1,050 research outputs found
Parallel ion strings in linear multipole traps
Additional radio-frequency (rf) potentials applied to linear multipole traps
create extra field nodes in the radial plane which allow one to confine single
ions, or strings of ions, in totally rf field-free regions. The number of nodes
depends on the order of the applied multipole potentials and their relative
distance can be easily tuned by the amplitude variation of the applied
voltages. Simulations using molecular dynamics show that strings of ions can be
laser cooled down to the Doppler limit in all directions of space. Once cooled,
organized systems can be moved with very limited heating, even if the cooling
process is turned off
Bioergographie des Pharmakologen Otto Riesser (1882-1949)
Otto Max Riesser war nicht nur ein hervorragender Mediziner, Pharmakologe und Physiologe, sondern als Hochschullehrer hatte er auch eine Reihe junger Wissenschaftler ausgebildet, die später namhafte Forscher wurden. Riesser war von 1932 bis 1938 Mitglied der Deutschen Akademie der Naturforscher in Halle/Saale, er gehörte dem Vorstand der Deutschen Pharmakologischen Gesellschaft an, und im „Biographischen Lexikon der hervorragenden Ärzte der letzten fünfzig Jahre 1880-1930“ gibt es unter seinem Namen einen Eintrag. Die Liste seiner wissenschaftlichen Arbeiten und die Zahl seiner Schüler wären mit Sicherheit umfangreicher gewesen, wenn man ihn ab 1933, wegen seiner jüdischen Herkunft, nicht diskriminiert und verfolgt hätte. Seitdem konnte er dem wissenschaftlichen Arbeiten unter normalen Bedingungen nicht mehr nachgehen
Radiofrequency multipole traps: Tools for spectroscopy and dynamics of cold molecular ions
Multipole radiofrequency ion traps are a highly versatile tool to study
molecular ions and their interactions in a well-controllable environment. In
particular the cryogenic 22-pole ion trap configuration is used to study
ion-molecule reactions and complex molecular spectroscopy at temperatures
between few Kelvin and room temperatures. This article presents a tutorial on
radiofrequency ion trapping in multipole electrode configurations. Stable
trapping conditions and buffer gas cooling, as well as important heating
mechanisms, are discussed. In addition, selected experimental studies on cation
and anion-molecule reactions and on spectroscopy of trapped ions are reviewed.
Starting from these studies an outlook on the future of multipole ion trap
research is given
An ion ring in a linear multipole trap for optical frequency metrology
A ring crystal of ions trapped in a linear multipole trap is studied as a
basis for an optical frequency standard. The equilibrium conditions and cooling
possibilities are discussed through an analytical model and molecular dynamics
simulations. A configuration which reduces the frequency sensitivity to the
fluctuations of the number of trapped ions is proposed. The systematic shifts
for the electric quadrupole transition of calcium ions are evaluated for this
ring configuration. This study shows that a ring of 10 or 20 ions allows to
reach a short term stability better than for a single ion without introducing
limiting long term fluctuations
Non-Destructive Identification of Cold and Extremely Localized Single Molecular Ions
A simple and non-destructive method for identification of a single molecular
ion sympathetically cooled by a single laser cooled atomic ion in a linear Paul
trap is demonstrated. The technique is based on a precise determination of the
molecular ion mass through a measurement of the eigenfrequency of a common
motional mode of the two ions. The demonstrated mass resolution is sufficiently
high that a particular molecular ion species can be distinguished from other
equally charged atomic or molecular ions having the same total number of
nucleons
Falsification Of The Atmospheric CO2 Greenhouse Effects Within The Frame Of Physics
The atmospheric greenhouse effect, an idea that many authors trace back to
the traditional works of Fourier (1824), Tyndall (1861), and Arrhenius (1896),
and which is still supported in global climatology, essentially describes a
fictitious mechanism, in which a planetary atmosphere acts as a heat pump
driven by an environment that is radiatively interacting with but radiatively
equilibrated to the atmospheric system. According to the second law of
thermodynamics such a planetary machine can never exist. Nevertheless, in
almost all texts of global climatology and in a widespread secondary literature
it is taken for granted that such mechanism is real and stands on a firm
scientific foundation. In this paper the popular conjecture is analyzed and the
underlying physical principles are clarified. By showing that (a) there are no
common physical laws between the warming phenomenon in glass houses and the
fictitious atmospheric greenhouse effects, (b) there are no calculations to
determine an average surface temperature of a planet, (c) the frequently
mentioned difference of 33 degrees Celsius is a meaningless number calculated
wrongly, (d) the formulas of cavity radiation are used inappropriately, (e) the
assumption of a radiative balance is unphysical, (f) thermal conductivity and
friction must not be set to zero, the atmospheric greenhouse conjecture is
falsified.Comment: 115 pages, 32 figures, 13 tables (some typos corrected
The chemistry of vibrationally excited H2 in the interstellar medium
The internal energy available in vibrationally excited H2 molecules can be
