Magnetic microstructure of nanostructured Fe, studied by small angle neutron scattering

Small angle neutron scattering (SANS) was applied to achieve insight into the magnetic correlations in nanostructured Fe. The results confirm the expected microstructure involving ferromagnetic grains and a nonmagnetic or weakly magnetic interface region, the interfaces occupying about half the specimen volume. The SANS measurements further reveal that in nanostructured Fe the magnetic correlations are not confined to single grains, but are extended across the interfaces and result in the alignment of the magnetization over several hundreds of grains. An external field of 1.5 kOe is not sufficient for complete magnetic alignment of the entire specimen. However, the long-range magnetic correlations are considerably disturbed by this field. Reducing the external magnetic field to zero causes the magnetic correlations to resume microstructural characteristics similar to what they had in the original stat

Low temperature shape relaxation of 2-d islands by edge diffusion

We present a precise microscopic description of the limiting step for low temperature shape relaxation of two dimensional islands in which activated diffusion of particles along the boundary is the only mechanism of transport allowed. In particular, we are able to explain why the system is driven irreversibly towards equilibrium. Based on this description, we present a scheme for calculating the duration of the limiting step at each stage of the relaxation process. Finally, we calculate numerically the total relaxation time as predicted by our results and compare it with simulations of the relaxation process.Comment: 11 pages, 5 figures, to appear in Phys. Rev.

Structural and optical studies of FeSb2 under high pressure

Nanostructured orthorhombic FeSb2 and an amorphous phase were formed by mechanical alloying starting from a mixture of high purity elemental Fe and Sb powders. The effects of high pressures on structural and optical properties were studied using X-ray diffraction (XRD) and Raman spectroscopy (RS). XRD patterns showed the presence of the orthorhombic FeSb2 phase up to the maximum pressure applied (28.2 GPa). The XRD patterns showed also an increase in the amount of the amorphous phase with increasing pressure up to 23.3 GPa. At 14.3 GPa, together with the former phases, a new phase was observed and indexed to a tetragonal FeSb2 phase, but its volume fraction is small at least up to 23.3 GPa. For the orthorhombic FeSb2 phase, the pressure dependence of the volume fitted to a Birch-Murnaghan equation of state gave a bulk modulus = 74.2 +- 3.0 GPa and its pressure derivative = 7.5 +- 0.6. RS measurements were performed from atmospheric pressure up to 45.2 GPa. For the orthorhombic FeSb2 phase, the Raman active mode was observed up to the maximum pressure applied, while the mode disappeared at 16.6 GPa. For pressures higher than 21 GPa, the Raman active mode of a tetragonal FeSb2 phase was observed, confirming ab initio calculations reported in the literature.Comment: 31 pages, 11 figures and 2 tables. Already submitted for publicatio

Admixed pellets for fast and efficient delivery of plasma enhancement gases: Investigations at AUG exploring the option for EU-DEMO

Gas and pellet injection are envisaged for particle fuelling in EU-DEMO. The gas system will provide edge and divertor fuelling and any further gas species required for operation. Pellets, mm-sized bodies formed from solid hydrogen fuel, are designed for efficient and fast core fuelling. However, they can also be employed for a more efficient delivery of plasma enhancement gases, by admixing them with the fuelling pellets. To check this option for EU-DEMO, explorative investigations have been performed at ASDEX Upgrade (AUG). The AUG system produces ice in a batch process sufficient for about 100 pellets, initially designed for operation with pure H$_2$ or D$_2$. On a trial basis, pellet formation was tested using an H$_2$/D$_2$ mixture and admixtures containing small amounts (up to 2 mol%) of N$_2$, Ar, Kr or Xe in the D$_2$ host. A homogeneous and reproducible ice composition was found for the H$_2$/D$_2$ = 1:1 case. For all the admixed gases, a depletion of the admixture in the ice with increasing atomic number is observed. Nevertheless, the fast and efficient delivery of admixed pellets was clearly demonstrated in dedicated plasma experiments at AUG. Detailed investigations showed that the Ar supplied via admixed pellets has a higher radiation efficiency and a faster radiation rise than an Ar/D$_2$ gas puff. Furthermore, Ar density measurements in a discharge with admixed pellet injection show reasonable agreement with findings of a fading admixed species’ concentration along the ice rod and assumptions on the pellet ablation location in the plasma. Investigations performed at the Oak Ridge National Laboratory with a large batch extruder using up to 2 mol% Ne in D$_2$ confirmed that production of much larger ice quantities can be achieved. These initial explorative investigations clearly reveal the great potential of admixed pellets, although they also demonstrate that further technology efforts are required before their benefits can be utilized

