U–Pb ages and Hf-isotope data of detrital zircons from the late Neoarchean-Paleoproterozoic Minas Basin, SE Brazil

Because of its world-class iron ore deposits and promising Au and U mineralizations, the late Neoarchean to Paleoproterozoic Minas Basin (Minas Supergroup, SE of Brazil) is one of the best-studied basins in South America. However, the lack of datable interlayered volcanic rocks prevented discourse over ages of the strata, the sources and the nature of its ore deposits. In this paper, we present detrital zircon U–Pb age patterns coupled with Lu–Hf data for 18 samples, representing different stages of the Minas Basin evolution (∼2000 analyzed zircons). Age spectra for the main basal unit (Moeda Formation) show a classic rift-related detrital zircon pattern, characterized by multiple autochthonous sources, which in turn are much older than the age of deposition. Maximum age for the rifting event is constrained at ca. 2600 Ma. Detritus accumulated at the base of the Minas Supergroup were derived from Archean source rocks and their sedimentation was marked by differential uplift of the Archean crust, shortly after the 2730–2600 Ma high-K calc-alkaline magmatism (Mamona Event). The age of the BIF deposits is younger than 2600 Ma, most likely coinciding with the great oxygenation event between 2400 and 2200 Ma and the precipitation of banded iron deposits worldwide. Detrital zircons from the topmost units of the Minas strata suggest that tectonic inversion and closure of the basin took place at ca. 2120 Ma with the deposition of the synorogenic Sabará Group. Rhyacian zircon supply showing juvenile Hf signatures gives evidence of a late Rhyacian amalgamation between the Mineiro Belt and the craton. The εHf signatures support the hypothesis that the Archean crystalline crust of the craton was mostly built by crust–mantle mixing processes, with a successive decrease of εHf values in zircons crystallized after 3250 Ma and minor mantle-like additions after Paleoarchean times. Regionally, our dataset supports previous interpretations of a long-lived evolution of the southern São Francisco Craton comprising a succession of convergent island arcs, small microplate collisions, and development of Archean convergent and divergent basins that evolved between Archean and Paleoproterozoic times.Fil: Martínez Dopico, Carmen Irene. Universidade Federal de Ouro Preto; Brasil. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Lana, Cristiano. Universidade Federal de Ouro Preto; BrasilFil: Moreira, Hugo S.. University of Portsmouth; Reino UnidoFil: Cassino, Lucas F.. Universidade Federal de Ouro Preto; BrasilFil: Alkmim, Fernando F.. Universidade Federal de Ouro Preto; Brasi

Avaliação da precisão e aplicação de método para determinação de impurezas do café torrado e moído.

A detecção de impurezas do café torrado e moído é esse ncial para assegurar a melhoria da qualidade da produção e do produto. O objetivo desse trabalho foi avaliar a precisão obtida com o método de microscopia em duas faixas de concentração e com a utilização de três analistas diferentes. As análises preconizadas por este estudo foram realizadas na Unidade de Microscopia do Laboratório Nacional Agropecuário (LANAGRO-MG), situada em Pedro Leopoldo, MG. O método para detecção, identificação e quantificação das impurezas cascas e paus em café torrado e moído baseia-se no desengorduramento parcial do café com solvente orgânico, eliminação do pó fino por peneiração e determinação por catação através do uso de microscópio estereoscópico. As análises foram constituídas por 11 amostras de café torrado e moído feitas em duplicata por três analistas totalizando 66 determinações, cujos resultados foram fornecidos em porcentagens das impurezas cascas e paus. Os desvios padrão e os coeficientes de variação dos resultados analíticos do método estudado diminuíram a medida que se aumentou a concentração de cascas e paus. Na faixa de concentração acima de 2,5% o coeficiente de variação geral obtido foi 22,5% sendo plenamente aceitável. Na faixa de concentração de 0,1 a 0,5% o coeficiente de variação geral obtido foi 44,5% o que indica que, nestas concentrações, o resultado obtido não tem a mesma confiabilidade das faixas de concentração mais altas. Um estudo mais profundo avaliando-se todos os parâmetros de desempenho do método, e contando com um numero maior de análises é necessário para se validar adequadamente esta metodologia

U?Pb ages and Hf-isotope data of detrital zircons from the late Neoarchean-Paleoproterozoic Minas Basin, SE Brazil.

