802 research outputs found
Fragility and compressibility at the glass transition
Isothermal compressibilities and Brillouin sound velocities from the
literature allow to separate the compressibility at the glass transition into a
high-frequency vibrational and a low-frequency relaxational part. Their ratio
shows the linear fragility relation discovered by x-ray Brillouin scattering
[1], though the data bend away from the line at higher fragilities. Using the
concept of constrained degrees of freedom, one can show that the vibrational
part follows the fragility-independent Lindemann criterion; the fragility
dependence seems to stem from the relaxational part. The physical meaning of
this finding is discussed. [1] T. Scopigno, G. Ruocco, F. Sette and G. Monaco,
Science 302, 849 (2003)Comment: 4 pages, 2 figures, 2 tables, 33 references. Slightly changed after
refereein
Dynamic vehicle routing with time windows in theory and practice
The vehicle routing problem is a classical combinatorial optimization
problem. This work is about a variant of the vehicle routing problem
with dynamically changing orders and time windows. In real-world
applications often the demands change during operation time. New orders
occur and others are canceled. In this case new schedules need to be
generated on-the-fly. Online optimization algorithms for dynamical
vehicle routing address this problem but so far they do not consider
time windows. Moreover, to match the scenarios found in real-world
problems adaptations of benchmarks are required. In this paper, a
practical problem is modeled based on the procedure of daily routing of a
delivery company. New orders by customers are introduced dynamically
during the working day and need to be integrated into the schedule. A
multiple ant colony algorithm combined with powerful local search
procedures is proposed to solve the dynamic vehicle routing problem with
time windows. The performance is tested on a new benchmark based on
simulations of a working day. The problems are taken from Solomon’s
benchmarks but a certain percentage of the orders are only revealed to
the algorithm during operation time. Different versions of the MACS
algorithm are tested and a high performing variant is identified.
Finally, the algorithm is tested in situ: In a field study, the
algorithm schedules a fleet of cars for a surveillance company. We
compare the performance of the algorithm to that of the procedure used
by the company and we summarize insights gained from the implementation
of the real-world study. The results show that the multiple ant colony
algorithm can get a much better solution on the academic benchmark
problem and also can be integrated in a real-world environment
Deforming glassy polystyrene: Influence of pressure, thermal history, and deformation mode on yielding and hardening
The toughness of a polymer glass is determined by the interplay of yielding, strain softening, and strain hardening. Molecular-dynamics simulations of a typical polymer glass, atactic polystyrene, under the influence of active deformation have been carried out to enlighten these processes. It is observed that the dominant interaction for the yield peak is of interchain nature and for the strain
hardening of intrachain nature. A connection is made with the microscopic cage-to-cage motion. It is found that the deformation does not lead to complete erasure of the thermal history but that differences persist at large length scales. Also we find that the strain-hardening modulus increases with increasing external pressure. This new observation cannot be explained by current theories
such as the one based on the entanglement picture and the inclusion of this effect will lead to an improvement in constitutive modeling
Augmented Reality in Astrophysics
Augmented Reality consists of merging live images with virtual layers of
information. The rapid growth in the popularity of smartphones and tablets over
recent years has provided a large base of potential users of Augmented Reality
technology, and virtual layers of information can now be attached to a wide
variety of physical objects. In this article, we explore the potential of
Augmented Reality for astrophysical research with two distinct experiments: (1)
Augmented Posters and (2) Augmented Articles. We demonstrate that the emerging
technology of Augmented Reality can already be used and implemented without
expert knowledge using currently available apps. Our experiments highlight the
potential of Augmented Reality to improve the communication of scientific
results in the field of astrophysics. We also present feedback gathered from
the Australian astrophysics community that reveals evidence of some interest in
this technology by astronomers who experimented with Augmented Posters. In
addition, we discuss possible future trends for Augmented Reality applications
in astrophysics, and explore the current limitations associated with the
technology. This Augmented Article, the first of its kind, is designed to allow
the reader to directly experiment with this technology.Comment: 15 pages, 11 figures. Accepted for publication in Ap&SS. The final
publication will be available at link.springer.co
Fatty Acid Methyl Esters as Biosolvents of Epoxy Resins: A Physicochemical Study
The C8 to C18 fatty acid methyl esters (FAME) have been compared as solvents for two epoxy resin pre-polymers, bisphenol A diglycidyl ether (DGEBA) and triglycidyl paminophenol ether (TGPA). It was found that the solubilization limits vary according to the ester and that methyl caprylate is the best solvent of both resins. To explain these solubility performances, physical and chemical properties of FAME were studied, such as the Hansen parameters, viscosity, binary diffusion coefficient and vaporization enthalpy. Determination of the physicochemical parameters of FAME was carried out by laboratory experimentations and by calculation from bibliographic data. The Hansen parameters of FAME and epoxy resins pre-polymers were theoretically and experimentally determined. The FAME chain length showed a long dependence on the binary diffusion parameters and kinematic viscosity, which are mass and momentum transport properties. Moreover, the vaporization enthalpy of these compounds was directly correlated with the solubilization limits
Dynamic vehicle routing with time windows in theory and practice
The vehicle routing problem is a classical combinatorial optimization
problem. This work is about a variant of the vehicle routing problem
with dynamically changing orders and time windows. In real-world
applications often the demands change during operation time. New
orders occur and others are canceled. In this case new schedules
need to be generated on-the-fly. Online optimization algorithms for
dynamical vehicle routing address this problem but so far they do
not consider time windows. Moreover, to match the scenarios found
in real-world problems adaptations of benchmarks are required. In
this paper, a practical problem is modeled based on the procedure
of daily routing of a delivery company. New orders by customers are
introduced dynamically during the working day and need to be integrated
into the schedule. A multiple ant colony algorithm combined with
powerful local search procedures is proposed to solve the dynamic
vehicle routing problem with time windows. The performance is tested
on a new benchmark based on simulations of a working day. The problems
are taken from Solomon's benchmarks but a certain percentage of the
orders are only revealed to the algorithm during operation time.
