281 research outputs found

    MST15-EISCAT18-Program

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    15th MST Radar Workshop (May 27-30, 2017, NIPR)18th EISCAT symposium (May 26-31, 2017, NIPR

    Targeted optimization of chromatographic columns based on 3D analysis of packing microstructure

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    The preparation, structure, and performance of functional materials porous are strongly interrelated. Hence, a detailed analysis of the pore structure of a functional porous material in combination with a detailed characterisation of its performance can provide an understanding of the influence of individual parameters during preparation and thus identify structural limitations to an improved utilization. The obtained results can be used to tune the preparation towards a better pore structure suited for the targeted application. This work focuses on packings of silica-based particles for highly efficient chromatographic separations. The prepared packings combine an interparticle macropore space for fast flow-based transport with an intraparticle mesopore space providing high surface areas for molecule-surface interactions. Such packed columns have a wide field of application, not only in highly efficient separations, but also for catalysis, and (energy) storage However, the focus here is on separations in liquid chromatography. In Chapter 1, the influence of the slurry concentration on separation efficiency and bed structure was investigated for capillary columns (75 ”m inner diameter, 30 cm length) packed with 1.3 ”m bridged-ethyl hybrid (BEH) fully porous silica particles. The slurry concentration was varied from 5 to 50 mg/mL while every other packing parameter was kept constant. Chromatographic characterisation with hydroquinone as weakly retained analyte revealed highly efficient separations (reduced plate heights as low as 1.5) at an optimal intermediate slurry concentration of 20 mg/mL for this specific set of packing parameters. Confocal laser scanning microscopy (CLSM) was utilized to conduct a three-dimensional reconstruction and to carry out a detailed morphological analysis of the column with the best performance, a column packed with a slurry concentration below the optimum, and one packed above the optimum. Two counteracting effects were revealed: Radial heterogeneities limit the separation efficiency for columns packed at low slurry concentrations. With an increase in slurry concentration, these radial effects get supressed but the number and size of large voids with a diameter similar to the mean particle diameter increase significantly. Interestingly, the reconstructions also revealed high external bed porosities between 0.47 and 0.50 which are higher than expected with respect to the random loose packing limit reported for frictional, cohesionless particles. However, no signs of bed instability could be observed demonstrating the significant impact of interparticle forces for particles as small as 1.3 ”m. In Chapter 2, the investigation of the optimal slurry concentration was expanded by analysing the effects for a different particle size to obtain a more general picture. A similar set of capillary columns (75 ”m inner diameter, 45 cm length) was packed with 1.9 ”m BEH particles at eleven different slurry concentrations between 5 and 200 mg/mL including additional tests for reproducibility at selected concentrations and the observation of bed formation using optical microscopy. While comparable reduced plate heights were achieved, the observed optimum of 140-160 mg/mL to pack highly efficient columns reproducibly differed significantly from the 20 mg/mL for the 1.3 ”m particles identified in Chapter 1. This can be explained by the difference in the particle diameter as interparticle forces and particle aggregation become more dominant at still smaller diameters. CLSM-based reconstructions revealed similar trends in the bed structures as seen in Chapter 1. At low concentrations, pronounced ordered particle layers in the direct vicinity of the column wall, local bed densification near the column wall, and particle size-segregation limit the achieved separation efficiency. The peculiarity of the first effect is continuously decreasing with an increase in the slurry concentration even beyond the optimum while the latter two effects are already supressed at the optimal slurry concentration. On the other hand, the number and size of large voids increase with an increase in the utilized slurry concentration as already seen in Chapter 1. The videos acquired during column packing provided very helpful insights into bed formation mechanisms and thus delivered possible explanations for these structural features. At 10 mg/mL, particles arrive individually at the bed front allowing individual settlement and rearrangement on the arrival of following particles what allows a discrimination of particles according to their individual properties. The picture looks completely different for 100 mg/mL as example for higher concentrated slurries. Here, particles tend to aggregate during packing and arrive in large batches. This prevents discrimination of individual particles but significantly reduces the chances for rearrangement and is thus prone to the conservation of defects formed between the border of the arriving batches of particles and the front of the bed. Chapter 3 is based on the results obtained during the work presented in Chapters 1 and 2. The combination of high slurry concentration and ultrasound was already proposed there as chance to keep transcolumn heterogeneities as low as possible while preventing the formation of large voids. To test this hypothesis, two sets, each consisting of three capillary columns (75 ”m inner diameter, 100 cm length) were packed with 1.9 ”m BEH particles at a slurry concentration of 200 mg/mL; one set under application of ultrasound during packing, the other one without. All three columns, which underwent sonication, showed significantly better performance than each of the other columns. The obtained reduced minimum plate height for a weakly retained analyte was even lower than the already impressive value of 1.5 for columns packed at a slurry concentration optimal for packing without sonication and reached values close to unity over a length of 1 m for the best-performing column. The achieved theoretical plate counts of ~500,000 demonstrate a unique potential for highly efficient separations of extremely complex samples. In Chapter 4, the focus is shifted from capillary columns to the more common analytical format. CLSM could not be applied here as the steel columns are not transparent and extrusion of the bed is not possible without losing either stability or optical transparency. Thus, an imaging and reconstruction procedure based on focused ion beam scanning electron microscopy was developed using a commercial narrow-bore analytical column (2.1 mm inner diameter, 50 mm length) packed with 1.7 ”m BEH particles. The packing was embedded with poly(divinylbenzene) prior to extrusion from the steel column in order to conserve the bed structure. Two image stacks were acquired and reconstructed at characteristic positions within the bed: one in the central section of the column along the flow direction to obtain the bulk properties of the bed and one from the column wall towards the column centre to investigate and quantify the influence of the geometrical wall effect and the second wall effect. To investigate the effect of the microstructure in the wall region on local flow through the bed, a radially resolved flow profile was obtained by lattice-Boltzmann simulations. For this column, the region affected by wall effects spanned over approximately 62 particle diameters showing a decrease in the local mean porosity by up to 10% and an increase in the local mean particle diameter by up to 3% with respect to the bulk region inducing a decrease of the local flow velocity by up to 23%. Furthermore, four more ordered layers of particles were formed directly at the hard column wall due to the geometrical wall effect leading to local velocity fluctuations by up to a factor of three. These quantified structural features are in excellent agreement with previous reports about macroscopic characterisations of the wall effects by optical or chromatographic measurements