Because of its world-class iron ore deposits and promising Au and U mineralizations, the late Neoarchean to Paleoproterozoic Minas Basin (Minas Supergroup, SE of Brazil) is one of the best-studied basins in South America. However, the lack of datable interlayered volcanic rocks prevented discourse over ages of the strata, the sources and the nature of its ore deposits. In this paper, we present detrital zircon U? Pb age patterns coupled with Lu?Hf data for 18 samples, representing different stages of the Minas Basin evolution ( 2000 analyzed zircons). Age spectra for the main basal unit (Moeda Formation) show a classic rift-related detrital zircon pattern, characterized by multiple autochthonous sources, which in turn are much older than the age of deposition. Maximum age for the rifting event is constrained at ca. 2600 Ma. Detritus accumulated at the base of the Minas Supergroup were derived from Archean source rocks and their sedimentation was marked by differential uplift of the Archean crust, shortly after the 2730?2600 Ma high-K calc-alkaline magmatism (Mamona Event). The age of the BIF deposits is younger than 2600 Ma, most likely coinciding with the great oxygenation event between 2400 and 2200 Ma and the precipitation of banded iron deposits worldwide. Detrital zircons from the topmost units of the Minas strata suggest that tectonic inversion and closure of the basin took place at ca. 2120 Ma with the deposition of the synorogenic Sabar? Group. Rhyacian zircon supply showing juvenile Hf signatures gives evidence of a late Rhyacian amalgamation between the Mineiro Belt and the craton. The eHf signatures support the hypothesis that the Archean crystalline crust of the craton was mostly built by crust?mantle mixing processes, with a successive decrease of eHf values in zircons crystallized after 3250 Ma and minor mantle-like additions after Paleoarchean times. Regionally, our dataset supports previous interpretations of a long-lived evolution of the southern S?o Francisco Craton comprising a succession of convergent island arcs, small microplate collisions, and developmen

Effect of heat and moisture exchangers on the prevention of ventilator-associated pneumonia in critically ill patients

Ventilator-associated pneumonia (VAP) remains one of the major causes of infection in the intensive care unit (ICU) and is associated with the length of hospital stay, duration of mechanical ventilation, and use of broad-spectrum antibiotics. We compared the frequency of VAP 10 months prior to (pre-intervention group) and 13 months after (post-intervention group) initiation of the use of a heat and moisture exchanger (HME) filter. This is a study with prospective before-and-after design performed in the ICU in a tertiary university hospital. Three hundred and fourteen patients were admitted to the ICU under mechanical ventilation, 168 of whom were included in group HH (heated humidifier) and 146 in group HME. The frequency of VAP per 1000 ventilator-days was similar for both the HH and HME groups (18.7 vs 17.4, respectively; P = 0.97). Duration of mechanical ventilation (11 vs 12 days, respectively; P = 0.48) and length of ICU stay (11 vs 12 days, respectively; P = 0.39) did not differ between the HH and HME groups. The chance of developing VAP was higher in patients with a longer ICU stay and longer duration of mechanical ventilation. This finding was similar when adjusted for the use of HME. The use of HME in intensive care did not reduce the incidence of VAP, the duration of mechanical ventilation, or the length of stay in the ICU in the study population

