3,426 research outputs found

    Electron Transport in Metallic Grains

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    We discuss electron transport in individual nanometer-scale metallic grains at dilution refrigerator temperatures. In the weak coupling regime, the grains exhibit Coulomb blockade and discrete energy levels. Electron-electron interactions lead to clustering and broadening of quasiparticle states. Magnetic field dependences of tunneling resonances directly reveal Kramers degeneracy and Lande g-factors. In grains of Au, which have strong spin-orbit interaction, g-factors are strongly suppressed from the free electron value. We have recently studied grains in the strong coupling regime. Coulomb blockade persists in this regime. It leads to a suppression in sample conductance at zero bias voltage at low temperatures. The conductance fluctuates with the applied magnetic field near zero bias voltage. We present evidence that the fluctuations are induced by electron spin. This paper reviews the evolving progress in interpreting these observations.Comment: Since the original submission, we have gathered data in weak coupling regime, showing that our initial speculation - that the conductance dip is due to EE interactions in the Altshuler-Aronov sense - is not correct. Instead, it is caused by the Coulomb Blockade. Conference Proceedings, "Quantum Transport and Quantum Coherence" Localisation 2002, Sophia University, Tokyo, August 16-19, to be published in the supplement of the Journal of the Physical Society of Japa

    Ocean warming-acidification synergism undermines dissolved organic matter assembly.

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    Understanding the influence of synergisms on natural processes is a critical step toward determining the full-extent of anthropogenic stressors. As carbon emissions continue unabated, two major stressors--warming and acidification--threaten marine systems on several scales. Here, we report that a moderate temperature increase (from 30°C to 32°C) is sufficient to slow--even hinder--the ability of dissolved organic matter, a major carbon pool, to self-assemble to form marine microgels, which contribute to the particulate organic matter pool. Moreover, acidification lowers the temperature threshold at which we observe our results. These findings carry implications for the marine carbon cycle, as self-assembled marine microgels generate an estimated global seawater budget of ~1016 g C. We used laser scattering spectroscopy to test the influence of temperature and pH on spontaneous marine gel assembly. The results of independent experiments revealed that at a particular point, both pH and temperature block microgel formation (32°C, pH 8.2), and disperse existing gels (35°C). We then tested the hypothesis that temperature and pH have a synergistic influence on marine gel dispersion. We found that the dispersion temperature decreases concurrently with pH: from 32°C at pH 8.2, to 28°C at pH 7.5. If our laboratory observations can be extrapolated to complex marine environments, our results suggest that a warming-acidification synergism can decrease carbon and nutrient fluxes, disturbing marine trophic and trace element cycles, at rates faster than projected

    Integrating Distributed Generation: Regulation and Trends in Three Leading Countries

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    We explore trends in the deployment and integration of distributed generation in Germany, Denmark and Sweden. In particular, we examine the regulation of renewable energy generation with a focus on grid access and connection mechanisms. The high rate of distributed generation penetration in these countries is the result of early support given to the expansion of renewable energy generation – mainly wind and solar - within their respective national policies. Germany and Denmark are the countries with the most sophisticated support schemes, which have shown changes over time. In terms of connections, Germany is the country with the most favourable connection regime. It provides not only priority connection but also priority use of the grid to generation units that produce electricity from renewable energy sources. Sweden guarantees equal treatment among different technologies (i.e. a non-discrimination principle) and is thus the least favourable. High connection costs have been observed, especially in Germany and Denmark. The costs of network upgrades are usually socialised across customers. The use of smart solutions combined with novel business models might allow more efficient use of the current distribution electricity infrastructure. Hence, integration issues should be taken into consideration in order to avoid expansion of distributed generation in a way that unnecessarily raises total system costs, via high connection costs

    Aflatoxines i ocratoxines: agents tòxics que cal controlar

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    El present article se centra en l'estudi de toxines produïdes per fongs dels gèneres Aspergillus i Penicillium, més concretament en les aflatoxines B1, G1, B2, G2 i ocratoxina A. Es dóna una visió general del tema quant a origen, legislació, toxicitat i control de micotoxines. A més, es presenten tres mètodes per a l'anàlisi d'aquestes toxines en productes vegetals, ja que són els substrats en els quals es presenten més habitualment. Primerament, es desenvolupa un metòde d'anàlisi per a la determinació d'aflatoxines B1, G1, B2 i G2 en una planta medicinal. Posteriorment, s'optimitza l'anàlisi d'ocratoxina A en cafè i finalment es presenta un mètode per a la determinació simultània d'aflatoxines B1, G1, B2, G2 i ocratoxina A en cervesa. En tots els mètodes s'empra extracció en fase sòlida de reblert polimèric i cromatografia líquida de fase inversa. La detecció es realitza per espectrometria de masses de quadrupol simple amb ionització a pressió atmosfèrica.This paper is focused on the study of mycotoxins produced by fungi of the genera Aspergillus and Penicillium, specifically on aflatoxins B1, G1, B2, G2 and ochratoxin A. A general survey of mycotoxin origin, toxicity, legislation and control is presented. Furthermore, three analytical methods for the analysis of mycotoxins in vegetable products is presented, due to these substrates are the most liable to be contaminated. First, a method for the determination of aflatoxins B1, G1, B2 and G2 in a medicinal herb is presented. Afterwards, the analysis of ochratoxin A in coffee was optimized. Finally, a method for the simultaneous analysis of aflatoxins B1, G1, B2, G2 and ochratoxin A in beer is developed. All the methods apply solid-phase clean-up using a polymeric sorbent and liquid chromatography with a reversed phase column. A single quadruple mass spectrometer with an electrospray ionization source was used as a detector
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