenting the techniques and instruments for collecting and analyzing data. In the fifth chapter the development of the research is presented, in the sixth chapter the results of the investigation are shown, in the seventh and last chapter, the discussion is presented. Finally, the obtained conclusions, recommendations, references and annexes are presented

    INTERPRETATION OF MERCURY INJECTION EXPERIMENTS USING A MINIMUM SET OF POROUS DESCRIPTORS DERIVED BY QUANTITATIVE IMAGE ANALYSIS

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    ABSTRACT The porosity exposed in a series of petrographic thin sections from a sub-arkosic sandstone reservoir of the Alwyn area (North Sea) is described by 5 morphological porous descriptors, Pore-Types, obtained by quantitative image analysis procedures and pattern recognition algorithms developed b

    Modélisation de la perméabilité d'un réservoir gréseux de Mer du Nord par combinaison de données d'analyse d'images et de courbes de pression capillaire

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    Belin Sophie, Anguy Yannick, Bernard Dominique, Fritz Bertrand. Modélisation de la perméabilité d'un réservoir gréseux de Mer du Nord par combinaison de données d'analyse d'images et de courbes de pression capillaire. In: Transferts dans les systèmes sédimentaires : de l'échelle du pore à celle du bassin. Réunion spécialisée SGF-TRABAS/CNRS, Paris 27-28 septembre 1999. Résumés. Strasbourg : Institut de Géologie – Université Louis-Pasteur, 1999. pp. 15-16. (Sciences Géologiques. Mémoire, 99

    Modélisation de la perméabilité d'un réservoir gréseux de Mer du Nord par combinaison de données d'analyse d'images et de courbes de pression capillaire

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    Belin Sophie, Anguy Yannick, Bernard Dominique, Fritz Bertrand. Modélisation de la perméabilité d'un réservoir gréseux de Mer du Nord par combinaison de données d'analyse d'images et de courbes de pression capillaire. In: Transferts dans les systèmes sédimentaires : de l'échelle du pore à celle du bassin. Réunion spécialisée SGF-TRABAS/CNRS, Paris 27-28 septembre 1999. Résumés. Strasbourg : Institut de Géologie – Université Louis-Pasteur, 1999. pp. 15-16. (Sciences Géologiques. Mémoire, 99
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