used to overcome or diminish the activation barrier of various chemical
reactions of interest for molecular astrophysics. In this article we
investigate in detail the impact on the chemical composition of interstellar
clouds of the reactions of vibrationally excited H2 with C+, He+, O, OH, and
CN, based on the available chemical kinetics data. It is found that the
reaction of H2 (v>0) and C+ has a profound impact on the abundances of some
molecules, especially CH+, which is a direct product and is readily formed in
astronomical regions with fractional abundances of vibrationally excited H2,
relative to ground state H2, in excess of 10^(-6), independently of whether the
gas is hot or not. The effects of these reactions on the chemical composition
of the diffuse clouds zeta Oph and HD 34078, the dense PDR Orion Bar, the
planetary nebula NGC 7027, and the circumstellar disk around the B9 star HD
176386 are investigated through PDR models. We find that formation of CH+ is
especially favored in dense and highly FUV illuminated regions such as the
Orion Bar and the planetary nebula NGC 7027, where column densities in excess
of 10^(13) cm^(-2) are predicted. In diffuse clouds, however, this mechanism is
found to be not efficient enough to form CH+ with a column density close to the
values derived from astronomical observations.Comment: accepted for publication in the Astrophysical Journal; 9 pages, 7
figure
New method to study ion-molecule reactions at low temperatures and application to the H + H H + H reaction
Studies of ion-molecule reactions at low temperatures are difficult because
stray electric fields in the reaction volume affect the kinetic energy of
charged reaction partners. We describe a new experimental approach to study
ion-molecule reactions at low temperatures and present, as example, a
measurement of the
reaction with the ion prepared in a single rovibrational state at
collision energies in the range -60 K. To reach such
low collision energies, we use a merged-beam approach and observe the reaction
within the orbit of a Rydberg electron, which shields the ions from stray
fields. The first beam is a supersonic beam of pure ground-state H
molecules and the second is a supersonic beam of H molecules excited to
Rydberg-Stark states of principal quantum number selected in the range
20-40. Initially, the two beams propagate along axes separated by an angle of
10. To merge the two beams, the Rydberg molecules in the latter beam
are deflected using a surface-electrode Rydberg-Stark deflector. The collision
energies of the merged beams are determined by measuring the velocity
distributions of the two beams and they are adjusted by changing the
temperature of the pulsed valve used to generate the ground-state
beam and by adapting the electric-potential functions to the electrodes of the
deflector. The collision energy is varied down to below K, i.e., below meV, with an energy resolution of 100
eV. We demonstrate that the Rydberg electron acts as a spectator and does
not affect the cross sections, which are found to closely follow a
classical-Langevin-capture model in the collision-energy range investigated.
Because all neutral atoms and molecules can be excited to Rydberg states, this
method of studyingComment: 39 pages, 10 figure
Blackbody-radiation-assisted molecular laser cooling
The translational motion of molecular ions can be effectively cooled
sympathetically to temperatures below 100 mK in ion traps through Coulomb
interactions with laser-cooled atomic ions. The distribution of internal
rovibrational states, however, gets in thermal equilibrium with the typically
much higher temperature of the environment within tens of seconds. We consider
a concept for rotational cooling of such internally hot, but translationally
cold heteronuclear diatomic molecular ions. The scheme relies on a combination
of optical pumping from a few specific rotational levels into a ``dark state''
with redistribution of rotational populations mediated by blackbody radiation.Comment: 4 pages, 5 figure
Spectroscopy and dissociative recombination of the lowest rotational states of H3+
The dissociative recombination of the lowest rotational states of H3+ has
been investigated at the storage ring TSR using a cryogenic 22-pole
radiofrequency ion trap as injector. The H3+ was cooled with buffer gas at ~15
K to the lowest rotational levels, (J,G)=(1,0) and (1,1), which belong to the
ortho and para proton-spin symmetry, respectively. The rate coefficients and
dissociation dynamics of H3+(J,G) populations produced with normal- and para-H2
were measured and compared to the rate and dynamics of a hot H3+ beam from a
Penning source. The production of cold H3+ rotational populations was
separately studied by rovibrational laser spectroscopy using chemical probing
with argon around 55 K. First results indicate a ~20% relative increase of the
para contribution when using para-H2 as parent gas. The H3+ rate coefficient
observed for the para-H2 source gas, however, is quite similar to the H3+ rate
for the normal-H2 source gas. The recombination dynamics confirm that for both
source gases, only small populations of rotationally excited levels are
present. The distribution of 3-body fragmentation geometries displays a broad
part of various triangular shapes with an enhancement of ~12% for events with
symmetric near-linear configurations. No large dependences on internal state or
collision energy are found.Comment: 10 pages, 9 figures, to be published in Journal of Physics:
Conference Proceeding
- …