Effect of physical aging on the low-frequency vibrational density of states of a glassy polymer

The effects of the physical aging on the vibrational density of states (VDOS) of a polymeric glass is studied. The VDOS of a poly(methyl methacrylate) glass at low-energy (<15 meV), was determined from inelastic neutron scattering at low-temperature for two different physical thermodynamical states. One sample was annealed during a long time at temperature lower than Tg, and another was quenched from a temperature higher than Tg. It was found that the VDOS around the boson peak, relatively to the one at higher energy, decreases with the annealing at lower temperature than Tg, i.e., with the physical aging.Comment: To be published in Europhys. Let

High order vibration modes of glass embedded AgAu nanoparticles

High resolution low frequency Raman scattering measurements from embedded AgAu nanoparticles unveil efficient scattering by harmonics of both the quadrupolar and the spherical modes. Comparing the experimental data with theoretical calculations that account for both the embedding medium and the resonant Raman process enables a very complete description of the observed multiple components in terms of harmonics of both the quadrupolar and spherical modes, with a dominating Raman response from the former ones. It is found that only selected harmonics of the quadrupolar mode contribute significantly to the Raman spectra in agreement with earlier theoretical predictions.Comment: 11 pages, 4 figure

Importance of cooling in triggering the collapse of hypermassive neutron stars

The inspiral and merger of a binary neutron star (NSNS) can lead to the formation of a hypermassive neutron star (HMNS). As the HMNS loses thermal pressure due to neutrino cooling and/or centrifugal support due to gravitational wave (GW) emission, and/or magnetic breaking of differential rotation it will collapse to a black hole. To assess the importance of shock-induced thermal pressure and cooling, we adopt an idealized equation of state and perform NSNS simulations in full GR through late inspiral, merger, and HMNS formation, accounting for cooling. We show that thermal pressure contributes significantly to the support of the HMNS against collapse and that thermal cooling accelerates its "delayed" collapse. Our simulations demonstrate explicitly that cooling can induce the catastrophic collapse of a hot hypermassive neutron star formed following the merger of binary neutron stars. Thus, cooling physics is important to include in NSNS merger calculations to accurately determine the lifetime of the HMNS remnant and to extract information about the NS equation of state, cooling mechanisms, bar instabilities and B-fields from the GWs emitted during the transient phase prior to BH formation.Comment: 13 pages, 7 figures, matches published versio

Light Element Abundance Patterns in the Orion Association: I) HST Observations of Boron in G-dwarfs

The boron abundances for two young solar-type members of the Orion association, BD -6 1250 and HD 294297, are derived from HST STIS spectra of the B I transition at 2496.771 A. The best-fit boron abundances for the target stars are 0.13 and 0.44 dex lower than the solar meteoritic value of log e(B)=2.78. An anticorrelation of boron and oxygen is found for Orion when these results are added to previous abundances obtained for 4 B-type stars and the G-type star BD -5 1317. An analysis of the uncertainties in the abundance calculations indicates that the observed anticorrelation is probably real. The B versus O relation observed in the Orion association does not follow the positive correlation of boron versus oxygen which is observed for the field stars with roughly solar metallicity. The observed anticorrelation can be accounted for by a simple model in which two poorly mixed components of gas (supernova ejecta and boron-enriched ambient medium) contribute to the new stars that form within the lifetime of the association. This model predicts an anticorrelation for Be as well, at least as strong as for boron.Comment: 16 pages + 1 table + 7 figures, accepted for publication in Ap

Volatility Spillover and Time-Varying Conditional Correlation Between DDGS, Corn, and Soybean Meal Markets

We find distiller\u27s dried grains with solubles (DDGS) prices to be positively correlated with both corn and soybean meal prices in the long run. However, neither corn nor soybean meal prices respond to deviations from this long-run relationship. We also identify strong time-varying dynamic conditional correlations between the markets, with the correlation between DDGS and corn strengthened after the expansion of ethanol production. There also appear to exist significant volatility spillovers from both the corn and soybean meal markets to the DDGS market, with the impact from corn shocks much larger compared to soybean meal shocks

Heat Transport in a Strongly Overdoped Cuprate: Fermi Liquid and Pure d-wave BCS Superconductor

The transport of heat and charge in the overdoped cuprate superconductor Tl_2Ba_2CuO_(6+delta) was measured down to low temperature. In the normal state, obtained by applying a magnetic field greater than the upper critical field, the Wiedemann-Franz law is verified to hold perfectly. In the superconducting state, a large residual linear term is observed in the thermal conductivity, in quantitative agreement with BCS theory for a d-wave superconductor. This is compelling evidence that the electrons in overdoped cuprates form a Fermi liquid, with no indication of spin-charge separation.Comment: 4 pages, 2 figures, published version, title changed, Phys. Rev. Lett. 89, 147003 (2002

Hamiltonian of a spinning test-particle in curved spacetime

Using a Legendre transformation, we compute the unconstrained Hamiltonian of a spinning test-particle in a curved spacetime at linear order in the particle spin. The equations of motion of this unconstrained Hamiltonian coincide with the Mathisson-Papapetrou-Pirani equations. We then use the formalism of Dirac brackets to derive the constrained Hamiltonian and the corresponding phase-space algebra in the Newton-Wigner spin supplementary condition (SSC), suitably generalized to curved spacetime, and find that the phase-space algebra (q,p,S) is canonical at linear order in the particle spin. We provide explicit expressions for this Hamiltonian in a spherically symmetric spacetime, both in isotropic and spherical coordinates, and in the Kerr spacetime in Boyer-Lindquist coordinates. Furthermore, we find that our Hamiltonian, when expanded in Post-Newtonian (PN) orders, agrees with the Arnowitt-Deser-Misner (ADM) canonical Hamiltonian computed in PN theory in the test-particle limit. Notably, we recover the known spin-orbit couplings through 2.5PN order and the spin-spin couplings of type S_Kerr S (and S_Kerr^2) through 3PN order, S_Kerr being the spin of the Kerr spacetime. Our method allows one to compute the PN Hamiltonian at any order, in the test-particle limit and at linear order in the particle spin. As an application we compute it at 3.5PN order.Comment: Corrected typo in the ADM Hamiltonian at 3.5 PN order (eq. 6.20

An Inverse Method for Policy-Iteration Based Algorithms

We present an extension of two policy-iteration based algorithms on weighted graphs (viz., Markov Decision Problems and Max-Plus Algebras). This extension allows us to solve the following inverse problem: considering the weights of the graph to be unknown constants or parameters, we suppose that a reference instantiation of those weights is given, and we aim at computing a constraint on the parameters under which an optimal policy for the reference instantiation is still optimal. The original algorithm is thus guaranteed to behave well around the reference instantiation, which provides us with some criteria of robustness. We present an application of both methods to simple examples. A prototype implementation has been done