256 research outputs found

    Evidence for vivianite formation and its contribution to long-term phosphorus retention in a recent lake sediment: a novel analytical approach

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    Vivianite, Fe3(PO4)2 · 8 H2O, is a ferrous iron phosphate mineral which forms in waterlogged soils and sediments. The phosphorus (P) bound in its crystal lattice is considered to be immobilised because vivianite is stable under anoxic, reducing, sedimentary conditions. Thus, vivianite formation can make a major contribution to P retention during early diagenesis. Much remains unknown about vivianite in sediments, because technical challenges have rendered direct identification and quantification difficult. To identify vivianite and assess its significance for P burial during early diagenesis we studied the consequences of a 1992/1993 in-lake application of FeCl3 and Fe(OH)3 aimed at restoring Lake Groß-Glienicke (Berlin, Germany). In a novel approach, we firstly applied a heavy-liquid separation to the iron-rich surface sediments which allowed direct identification of vivianite by X-ray diffraction in the high-density (ρ > 2.3 g cm−3) sediment fraction. Secondly, we assessed the contribution of vivianite to P retention, combining results from chemical digestion with magnetic susceptibility data derived from magnetic hysteresis measurements. Scanning electron microscopy revealed that the dark blue spherical vivianite nodules were 40–180 μm in diameter, and formed of platy- and needle-shaped crystal aggregates. Although equilibrium calculations indicated supersaturation of vivianite throughout the upper 30 cm of the sediment, the vivianite deposits were homogeneously distributed within, and restricted to, the upper 23 cm only. Thus, supersaturated pore water alone cannot serve as a reliable predictor for the in situ formation of vivianite. In Lake Groß -Glienicke, vivianite formation continues to be triggered by the artificial iron amendment more than 20 yr ago, significantly contributing to P retention in surface sediments

    Lambda-effect from forced turbulence simulations

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    Aims: We determine the components of the Λ\Lambda-effect tensor that quantifies the contributions to the turbulent momentum transport even for uniform rotation. Methods: Three-dimensional numerical simulations are used to study turbulent transport in triply periodic cubes under the influence of rotation and anisotropic forcing. Comparison is made with analytical results obtained via the so-called minimal tau-approximation. Results: In the case where the turbulence intensity in the vertical direction dominates, the vertical stress is always negative. This situation is expected to occur in stellar convection zones. The horizontal component of the stress is weaker and exhibits a maximum at latitude 30 degrees - regardless of how rapid the rotation is. The minimal tau-approximation captures many of the qualitative features of the numerical results, provided the relaxation time tau is close to the turnover time, i.e. the Strouhal number is of order unity.Comment: 20 pages, 14 figures, accepted for publication in Astronomy & Astrophysic

    Non-inversion conservation tillage as an underestimated driver of tillage erosion

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    Tillage erosion is a widely underestimated process initiating soil degradation especially in case of large agricultural fields located in rolling topography. It is often assumed that, conservation, non-inversion tillage causes less tillage erosion than conventional inversion tillage. In this study, tillage erosion was determined on three paired plots comparing non-inversion chisel versus inversion mouldboard tillage. The experiments were performed at three sites in Northeast Germany with gentle, moderate, and steep slope, while tillage depth (0.25 m) and speed (≈ 6 km h−1) were kept constant during all experiments. The results indicate that non-inversion tillage produces significantly more soil movement compared to inversion tillage. The soil translocation distance was by a factor of 1.3–2.1 larger in case of chisel tillage. The largest difference in translocation distance and tillage transport coefficient (ktil) was found on the gentle slope exhibiting the lowest soil cohesion. Our results together with an evaluation of ktil values derived from literature and standardised for 0.25 m tillage depth contradict the general assumption that non-inversion tillage reduces tillage erosion. In tillage erosion dominated areas, non-inversion tillage applied with high tillage speed and depth potentially increases tillage erosion and fails its purpose to serve as soil conservation measure

    NON INTRUSIVE MEASUREMENTS OF A LPP COMBUSTOR UNDER ELEVATED PRESSURE CONDITIONS

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    ABSTRACT To meet increasingly tight regulations on emission control appropriate combustor designs need to be developed. With different combustion concepts like RQL (Rich Quench Lean) and LPP (Lean Premixed Prevaporized) it has been proven that it is possible to reach the objective of a significant reduction of the NO X emissions. To gain further insight into the real combustion process it is of importance to be able to "look into" the flame without interfering with the actual combustion process. At the combustion laboratory of the Institute of Flight Propulsion at Munich University of Technology a combustion test facility is set up to study combustion characteristics under pressure up to 6 bar and inlet airflow temperature up to 650 K. A newly designed LPP concept was adapted into an optically accessible model combustion chamber. The objective of the study was to operate the LPP combustor under semi-realistic conditions and to obtain more knowledge on the influence of pressure on the combustion process. With suitable non-intrusive laser-spectroscopic measuring techniques like LIF (Laser Induced Fluorescence) the fuel spray, the nitric oxides and the hydroxyl radical were detected in several planes parallel to the combustor axis at different combustor pressures. As expected the pressure has a strong effect on droplet distribution and evaporation. Also with increasing pressure it was possible to operate the combustor under leaner conditions. A strong dependence on pressure of the formation of nitric oxides was detected. To quantify these results samples with a water-cooled probe were taken, analyzed and compared with the non intrusive measurements

