695 research outputs found
Synthesis and characterisation of nanocrystalline ZrN PVD coatings on AISI 430 stainless steel
The nanocrystalline films of zirconium nitride have been synthesized using ion-plasma vacuum-arc deposition technique in combination with high-frequency discharge (RF) on AISI 430 stainless steel at 150oC. Structure examinations X-ray fluorescent analysis (XRF), X-ray diffraction analysis (XRD), scanning electron microscopy (SEM) with microanalysis (EDS), and transmission electron microscopy (TEM), nanoidentation method – were performed to study phase and chemical composition, surface morphology, microstructure and nanohardness of coatings. The developed technology provided low-temperature coatings synthesis, minimized discharge breakdown decreasing formation of macroparticles (MPs) and allowed to deposit ZrN coatings with hardness variation 26.6…31.5 GPa. It was revealed that ZrN single-phase coatings of cubic modification with finecrystalline grains of 20 nm in size were formed
Anti-corrosion ceramic coatings on the surface of Nd-Fe-B repelling magnets
The results of vacuum-arc deposition of thin ZrO₂coatings to protect the surface of Nd-Fe-B permanent magnets used as repelling devices in orthodontics are presented. The structure, phase composition and mechanical properties of zirconium dioxide films have been investigated by means of SEM, XRD, EDX, XRF and nanoindentation method. It was revealed the formation of polycrystalline ZrO₂ films of monoclinic modification with average grain size 25 nm. The influence of the ZrO₂ coating in terms of its barrier properties for corrosion in quasi-physiological 0.9 NaCl solution has been studied. Electrochemical measurements indicated good barrier properties of the coating on specimens in the physiological solution environment
On the dynamics of mortality and the ephemeral nature of mammalian megafauna
Energy flow through consumer-resource interactions is largely determined by
body size. Allometric relationships govern the dynamics of populations by
impacting rates of reproduction, as well as alternative sources of mortality,
which have differential impacts on smaller to larger organisms. Here we derive
and investigate the timescales associated with four alternative sources of
mortality for terrestrial mammals: mortality from starvation, mortality
associated with aging, mortality from consumption by predators, and mortality
introduced by anthropogenic subsidized harvest. The incorporation of these
allometric relationships into a minimal consumer-resource model illuminates
central constraints that may contribute to the structure of mammalian
communities. Our framework reveals that while starvation largely impacts
smaller-bodied species, the allometry of senescence is expected to be more
difficult to observe. In contrast, external predation and subsidized harvest
have greater impacts on the populations of larger-bodied species. Moreover, the
inclusion of predation mortality reveals mass thresholds for mammalian
herbivores, where dynamic instabilities may limit the feasibility of megafaunal
populations. We show how these thresholds vary with alternative predator-prey
mass relationships, which are not well understood within terrestrial systems.
Finally, we use our framework to predict the harvest pressure required to
induce mass-specific extinctions, which closely align with previous estimates
of anthropogenic megafaunal exploitation in both paleontological and historical
contexts. Together our results underscore the tenuous nature of megafaunal
populations, and how different sources of mortality may contribute to their
ephemeral nature over evolutionary time.Comment: 10 pages, 5 figures, 1 table, 4 appendices, 8 supplementary figure
Expermental research of the effects of benofilin on the functional renal function in the evalution of ethylene glycol toxic loss
Effect of benofilin – a new compound among a new derivative of theophylline and hofitol (70 mg/kg) on functional renal function was studied based on the rat experimental model of acute kidney damage by ethylene glycol. The toxic products of the metabolism of ethylene glycol cause renal tubular damage resulting in acute renal failure (ARF). As a result of the application of benofilin its ability is established to prevent the death of animals in the first day of the experiment. By the ability to prevent impaired kidney function in rats benofilin exceeds the effect of the hofitol
Anomalous pressure effect on the magnetic ordering in multiferroic BiMnO3
We report the magnetic field dependent dc magnetization and the
pressure-dependent (pmax ~ 16 kbar) ac susceptibilities Xp(T) on both powder
and bulk multiferroic BiMnO3 samples, synthesized in different batches under
high pressure. A clear ferromagnetic (FM) transition is observed at TC ~ 100 K,
and increases with magnetic field. The magnetic hysteresis behavior is similar
to that of a soft ferromagnet. Ac susceptibility data indicate that both the FM
peak and its temperature (TC) decrease simultaneously with increasing pressure.
Interestingly, above a certain pressure (9 ~ 11 kbar), another peak appears at
Tp ~ 93 K, which also decreases with increasing pressure, with both these peaks
persisting over some intermediate pressure range (9 ~ 13 kbar). The FM peak
disappears with further application of pressure; however, the second peak
survives until present pressure limit (pmax ~ 16 kbar). These features are
considered to originate from the complex interplay of the magnetic and orbital
structure of BiMnO3 being affected by pressure.Comment: 4 pages,4 figures, publised in Physical Review B 78, 092404/200
Reactor with Swirled Fluidized Bed Electrode for in Situ H2O2 Production and Utilization for Oxidative Treatment of Organic Pollutants
Несмотря на значительный прогресс в разработке каталитических систем окисления
органических соединений в мягких условиях, их практическое использование затрудняется
отсутствием дешёвых источников восстановленных форм кислорода, таких как H2O2, NaOCl
и т.д. Непосредственное получение таких соединений в химическом реакторе, например,
электрохимическим путём, представляется многообещающим подходом к решению этой
проблемы. В данной работе предложен новый реактор для проведения окислительной
обработки водных растворов, основанный на использовании закрученного псевдоожиженного
электрода для электрохимического восстановления кислорода воздуха и in situ получения
разбавленных растворов пероксида водорода. Реактор позволяет одновременно получать
активный окислитель и использовать его для проведения окислительных реакций сразу во
всём доступном реакционном объёме, что выгодно отличает его от электрохимических
реакторов с плоскими электродами. В реакторе данного типа возможно применение самых
разнообразных гомогенных и гетерогенных каталитических систем, использующих пероксид
водородаIn spite of remarkable progress in the development of catalytic systems for oxidation at mild conditions,
their application and further development are limited by the absence of cheap sources of reduced
oxygen forms (H2O2, NaOCl, etc). The in situ generation of hydrogen peroxide is very promising to
resolving this problem. It is suggested an approach based on in situ production of diluted hydrogen
peroxide solutions from air oxygen in a new type electrochemical reactor with a swirled fluidized bed
electrode for carrying out oxidative reactions with organic compounds. The reactor allows to process
simultaneously the oxidant production and the oxidative reactions and to utilize entire reaction volume
in contrast to electrochemical reactors with flat electrodes geometry. Reactor permits to use a variety
of homogeneous and heterogeneous catalytic systems which require hydrogen peroxid
Evaluation of the effect of plant growth retardants on vegetative growth, yield components, seed quality and crop maturity of kabuli chickpea
Non-Peer Reviewe
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