Rare earth oxycarbonates as a material class for chemoresistive CO2 gas sensors

AbstractIn this work we compare the CO2 gas sensing properties of two new materials synthesized from rare earth hydroxide (La(OH)3,Pr(OH)3) precursors, with the already reported ones for neodymium oxycarbonate, which was synthesized from the corresponding Nd(OH)3 precursor. In-situ XRD measurements show that by following similar thermal treatment, praseodymium hydroxide is transforming to the metal oxide while lanthanum hydroxide forms an oxycarbonate, like in the case of neodymium. The chemoresistive effects we found for the lanthanum oxycarbonate were even higher than the ones recorded for the neodymium oxycarbonate; for the praseodymium metal oxide we could not find any CO2 sensitivity. Accordingly, we think that the condition for CO2 sensing is the formation of the rare earth oxycarbonate

CO2 sensing with chemoresistive Nd2O2CO3 sensors - Operando insights

AbstractIn this work the sensing of Nd2O2CO3-based chemoresistive CO2 sensor was investigated combining DRIFT and DC-resistance measurements. Besides the already reported effect of CO2 exposure, we found that exposure to CO determines comparable effects and that the presence of oxygen in the background is not important. The humidity significantly influences the response for both gases. The spectroscopic results reveal that the exposure to both CO and CO2 consumes the water-related surface species – the rooted-hydroxyls being the electrically active one – and increases the concentration of carbonates; the decrease of the rooted-hydroxyls is probably the cause of the resistance increase

Design and application of a flow cell for carbon-film based electrochemical enzyme biosensors

A flow cell has been designed for use with an electrochemical enzyme biosensor, based on low-cost carbon-film electrodes. Three types of mediators were used: cobalt and copper hexacyanoferrates and poly(neutral red) (PNR), covered with glucose oxidase (GOx) immobilised by cross-linking with glutaraldehyde in the presence of bovine serum albumin or inside a oxysilane sol-gel network. Mixtures of sol-gel precursors were made from 3-aminopropyl-triethoxysilane (APTOS) together with methyltrimethoxysilane (MTMOS), methyltriethoxysilane (MTEOS), tetraethyloxysilane (TEOS) or 3-glycidoxypropyl-trimethoxysilane (GOPMOS), and the best chosen for encapsulation. Optimisation in batch mode, using amperometric detection at fixed potential, showed the PNR-GOx modified carbon-film electrodes to be best for flow analysis for both glutaraldehyde and sol-gel enzyme immobilisation. Both types of enzyme electrode were tested under flow conditions and the reproducibility and stability of the biosensors were evaluated. The biosensors were used for fermentation monitoring of glucose in grape must and interference studies were also performed.http://www.sciencedirect.com/science/article/B6THP-4M0BH9Y-2/1/306f5db86217ea276bf808fb05c0288

Behaviours, motivations and values: Validity, reliability, and utility of novice motorcyclist' self-report in road safety research

The continuing use of self-report methods demands consideration of the validity, reliability, and utility of self-report in road safety research. This thesis assesses self-report issues with respect to four key constructs in motorcycle safety research—exposure, on-road behaviours, riding motivations, and perceived value in a sample of Australian novice motorcycle riders. In Study 1 a comprehensive set of statistical analyses was performed to test the validity and reliability of various self-report measures of riding exposure. In Study 2 and Study 3 previously untested psychometric properties of stability, content validity, and predictive validity of the Motorcycle Rider Behaviour Questionnaire and the Motorcycle Rider Motivation Questionnaire in terms of police-recorded offences and crashes as well as previously assessed factor structure, internal consistency, and predictive validity in terms of self-reported crashes were examined. In Study 4 I demonstrated the utility of a contingent valuation (CV) survey in measuring, understanding, and therefore addressing the perceived value of rider training amongst novice riders. The four studies highlight that the appropriateness of self-report depends on not only the nature of the phenomenon under study but the extent to which the factors that contribute to validity and reliability are accounted for in the design of self-report measures

Sensing low concentrations of CO using flame-spray-made Pt/SnO2 nanoparticles

Tin dioxide nanoparticles of different sizes and platinum doping contents were synthesized in one step using the flame spray pyrolysis (FSP) technique. The particles were used to fabricate semiconducting gas sensors for low level CO detection, i.e. with a CO gas concentration as low as 5ppm in the absence and presence of water. Post treatment of the SnO2 nanoparticles was not needed enabling the investigation of the metal oxide particle size effect. Gas sensors based on tin dioxide with a primary particle size of 10nm showed signals one order of magnitude higher than the ones corresponding to the primary particle size of 330nm. In situ platinum functionalization of the SnO2 during FSP synthesis resulted in higher sensor responses for the 0.2wt% Pt-content than for the 2.0wt% Pt. The effect is mainly attributed to catalytic consumption of CO and to the associated reduced sensor response. Pure and functionalized tin dioxide nanoparticles have been characterized by Brunauer, Emmett and Teller (BET) surface area determination, X-ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM) and scanning transmission electron microscopy (STEM) while the platinum oxidation state and dispersion have been investigated by X-ray photoelectron spectroscopy (XPS) and extended X-ray absorption fine structure (EXAFS). The sensors showed high stability (up to 20days) and are suitable for low level CO detection: <10ppm according to European and 50ppm according to US legislation, respectivel

