427 research outputs found
Mapping the Wigner distribution function of the Morse oscillator into a semi-classical distribution function
The mapping of the Wigner distribution function (WDF) for a given bound-state
onto a semiclassical distribution function (SDF) satisfying the Liouville
equation introduced previously by us is applied to the ground state of the
Morse oscillator. Here we give results showing that the SDF gets closer to the
corresponding WDF as the number of levels of the Morse oscillator increases. We
find that for a Morse oscillator with one level only, the agreement between the
WDF and the mapped SDF is very poor but for a Morse oscillator of ten levels it
becomes satisfactory.Comment: Revtex, 27 pages including 13 eps figure
String Picture of Bose-Einstein Condensation
A nonrelativistic Bose gas is represented as a grand-canonical ensemble of
fluctuating closed spacetime strings of arbitrary shape and length. The loops
are characterized by their string tension and the number of times they wind
around the imaginary time axis. At the temperature where Bose-Einstein
condensation sets in, the string tension, being determined by the chemical
potential, vanishes, the system becomes critical, and the strings proliferate.
A comparison with Feynman's description in terms of rings of cyclicly permuted
bosons shows that the winding number of a loop corresponds to the number of
particles contained in a ring.Comment: 13 pages, 6 figures; references adde
Ultrasound assisted electrodeposition of Cu-SiO2 composite coatings: Effect of particle surface chemistry
Electrodeposition of Cu-SiO2 composite coatings from an alkaline non-cyanide electrolyte containing glutamate as complexing agent was studied. Silica mesoporous particles were synthesized using a modified Stöber methodology, and later their surface chemistry was changed by functionalizing them with 3-aminopropyltriethoxysilane. Particles microstructure and morphology were characterized (SEM, TEM, XRD) and their charging behavior in several electrolytes was studied through ζ-potential measurements. Galvanostatic deposition was performed in electrolytes containing both as-prepared and functionalized SiO2 at various current densities, and the influence of ultrasonic irradiation (37 Hz) was evaluated. For some experiments, 1.5 g L− of Polyquaternium 7 were added to the solution. SEM and XRD were used to characterized coatings morphology and microstructure, whereas EDS was used to estimate SiO2 wt%. The results showed that the effect of ultrasound on the codeposition process depends on current density and particle surface chemistry. All the trends observed in this study could be explained taking into account ζ-potential values recorded and previously reported theories. Adjusting the experimental conditions, it was possible to obtain deposits with SiO2 contents of ≈5 wt%. Finally, it was found that both ultrasonic irradiation and Polyquaternium 7 affect the morphology and crystal orientation of the deposits.Fil: Bengoa, Leandro Nicolás. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: Ispas, Adriana. Technische Universität Ilmenau; AlemaniaFil: Bengoa, Jose Fernando. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; ArgentinaFil: Bund, A.. Technische Universität Ilmenau; AlemaniaFil: Egli, Walter Alfredo. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones en Tecnología de Pinturas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones en Tecnología de Pinturas; Argentin
Three-body Faddeev Calculation for 11Li with Separable Potentials
The halo nucleus Li is treated as a three-body system consisting of an
inert core of Li plus two valence neutrons. The Faddeev equations are
solved using separable potentials to describe the two-body interactions,
corresponding in the n-Li subsystem to a p resonance plus a
virtual s-wave state. The experimental Li energy is taken as input and
the Li transverse momentum distribution in Li is studied.Comment: 6 pages, RevTeX, 1 figur
Nanoparticle gas phase electrodeposition: fundamentals, fluid dynamics, and deposition kinetics
This communication uncovers missing fundamental elements and an expanded model of gas phase electrodeposition; a relatively new and in large parts unexplored process, which combines particle generation, transport zone and deposition zone in an interacting setup. The process enables selected area deposition of charged nanoparticles that are dispersed and transported by a carrier gas at atmospheric pressure conditions. Two key parameters have been identified: carrier gas flow rate and spark discharge power. Both parameters affect electrical current carried by charged species, nanoparticle mass, particle size and film morphology. In combination, these values enable to provide an estimate of the gas flow dependent Debye length. Together with Langmuir probe measurements of electric potential and field distribution, the transport can be described and understood. First, the transport of the charged species is dominated by the carrier gas flow. In close proximity, the transport is electric field driven. The transition region is not fixed and correlates with the electric potential profile, which is strongly dependent on the deposition rate. Considering the film morphology, the power of the discharge turns out to be the most relevant parameter. Low spark power combined with low gas flow leads to dendritic film growth. In contrast, higher spark power combined with higher gas flow produces compact layers