Ensino de Geociências na universidade

In colonial times, in Brazil, although intense mining activities occurred in the search for gold and diamonds, relevant geoscientific actions did not occur. In the 19th century, a few geological exploratory trips were made, from which several written contributions resulted. Moreover, important institutions were created, such as the National Observatory, the Meteorological Service, the Magnetic Observatory at Vassouras and the Mining School of Ouro Preto in 1876, The formal teaching of Geosciences in Brazil started only in 1957, with the ”Campaign for the training of geologists” (CAGE), that created and provided material and human resources to four Geology undergraduate courses. In Meteorology the first course was in 1973, in Oceanography in 1971 and in Geophysics in 1983. Now, 48 Brazilian universities offer 71 undergraduate courses in Geosciences, 33 in Geology, 3 in Geological Engineering, 14 in Meteorology, 13 in Oceanography and 8 in Geophysics. Fifty-seven graduate programs exist in Brazil, 13 of which are considered of excellence, indicating that the area is mature and consolidated. Most geologists and geophysicists were absorbed in geological mapping activities, as well as mining and oil exploration. Meteorologists dedicated themselves to meteorological and climatic monitoring, as well as to projects in hydroelectric, wind and solar energy. Graduates in Oceanography worked in institutions related to the environment, agriculture, and to the Ministry of the Navy. The atmospheric and oceanographic sciences are of global relevance in studies of climatic changes and global warming. In turn, the major challenge of geologists and geophysicists is to improve knowledge of the Brazilian territory, at the local and regional scale.No Brasil colonial, apesar de intensa atividade mineira na busca de ouro e diamantes, não houve práticas geocientíficas relevantes. No século XIX ocorreram diversas explorações geológicas, das quais resultou uma vasta contribuição escrita. Além disso foram criadas importantes instituições, como o Observatório Nacional, o Serviço Meteorológico, o Observatório Magnético de Vassouras e a Escola de Minas de Ouro Preto em 1876. O ensino formal de Geociências no Brasil foi iniciado apenas em 1957, com a Campanha de Formação de Geólogos (CAGE), que criou e forneceu recursos materiais e humanos para quatro cursos de graduação em Geologia. Na Meteorologia a graduação se iniciou em 1963, na Oceanografia em 1971, e na Geofísica em 1983. Atualmente, 47 universidades brasileiras oferecem 71 cursos de graduação nas Geociências. Há 33 cursos de Geologia, três de Engenharia Geológica, 14 de Meteorologia, 13 de Oceanografia e 8 de Geofísica. Há no Brasil 57 programas de pós-graduação em Geociências, 13 dos quais considerados de excelência, indicando que a situação atual da área é de consolidação e maturidade. Geólogos e geofísicos foram absorvidos, em sua maioria, pelas atividades de mapeamento geológico, exploração mineral e de petróleo. Meteorologistas dedicaram-se ao monitoramento meteorológico e climático, e também a projetos de energia hidroelétrica, eólica e solar. Na Oceanografia, os formados atuaram em órgãos relacionados com ambiente, agricultura e no Ministério da Marinha. Quanto à pesquisa, as ciências atmosféricas e oceanográficas são de grande relevância global, no estudo das mudanças climáticas e o aquecimento global. Por sua vez, o maior desafio de geólogos e geofísicos é o de melhorar do conhecimento do território brasileiro, na escala local ou regional

Validação de método para determinação de sedimentos em café torrado e moído.

A análise de sedimentos do café torrado e moído faz parte dos procedimentos de controle da qualidade do produto. O objetivo desse trabalho foi validar um método de determinação de sedimentos em café torrado e moído baseada no princípio da decantação com o uso de solvente orgânico. Um conjunto de 30 amostras do produto foi fortificado em cinco níveis crescentes de sedimentos, 0,4%, 0,8%, 1,2%, 1,6% e 3% e analisado com duplicação por dois analistas, totalizando 120 resultados. Na avaliação da precisão em condições de repetibilidade e intermediária foi obtido índice de dispersão numa faixa adequada, abaixo de 20%, apropriada para uso. A exatidão e a precisão do método foram consideradas satisfatórias, tendo a incerteza abaixo de 15%, comprovando adequação do uso do método para análise de rotina na determinação de sedimentos em café torrado e moído

Reconstruction of the frequency-wavenumber spectrum of water waves with an airborne acoustic Doppler array for non-contact river monitoring

