256 research outputs found
Dynamic equations for three different qudits in a magnetic field
A closed system of equations for the local Bloch vectors and spin correlation
functions of three magnetic qudits, which are in an arbitrary, time-dependent,
external magnetic field, is obtained using decomplexification of the
Liouville-von Neumann equation. The algorithm of the derivation of the dynamic
equations is presented. In the basis convenient for the important physical
applications structure constants of algebra su(2S+1) are calculated.Comment: 11 page
Irreversible Performance of a Quantum Harmonic Heat Engine
The unavoidable irreversible losses of power in a heat engine are found to be
of quantum origin. Following thermodynamic tradition a model quantum heat
engine operating by the Otto cycle is analyzed. The working medium of the model
is composed of an ensemble of harmonic oscillators. A link is established
between the quantum observables and thermodynamical variables based on the
concept of canonical invariance. These quantum variables are sufficient to
determine the state of the system and with it all thermodynamical variables.
Conditions for optimal work, power and entropy production show that maximum
power is a compromise between the quasistatic limit of adiabatic following on
the compression and expansion branches and a sudden limit of very short time
allocation to these branches. At high temperatures and quasistatic operating
conditions the efficiency at maximum power coincides with the endoreversible
result. The optimal compression ratio varies from the square root of the
temperature ratio in the quasistatic limit where their reversibility is
dominated by heat conductance to the temperature ratio to the power of 1/4 in
the sudden limit when the irreversibility is dominated by friction. When the
engine deviates from adiabatic conditions the performance is subject to
friction. The origin of this friction can be traced to the noncommutability of
the kinetic and potential energy of the working medium.Comment: 25 pages, 7 figures. Revision added explicit heat-transfer expression
and extended the discussion on the quantum origin of frictio
The falling chain of Hopkins, Tait, Steele and Cayley
A uniform, flexible and frictionless chain falling link by link from a heap
by the edge of a table falls with an acceleration if the motion is
nonconservative, but if the motion is conservative, being the
acceleration due to gravity. Unable to construct such a falling chain, we use
instead higher-dimensional versions of it. A home camcorder is used to measure
the fall of a three-dimensional version called an -slider. After
frictional effects are corrected for, its vertical falling acceleration is
found to be . This result agrees with the theoretical
value of for an ideal energy-conserving -slider.Comment: 17 pages, 5 figure
Optimal performance of endoreversible quantum refrigerators
The derivation of general performance benchmarks is important in the design of highly optimized heat engines and refrigerators. To obtain them, one may model phenomenologically the leading sources of irreversibility ending up with results that are model independent, but limited in scope. Alternatively, one can take a simple physical system realizing a thermodynamic cycle and assess its optimal operation from a complete microscopic description. We follow this approach in order to derive the coefficient of performance at maximum cooling rate for any endoreversible quantum refrigerator. At striking variance with the universality of the optimal efficiency of heat engines, we find that the cooling performance at maximum power is crucially determined by the details of the specific system-bath interaction mechanism. A closed analytical benchmark is found for endoreversible refrigerators weakly coupled to unstructured bosonic heat baths: an ubiquitous case study in quantum thermodynamics
Brownian Carnot engine
The Carnot cycle imposes a fundamental upper limit to the efficiency of a
macroscopic motor operating between two thermal baths. However, this bound
needs to be reinterpreted at microscopic scales, where molecular bio-motors and
some artificial micro-engines operate. As described by stochastic
thermodynamics, energy transfers in microscopic systems are random and thermal
fluctuations induce transient decreases of entropy, allowing for possible
violations of the Carnot limit. Despite its potential relevance for the
development of a thermodynamics of small systems, an experimental study of
microscopic Carnot engines is still lacking. Here we report on an experimental
realization of a Carnot engine with a single optically trapped Brownian
particle as working substance. We present an exhaustive study of the energetics
of the engine and analyze the fluctuations of the finite-time efficiency,
showing that the Carnot bound can be surpassed for a small number of
non-equilibrium cycles. As its macroscopic counterpart, the energetics of our
Carnot device exhibits basic properties that one would expect to observe in any
microscopic energy transducer operating with baths at different temperatures.
Our results characterize the sources of irreversibility in the engine and the
statistical properties of the efficiency -an insight that could inspire novel
strategies in the design of efficient nano-motors.Comment: 7 pages, 7 figure
Les Laboratoires de chimie
Data del Supplément: 1882Pag.: v.1: 145 p.; v.2: 74 p.; v.3: [81] f. de là m.Conté: v. 1: Texte -- v. 2: Supplément / Henrivaux, Girard et Pabst -- v. 3: Atla
The different paths to entropy
In order to undestand how the complex concept of entropy emerged,we propose a
trip towards the past reviewing the works of Clausius, Boltzmann, Gibbs and
Planck. In particular, since the Gibbs's work is not very well known, we
present a detailed analysis, recalling the three definitions of the entropy
that Gibbs gives. May be one of the most important aspect of the entropy is to
see it as a thermodynamic potential like the other thermodynamic potentials as
proposed by Callen. We close with some remarks on entropy and irreversibility.Comment: 32 page
Fundamental limits on quantum dynamics based on entropy change
It is well known in the realm of quantum mechanics and information theory that the entropy is non-decreasing for the class of unital physical processes. However, in general, the entropy does not exhibit monotonic behavior. This has restricted the use of entropy change in characterizing evolution processes. Recently, a lower bound on the entropy change was provided in the work of Buscemi, Das, and Wilde [Phys. Rev. A 93(6), 062314 (2016)]. We explore the limit that this bound places on the physical evolution of a quantum system and discuss how these limits can be used as witnesses to characterize quantum dynamics. In particular, we derive a lower limit on the rate of entropy change for memoryless quantum dynamics, and we argue that it provides a witness of non-unitality. This limit on the rate of entropy change leads to definitions of several witnesses for testing memory effects in quantum dynamics. Furthermore, from the aforementioned lower bound on entropy change, we obtain a measure of non-unitarity for unital evolutions
On thermodynamic and microscopic reversibility
The word 'reversible' has two (apparently) distinct applications in statistical thermodynamics. A thermodynamically reversible process indicates an experimental protocol for which the entropy change is zero, whereas the principle of microscopic reversibility asserts that the probability of any trajectory of a system through phase space equals that of the time reversed trajectory. However, these two terms are actually synonymous: a thermodynamically reversible process is microscopically reversible, and vice versa
Efficiency of inefficient endoreversible thermal machines
We present a study of the performance of endoreversible thermal machines optimized with respect to the thermodynamic force associated with the cold bath in the regime of small thermodynamic forces. These thermal machines can work either as an engine or as a refrigerator. We analyze how the optimal performances are determined by the dependence of the thermodynamic flux on the forces. The results are motivated and illustrated with a quantum model, the three level maser, and explicit analytical expressions of the engine efficiency as a function of the system parameters are given
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