    Upper bounds on the density of states of single Landau levels broadened by Gaussian random potentials

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    We study a non-relativistic charged particle on the Euclidean plane R^2 subject to a perpendicular constant magnetic field and an R^2-homogeneous random potential in the approximation that the corresponding random Landau Hamiltonian on the Hilbert space L^2(R^2) is restricted to the eigenspace of a single but arbitrary Landau level. For a wide class of Gaussian random potentials we rigorously prove that the associated restricted integrated density of states is absolutely continuous with respect to the Lebesgue measure. We construct explicit upper bounds on the resulting derivative, the restricted density of states. As a consequence, any given energy is seen to be almost surely not an eigenvalue of the restricted random Landau Hamiltonian.Comment: 16 pages, to appear in "Journal of Mathematical Physics

    An integrated—omics/chemistry approach unravels enzymatic and spontaneous steps to form flavoalkaloidal nudicaulin pigments in flowers of Papaver nudicaule L.

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    Flower colour is an important trait for plants to attract pollinators and ensure their reproductive success. Among yellow flower pigments, the nudicaulins in Papaver nudicaule L. (Iceland poppy) are unique due to their rarity and unparalleled flavoalkaloid structure. Nudicaulins are derived from pelargonidin glycoside and indole, products of the flavonoid and indole/tryptophan biosynthetic pathway, respectively. To gain insight into the molecular and chemical basis of nudicaulin biosynthesis, we combined transcriptome, differential gel electrophoresis (DIGE)-based proteome, and ultra-performance liquid chromatography–high resolution mass spectrometry (UPLC-HRMS)-based metabolome data of P. nudicaule petals with chemical investigations. We identified candidate genes and proteins for all biosynthetic steps as well as some key metabolites across five stages of petal development. Candidate genes of amino acid biosynthesis showed a relatively stable expression throughout petal development, whereas most candidate genes of flavonoid biosynthesis showed increasing expression during development followed by downregulation in the final stage. Notably, gene candidates of indole-3-glycerol-phosphate lyase (IGL), sharing characteristic sequence motifs with known plant IGL genes, were co-expressed with flavonoid biosynthesis genes, and are probably providing free indole. The fusion of indole with pelargonidin glycosides was retraced synthetically and promoted by high precursor concentrations, an excess of indole, and a specific glycosylation pattern of pelargonidin. Thus, nudicaulin biosynthesis combines the enzymatic steps of two different pathways with a spontaneous fusion of indole and pelargonidin glycoside under precisely tuned reaction conditions

    Early diagenetic vivianite [Fe-3(PO4)(2) center dot 8H(2)O] in a contaminated freshwater sediment and insights into zinc uptake: a mu-EXAFS, mu-XANES and Raman study

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    The sediments in the Salford Quays, a heavily-modified urban water body, contain high levels of organic matter, Fe, Zn and nutrients as a result of past contaminant inputs. Vivianite [Fe3(PO4)2 · 8H2O] has been observed to have precipitated within these sediments during early diagenesis as a result of the release of Fe and P to porewaters. These mineral grains are small (<100 μm) and micron-scale analysis techniques (SEM, electron microprobe, μ-EXAFS, μ-XANES and Raman) have been applied in this study to obtain information upon the structure of this vivianite and the nature of Zn uptake in the mineral. Petrographic observations, and elemental, X-ray diffraction and Raman spectroscopic analysis confirms the presence of vivianite. EXAFS model fitting of the FeK-edge spectra for individual vivianite grains produces Fe–O and Fe–P co-ordination numbers and bond lengths consistent with previous structural studies of vivianite (4O atoms at 1.99–2.05 Å; 2P atoms at 3.17–3.25 Å). One analysed grain displays evidence of a significant Fe3+ component, which is interpreted to have resulted from oxidation during sample handling and/or analysis. EXAFS modelling of the Zn K-edge data, together with linear combination XANES fitting of model compounds, indicates that Zn may be incorporated into the crystal structure of vivianite (4O atoms at 1.97 Å; 2P atoms at 3.17 Å). Low levels of Zn sulphate or Zn-sorbed goethite are also indicated from linear combination XANES fitting and to a limited extent, the EXAFS fitting, the origin of which may either be an oxidation artifact or the inclusion of Zn sulphate into the vivianite grains during precipitation. This study confirms that early diagenetic vivianite may act as a sink for Zn, and potentially other contaminants (e.g. As) during its formation and, therefore, forms an important component of metal cycling in contaminated sediments and waters. Furthermore, for the case of Zn, the EXAFS fits for Zn phosphate suggest this uptake is structural and not via surface adsorption

    Low lying spectrum of weak-disorder quantum waveguides

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    We study the low-lying spectrum of the Dirichlet Laplace operator on a randomly wiggled strip. More precisely, our results are formulated in terms of the eigenvalues of finite segment approximations of the infinite waveguide. Under appropriate weak-disorder assumptions we obtain deterministic and probabilistic bounds on the position of the lowest eigenvalue. A Combes-Thomas argument allows us to obtain so-called 'initial length scale decay estimates' at they are used in the proof of spectral localization using the multiscale analysis.Comment: Accepted for publication in Journal of Statistical Physics http://www.springerlink.com/content/0022-471
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