This work presents a novel method to reconstruct the frequency-wavenumber spectrum of water waves based on the complex acoustic Doppler spectra of scattered sound measured with an array of microphones. The reconstruction is based on a first-order small-roughness-amplitude expansion of the acoustic wave scattering equation, which is discretized and inverted by means of a singular value decomposition. An analogy of this approach to the first-order Bragg scattering problem is demonstrated by means of a stationary phase expansion. The approach enables the reconstruction of the dispersion relation of water waves when the ratio between roughness height and acoustic wavelength is less than 0.1, and when the surface wavelength is larger than 1/2 of the acoustic wavelength. The method is validated against synthetic data and data from laboratory and field experiments, to demonstrate its applicability to two-and three-dimensional complex patterns of water waves, and specifically to the surface deformations that arise naturally in a turbulent open-channel flow. Fitting the reconstructed data with the analytical dispersion relation enables the non-contact estimate of the underlying flow velocity for hydraulic conditions where the coexistence of different types of turbulence-forced and freely propagating water waves would limit the accuracy of standard non-contact Doppler velocimetry approaches, paving the way for robust and accurate non-contact river monitoring using acoustics

Validação de método para determinação das impurezas cascas e paus em café torrado e moído.

A determinação de impurezas do café torrado e moído faz parte das análises que contribuem para assegurar o controle da qualidade do produto. O objetivo deste trabalho foi validar o procedimento metodológico de microscopia para detecção e quantificação das impurezas cascas e paus em café torrado e moído. O método baseou-se no princípio da extração de gordura do café com solvente orgânico, eliminação do pó fino por peneiração e determinação por catação pelo uso de microscópio estereoscópico. Setenta amostras de café torrado e moído coletadas em estabelecimentos comerciais de Belo Horizonte, MG, tiveram as análises duplicadas por três analistas, totalizando 420 determinações, com os resultados expressos em porcentagens das impurezas cascas e paus. Os coeficientes de variação em condições de repetibilidade variaram de 7,0% a 27,9%, sendo considerados satisfatórios para microscopia. O fator analista tem forte influência nos parâmetros de precisão e exatidão do método. O método mostrou-se preciso a partir da concentração de 0,2% de impurezas. A exatidão do método foi satisfatória com a recuperação estando numa faixa aceitável. As incertezas variaram com a faixa de concentração de impurezas e tenderam a ser inversamente proporcionais. O método foi considerado adequado para análise destas impurezas do café torrado e moído e tem potencial para ser indicado nos procedimentos de fiscalização.Título em inglês: Valoidation of a method determine the impurities husks and straw in roast ground coffee

Characterization of xenotime from Datas (Brazil) as a potential reference material for in situ U-Pb geochronology

CITATION: Vasconcelos, A. D. et al. 2018. Characterization of xenotime from Datas (Brazil) as a potential reference material for in situ U-Pb geochronology. Geochemistry, Geophysics, Geosystems, 19:2262–2282, doi:10.1029/2017GC007412.The original publication is available at https://agupubs.onlinelibrary.wiley.comThis study investigates five megacrysts of xenotime (XN01, XN02, XN03, XN04, and XN05) as potential reference materials (RMs) for U‐Pb geochronology. These crystals belong to a 300 g xenotime assortment, collected from alluvial deposits in SE Brazil. Electron microprobe and Laser Ablation‐Inductively Coupled Plasma‐Mass Spectrometry (LA‐ICP‐MS) analyses show that the selected crystals are internally homogeneous for most rare earth element, (REE, except some light REE) but are relatively heterogeneous for U and Th. The xenotime REE patterns are consistent with an origin from hydrothermal quartz veins in the Datas area that cut greenschist‐facies metasediments and that locally contain other accessory phases such as rutile and monazite. High‐precision U‐Pb Isotope Dilution‐Thermal Ionization Mass Spectrometry (ID‐TIMS) analyses showed slight age heterogeneity for the XN01 crystal not observed in the XN02 sample. The two crystals have slightly different average 206Pb/238U ages of 513.4 ± 0.5 Ma (2 s) and 515.4 ± 0.2 Ma (2 s), respectively. In situ U‐Pb isotope data acquired via LA‐(Q,SF,MC)‐ICP‐MS are within the uncertainty of the ID‐TIMS data, showing homogeneity at the 1% precision of the laser ablation (and probably ion microprobe) technique. U‐Pb LA‐(MC, SF)‐ICP‐MS analyses, using XN01 as a primary RM, reproduced the ages of other established RMs within less than 1% deviation. Other Datas crystals (XN03‐05) also display a reproducibility in Pb/U dates better than 1% on LA‐ICP‐MS, making them good candidates for further testing by ID‐TIMS.https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2017GC007412Publisher's versio