Genetic Selection for Enhanced Folding In Vivo Targets the Cys14-Cys38 Disulfide Bond in Bovine Pancreatic Trypsin Inhibitor

The periplasm provides a strongly oxidizing environment; however, periplasmic expression of proteins with disulfide bonds is often inefficient. Here, we used two different tripartite fusion systems to perform in vivo selections for mutants of the model protein bovine pancreatic trypsin inhibitor (BPTI) with the aim of enhancing its expression in Escherichia coli. This trypsin inhibitor contains three disulfides that contribute to its extreme stability and protease resistance. The mutants we isolated for increased expression appear to act by eliminating or destabilizing the Cys14-Cys38 disulfide in BPTI. In doing so, they are expected to reduce or eliminate kinetic traps that exist within the well characterized in vitro folding pathway of BPTI. These results suggest that elimination or destabilization of a disulfide bond whose formation is problematic in vitro can enhance in vivo protein folding. The use of these in vivo selections may prove a valuable way to identify and eliminate disulfides and other rate-limiting steps in the folding of proteins, including those proteins whose in vitro folding pathways are unknown. Antioxid. Redox Signal. 14, 973-984.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/90494/1/ars-2E2010-2E3712.pd

A Versatile Route for the Synthesis of Nickel Oxide Nanostructures Without Organics at Low Temperature

Nickel oxide nanoparticles and nanoflowers have been synthesized by a soft reaction of nickel powder and water without organics at 100 °C. The mechanism for the formation of nanostructures is briefly described in accordance with decomposition of metal with water giving out hydrogen. The structure, morphology, and the crystalline phase of resulting nanostructures have been characterized by various techniques. Compared with other methods, the present method is simple, fast, economical, template-free, and without organics. In addition, the approach is nontoxic without producing hazardous waste and could be expanded to provide a general and convenient strategy for the synthesis of nanostructures to other functional nanomaterials

Fabrication of full density near-nanostructured cemented carbides by combination of VC/Cr3C2 addition and consolidation by SPS and HIP technologies

The aim of present work is to study the effect of VC and/or Cr3C2 in densification, microstructural development and mechanical behavior of nanocrystalline WC-12wt.%Co powders when they are sintered by spark plasma sintering (SPS) and hot isostatic pressing (HIP). The results were compared to those corresponding to conventional sintering in vacuum. The density, microstructure, X-ray diffraction, hardness and fracture toughness of the sintered materials were evaluated. Materials prepared by SPS exhibits full densification at lower temperature (1100 degrees C) and a shorter stay time (5 min), allowing the grain growth control. However, the effect of the inhibitors during SPS process is considerably lower than in conventional sintering. Materials prepared by HIP at 1100 degrees C and 30 min present full densification and a better control of microstructure in the presence of VC. The added amount of VC allows obtaining homogeneous microstructures with an average grain size of 120 nm. The hardness and fracture toughness values obtained were about 2100 HV30 and close to 10 MPa m(1/)2, respectively. (C) 2010 Elsevier Ltd. All rights reserved.The work is supported financially by the Spanish Ministry of Science and Innovation by means of the project MAT 2006-12945-C03-C02 and MAT 2009-14144-C03-C02.Bonache Bezares, V.; Salvador Moya, MD.; Fernández Valdés, A.; Borrell Tomás, MA. (2011). Fabrication of full density near-nanostructured cemented carbides by combination of VC/Cr3C2 addition and consolidation by SPS and HIP technologies. International Journal of Refractory Metals and Hard Materials. 29(2):202-208. https://doi.org/10.1016/j.ijrmhm.2010.10.007S20220829