Different versions of the MACS algorithm are tested and a high performing
variant is identified. Finally, the algorithm is tested in situ:
In a field study, the algorithm schedules a fleet of cars for a surveillance
company. We compare the performance of the algorithm to that of the
procedure used by the company and we summarize insights gained from
the implementation of the real-world study. The results show that
the multiple ant colony algorithm can get a much better solution
on the academic benchmark problem and also can be integrated in a
real-world environment.Algorithms and the Foundations of Software technolog
On temperature- and space-dimension dependent matter agglomeration in a mature growing stage
Model matter agglomerations, with temperature as leading control parameter,
have been considered, and some of their characteristics have been studied. The
primary interest has been focused on the grain volume fluctuations, the
magnitude of which readily differentiates between two commonly encountered
types of matter agglomeration/aggregation processes, observed roughly for high-
and low-density matter organizations. The two distinguished types of matter
arrangements have been described through the (entropic) potential driving
system. The impact of the potential type on the character of matter
agglomeration has been studied, preferentially for (low density) matter
agglomeration for which a logarithmic measure of its speed has been proposed. A
common diffusion as well as mechanical relaxation picture, emerging during the
mature growing stage, has been drawn using a phenomenological line of
argumentation. Applications, mostly towards obtaining soft agglomerates of
so-called jammed materials, have been mentioned
Transitions/relaxations in polyester adhesive/PET system
The correlations between the transitions and the dielectric relaxation processes of the oriented poly(ethylene terephthalate) (PET) pre-impregnated of the polyester thermoplastic adhesive have been investigated by differential scanning calorimetry (DSC) and dynamic dielectric spectroscopy (DDS). The thermoplastic polyester adhesive and the oriented PET films have been studied as reference samples. This study evidences that the adhesive chain segments is responsible for the physical structure evolution in the PET-oriented film. The transitions and dielectric relaxation modes’ evolutions in the glass transition region appear characteristic of the interphase between adhesive and PET film, which is discussed in terms of molecular mobility. The storage at room temperature of the adhesive tape involves the heterogeneity of the physical structure, characterized by glass transition dissociation. Thus, the correlation between the transitions and the dielectric relaxation processes evidences a segregation of the amorphous phases. Therefore, the physical structure and the properties of the material have been linked to the chemical characteristics
Cone calorimetry studies of fire retardant soybean-oil-based copolymers containing silicon or boron: Comparison of additive and reactive approaches
CO<inf>2</inf> absorption using diethanolamine-water solutions in a rotating spiral contactor
Results for mass transfer in a rotating spiral device are presented here for absorption of carbon dioxide from nitrogen carrier gas using mixtures of diethanolamine (DEA) and water. The ability of the device to examine the full range of flow rate ratio for the two phases while controlling the relative thicknesses of the phase layers is applied to surveying absorption performance over a wide range of DEA concentration at 312 K and 1.8 bara. Comparisons are made for a fixed 86 μm liquid layer thickness, which is shown to fix also the fraction of the liquid accessible by diffusion, while maintaining 90% removal of CO2 from a gas stream of 10% (mole) CO2 in nitrogen. The increasing liquid viscosity with DEA fraction is countered by reducing the liquid flow rate to maintain constant liquid layer thickness and diffusion depth. The allowed gas throughput, while meeting 90% removal, increases with DEA concentration until the increasing viscosity gives sufficient reduction in liquid flow rate to offset the increasing CO2 capacity of the liquid. The maximum gas flow rate has a broad peak centred at a DEA mole fraction of about 0.072 (31% by mass). Utilisation of the amine is increased as DEA concentration increases, apparently as a result of the longer residence time, suggesting an effect of chemical time scales on the order of seconds. For a fixed concentration, full utilisation of the amine is achieved by decreasing the liquid flow rate, which reduces layer thickness and increases diffusion time. The work highlights the use of the rotating spiral for rapid and accurate testing to determine optimum liquid composition of absorbent formulations
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