HARVESTING TECHNOLOGIES FOR MEDICINAL AND AROMATIC PLANTS

In recent years, the people had more and more the tendency to return to remedies offered by nature. Nowadays, according to W.H.O. data, over 80% out of world population is using the medicinal plants for which a great interest was generated by traditional phytotherapy and especially by the fact that they represent an important source of bioactive substances. Therefore, the fields cultivated with medicinal plants have been extended and the relevant culture technologies have been modernized and adapted to current requirements. In general, mechanized harvesting of medicinal and aromatic plants is an important prerequisite in achieving a good production. Lavender is one of the most valuable aromatic species due to its volatile oil obtained by distillation of fresh inflorescences, being widely used in industry of perfume, cosmetics, pharmaceuticals, aromatherapy, etc. Harvesting technologies of lavender and medicinal plants require specialized equipment designed according to cultivated field size. This paper presents a lavender harvesting technology, based on the utilization of a low-capacity equipment designed to gather the lavender from rather reduced surfaces. At the same time, a technology of harvesting medicnal plants, from which aerial organs (stems, leaves, flowers) are collected, is presented together with the small capacity equipment used for this purpose. This equipment was designed in order to support small farmers, for whom lavender and other medicinal species cultivation (from which the herb is capitalized) represents a real opportunity for obtaining major incomes

Assessment of emergency medical services in the Ashanti region of Ghana

Background: We aimed to assess the structure, function and performance of Ashanti Region’s emergency medical services system in the context of the regional need for prehospital emergency care.Design: A mixed-methods approach was employed, using retrospective collection of quantitative data and prospectively gathered qualitative data. Setting – pertinent data were collected from Ghanaian and international sources; interviews and technical assessments were performed primarily in the Ashanti Region of Ghana.Participants: All stakeholders relevant to emergency medical services in the Ashanti Region of Ghana were assessed; there was a special focus on National Ambulance Service (NAS) and Ashanti Region healthcare personnel.Intervention: This was an observational study using qualitative and quantitative assessment techniques.Main outcome measures: The structure, function and performance of the Ashanti emergency medical services system, guided by a relevant technical assessment framework.Results: NAS is the premier and only true prehospital agency in the Ashanti Region. NAS has developed almost every essential aspect of an EMS system necessary to achieve its mission within a low-resource setting. NAS continues to increase its number of response units to address the overwhelming Ashanti region demand, especially primary calls. Deficient areas in need of development are governance, reliable revenue, public access, community integration, clinical care guidelines, research and quality assurance processes.Conclusions: The Ashanti Region has a growing and thriving emergency medical services system. Although many essential areas for development were identified, NAS is well poised to meet the regional demand for prehospital emergency care and transport.Keywords: EMS, prehospital, ambulance, emergency, Ghana, Afric

TECHNOLOGY FOR ORGANIC WEED CONTROL

In recent years, crop maintenance works have become a major challenge for organic farming systems, where the application of chemical treatments is totally forbidden. The effect of weeds on crops varies according to pedoclimatic, biological or technological parameters, the resulting damages being both quantitative and qualitative. By weed control, we aim to prevent their competition in order to obtain maximum crop yields.Among the methods of thermal weed control, used as an alternative to chemical weeding, steam or hot water-based ones have been increasingly used as they provide an efficient, environmentally friendly and economical way of removing harmful plants.This paper presents a technology for the maintenance of medicinal and aromatic plant organic crops, based on the use of innovative equipment for weed thermal control by using hot water

Clinical trialist perspectives on the ethics of adaptive clinical trials: a mixed-methods analysis

Abstract Background In an adaptive clinical trial (ACT), key trial characteristics may be altered during the course of the trial according to predefined rules in response to information that accumulates within the trial itself. In addition to having distinguishing scientific features, adaptive trials also may involve ethical considerations that differ from more traditional randomized trials. Better understanding of clinical trial experts’ views about the ethical aspects of adaptive designs could assist those planning ACTs. Our aim was to elucidate the opinions of clinical trial experts regarding their beliefs about ethical aspects of ACTs. Methods We used a convergent, mixed-methods design employing a 22-item ACTs beliefs survey with visual analog scales and open-ended questions and mini-focus groups. We developed a coding scheme to conduct thematic searches of textual data, depicted responses to visual analog scales on box-plot diagrams, and integrated findings thematically. Fifty-three clinical trial experts from four constituent groups participated: academic biostatisticians (n = 5); consultant biostatisticians (n = 6); academic clinicians (n = 22); and other stakeholders including patient advocacy, National Institutes of Health, and U.S. Food and Drug Administration representatives (n = 20). Results The respondents recognized potential ethical benefits of ACTs, including a higher probability of receiving an effective intervention for participants, optimizing resource utilization, and accelerating treatment discovery. Ethical challenges voiced include developing procedures so trial participants can make informed decisions about taking part in ACTs and plausible, though unlikely risks of research personnel altering enrollment patterns. Conclusions Clinical trial experts recognize ethical advantages but also pose potential ethical challenges of ACTs. The four constituencies differ in their weighing of ACT ethical considerations based on their professional vantage points. These data suggest further discussion about the ethics of ACTs is needed to facilitate ACT planning, design and conduct, and ultimately better allow planners to weigh ethical implications of competing trial designs.http://deepblue.lib.umich.edu/bitstream/2027.42/111302/1/12910_2015_Article_22.pd