The Development of a High Resolution ESI-QTOFMS Coupled with Three Sect Quadrupoles

报道了实验室研制的电喷雾离子源 ,具有射频四极杆接口的高分辨飞行时间质谱 (ESI- QQQ- TOFMS)仪器。该仪器具有以下特点 :在离子调制区使用三组四极杆 ,有效地减少离子束的空间分散和能量分散 ;采用正负双脉冲推斥和离子垂直引入方式 ;经过优化设计的二级有网反射器 ;新颖的 MCP安装方法。经初步调试 ,该仪器的分辨本领已优于 1 0 ,0 0 0 ,质量测定精度优于 1 0× 1 0 - 6 。该仪器于 2 0 0 2年 6月通过了国家教育部科技成果鉴定 [鉴字 [教 2 0 0 2 ]第 0 0 8号 ],其主要性能指标已经达到了国际先进水平An high resolution ESI QQQ TOFMS coupled with three sect quadrupoles is reported.The home made instrument in the laboratory has a number of features. It can be used as tandem MS (MS/MS) owing to three sect quadrupoles used in the ion modulation part; the TOFMS analyzer adopted positive negative double extrusion pulse and orthogonal injection way; two grade ion reflector with grids designed by computer simulation, and new micro channel plate (MCP) mounting method. This instrument has already been in working condition after preliminary adjustment, and the resolution over 10,000 was achieved.国家自然科学基金资助项目 (专项 H-2 992 70 0 2和重点 2 92 45 110 ) ;; 教育部现代分析科学重点实验室开放课

无色透明的聚酰亚胺树脂材料及其制备方法

本发明公开了无色透明的聚酰亚胺树脂材料，选用1，2，3，4-环己烷四酸二酐作为二酐单体或共聚单体，与二元伯胺缩聚反应得到。由于1，2，3，4-环己烷四酸二酐单体具有扭曲的分子结构，使聚合物分子链间具有较大的自由体积，抑制了电荷转移络合物(CTC)在聚酰亚胺分子内和分子间的形成；同时由于脂肪结构的引入，改变了聚酰亚胺分子链中电子受激的跃迁方式，显著减弱了芳香族聚酰亚胺在可见光区域的吸收，从而大大提高了聚合物的透明性。所得聚酰亚胺薄膜的紫外光透过截止波长为280nm～380nm，450nm处的光透过率为86％～94％，且玻璃化转变温度为250℃～400℃，在太阳能电池的柔性衬底材料、柔性透明导电膜衬底材料、液晶显示材料等领域有较好的应用前景

华北上新世-更新世过渡期植被、气候与大气CO_2研究进展

上新世-更新世过渡期是新生代全球气候变化的重要拐点之一,此期气候经历了由"暖室"向"冰室"的转变。研究该气候转型期的特征可为科学界和国家层面应对现在和未来的全球气候变暖提供理论基础和实践指导。通过深入研究中国华北山西榆社盆地张村组上新世-更新世过渡期地层中保存的植物大化石、孢粉以及硅藻组合,为重建该时段陆地生态系统中植被演替和气候变化提供坚实的生物学证据。在综合回顾张村组化石植物研究历史的基础上,侧重介绍最近5年在古植被、古气候、古环境以及古大气CO2浓度重建等方面的最新进展。这些新成果定性及定量地刻画了第三纪-第四纪之交中国北方黄土高原东南缘气候变干、变凉的转型过程及其陆地生态系统中大气CO2浓度先升后降的变化趋势

JUNO Sensitivity on Proton Decay p→νˉK+p\to \bar\nu K^+ Searches

The Jiangmen Underground Neutrino Observatory (JUNO) is a large liquid scintillator detector designed to explore many topics in fundamental physics. In this paper, the potential on searching for proton decay in $p\to \bar\nu K^+$ mode with JUNO is investigated.The kaon and its decay particles feature a clear three-fold coincidence signature that results in a high efficiency for identification. Moreover, the excellent energy resolution of JUNO permits to suppress the sizable background caused by other delayed signals. Based on these advantages, the detection efficiency for the proton decay via $p\to \bar\nu K^+$ is 36.9% with a background level of 0.2 events after 10 years of data taking. The estimated sensitivity based on 200 kton-years exposure is $9.6 \times 10^{33}$ years, competitive with the current best limits on the proton lifetime in this channel

JUNO sensitivity on proton decay p → ν K + searches*

The Jiangmen Underground Neutrino Observatory (JUNO) is a large liquid scintillator detector designed to explore many topics in fundamental physics. In this study, the potential of searching for proton decay in the $p\to \bar{\nu} K^+$ mode with JUNO is investigated. The kaon and its decay particles feature a clear three-fold coincidence signature that results in a high efficiency for identification. Moreover, the excellent energy resolution of JUNO permits suppression of the sizable background caused by other delayed signals. Based on these advantages, the detection efficiency for the proton decay via $p\to \bar{\nu} K^+$ is 36.9% ± 4.9% with a background level of $0.2\pm 0.05({\rm syst})\pm$$0.2({\rm stat})$ events after 10 years of data collection. The estimated sensitivity based on 200 kton-years of exposure is $9.6 \times 10^{33}$ years, which is competitive with the current best limits on the proton lifetime in this channel and complements the use of different detection technologies