On the electrodeposition of titanium in ionic liquids
The ability to electrodeposit titanium at low temperatures would be an important breakthrough for making corrosion resistant layers on a variety of technically important materials. Ionic liquids have often been considered as suitable solvents for the electrodeposition of titanium. In the present paper we have extensively investigated whether titanium can be electrodeposited from its halides (TiCl4, TiF4, TiI4) in different ionic liquids, namely1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide ([EMIm]Tf2N), 1-butyl-1-methylpyrrolidinium bis(trifluoromethyl-sulfonyl)amide ([BMP]Tf2N), and trihexyltetradecyl-phosphonium bis(trifluoromethylsulfonyl)amide ([P14,6,6,6]Tf2N). Cyclic voltammetry and EQCM measurements show that, instead of elemental Ti, only non-stoichiometric halides are formed, for example with average stoichiometries of TiCl0.2, TiCl0.5 and TiCl1.1. In situ STM measurements show that—in the best case—an ultrathin layer of Ti or TiClx with thickness below 1 nm can be obtained. In addition, results from both electrochemical and chemical reduction experiments of TiCl4 in a number of these ionic liquids support the formation of insoluble titanium cation–chloride complex species often involving the solvent. Solubility studies suggest that TiCl3 and, particularly, TiCl2 have very limited solubility in these Tf2N based ionic liquids. Therefore it does not appear possible to reduce Ti4+ completely to the metal in the presence of chloride. Successful deposition processing for titanium in ionic liquids will require different maybe tailor-made titanium precursors that avoid these problems
Erratum Analysis of the physical and photoelectrochemical properties of c Si p a SiC H p photocathodes for solar water splitting
The photoelectrochemical (PEC) properties of sputtered aluminum doped hydrogenated amorphous silicon carbide thin films grown on p-type crystalline silicon substrates were investigated in 1 M H2SO4<i solution under chopped light illumination. Optical and structural properties of the top absorber layer were systematically assessed after post-deposition isochronical annealing treatments. Samples exhibited a noticeable improvement of the opto-electronic properties after thermal treatments. In addition, an abrupt enhancement of the photocurrent was observed reaching a saturation value of 17 mA cm(-2) at -1.75 V vs. Ag/AgCl (3.5 M KCl). In this research we propose that this enhancement effect is associated to a charge transfer kinetic mechanism influenced by surface states and the p-type substrate. The latter most likely due to the space charge region extending beyond the absorber layer reaching the substrate. Current density-potential and electrochemical impedance spectroscopy measurements in dark revealed a reduction of the SiO2 native layer at cathodic potentials higher than -1 V vs. Ag/AgCl (3.5 M KCl), which contributes to the high charge transfer kinetic of the system. We believe that these results will contribute to understand the substrate influence in the PEC performance of top absorber layers in multilayer structures for solar water splitting.This research was funded by FONDECYT (National Fund for Scientific, Technological Development and Technological Innovation) under the agreement 147-2017. The author M Mejia has been supported by the CONCYTEC Peru (National Council for Science, Technology and Technological Innovation) doctoral scholarship under the Contract Number 236-2015-FONDECYT as well as by the PUCP vicechancellorship for research (VRI, Project No. CAP-2019-3-0041/702). The authors would like to thank the Katholischer Akademischer Auslander-Dienst institution (KAAD) for the short-term grants given to conduct research internships in the Technische Universitat Ilmenau (TU Ilmenau). Finally, the authors would like to thank the German Research Foundation (DFG) (DFG-Gz: INST 273/56-1 FUGG) and the Materials Characterization Center (CAM) at PUCP, for the financial support to conduct the characterization experiments
A multi-scale hierarchical framework for developing understanding of river behaviour to support river management
The work leading to this paper was funded through the European Union’s FP7 programme under Grant Agreement No. 282656 (REFORM). The framework methodology was developed within the context of Deliverable D2.1 of the REFORM programme, and all partners who contributed to the development of the four parts of this deliverable are included in the author list of this paper. More details on the REFORM framework can be obtained from part 1 of Deliverable D2.1 (Gurnell et al. 2014), which is downloadable from http://www.reformrivers.eu/results/deliverables
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