    Innovative Strategies for Observations in the Arctic Atmospheric Boundary Layer

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    In this thesis, consisting of five scientific papers, I investigate the potential of unmanned aircraft systems (UAS) in stable boundary layer (SBL) research, by developing and applying a new innovative observation strategy. In this strategy we supplement ground-based micrometeorological observations from masts and remote-sensing systems with a number of different UAS. To achieve good agreement between the different systems employed in this approach, I further investigate the quality and intercomparability of UAS-based observations of atmospheric temperature, humidity, pressure and wind, and develop and apply common, best-practice data processing methods. In Paper I we give a brief introduction to the ISOBAR project and provide an overview over the first SBL campaign at Hailuoto and the prevailing synoptic, sea-ice and micrometeorological conditions. We demonstrate the quality of our measurement approach by combining UAS profile data with observations from the wind and temperature sensing systems. Repeated UAS temperature profiles give detailed insight into the temporal evolution of the SBL, which we find was often subject to rapid temperature changes affecting the entire depth of the SBL. We further highlight the potential of the sampled data by detailed investigations of a case study, featuring rapid shifts in turbulent regimes and strong elevated thermal instabilities, which were likely to result from the instability of an elevated internal gravity wave. In Paper II we assess the quality and intercomparability of UAS-based atmospheric observations from the most extensive intercomparison experiment to date. We evaluate the precision and bias of temperature, humidity, pressure, wind speed and direction observations from 38 individual UAS with 23 unique sensor configurations based on observations next to a 18-m mast equipped with reference instruments. In addition, we investigate the influence of sensor response on the quality of temperature and humidity profiles. By grouping the different sensor–platform combinations with respect to the type of aircraft, sensor type and sensor integration (i.e., measures for aspiration and radiation shielding), we attempt to draw general conclusions from the intercomparison results. Overall, we find most observation systems in good agreement with the reference observations, however, some systems showed fairly large biases. In general, hovering multicopters showed less variability than fixed-wing systems and we attribute this finding to the difference in sampling strategies. The most consistent observations of the mean wind were achieved by multicopter-mounted sonic anemometers. Sensor response errors were smaller for fine-bed thermistors compared to temperature sensors of integrated-circuit type, and sensor aspiration proofed to be substantially relevant. We conclude, that sensor integration considerations, like radiation shielding and aspiration, are likely to be as important as the choice of the sensor type, and give a couple of recommendations for future perspectives on UAS-based atmospheric measurements. Paper III presents the ISOBAR project to a broader scientific audience, including a description of the two measurement campaigns, ISOBAR17 and ISOBAR18 and the contrasting meteorological and sea ice conditions. We further provide an overview on the micrometeorological conditions during the 13 intensive observational periods (IOPs), which resulted in detailed data sets on the SBL in unprecedented spatiotemporal resolution. Numerous cases with very-stable stratification under clear-sky and weak-wind conditions were observed, featuring a variety of different SBL processes. These processes resulted in rapid changes in the SBL’s vertical structure. Based on selected in-depth case studies, we investigate the interactions of turbulence in the very stable boundary layer (VSBL) with different processes, i.e., a shear instability, associated with a low-level jet; a rapid and strong cooling event, observed a couple of meters above the ground; and a wave-breaking event, caused by the enhancement of wind shear. In a first qualitative model validation experiment we use data from one IOP to assess the performance of three different types of numerical models. Only the turbulence resolving large-eddy simulation model is found capable of reproducing a VSBL structure similar to the one observed during the IOP. The other models, i.e., an operational weather prediction and a single-column model, substantially overestimated the depth of the SBL. Paper IV introduces a new fixed-wing UAS for turbulence observations and first results from validation experiments carried out during ISOBAR18. Airborne observations of mechanical turbulence from straight horizontal flight paths are compared to corresponding eddy-covariance measurements mounted on a 10-m mast during weakly stable conditions with moderate wind speeds. Different average and spectral turbulence quantities, as well as mean wind speed and direction were computed for both systems and compared to each other. The UAS observations of mean wind and turbulence are in good agreement with the reference observations and the turbulence spectra agree qualitatively in the onset of the inertial subrange and the turbulence production range. Minor differences are likely to be caused by a slightly elevated UAS flight level and additional small altitude variations in the presence of relatively strong vertical gradients. In a second comparison, vertical profiles of mean wind and turbulence variables, determined from straight horizontal UAS flights at several different levels are compared qualitatively to profile observations from the 10-m mast and a phased-array sodar system providing 10-min averaged wind and vertical velocity variance profiles above 35 m. Qualitatively, the results agree well for the first two out of three profiles. During the third profile, the UAS data indicate the existence of a low-level jet but not an upside-down boundary layer structure, which would be expected due to the elevated source of turbulence. This observation is, however, not supported by the other measurement systems. Instead, the sodar data indicate a strong decrease in wind speed during the time of this profile. The fact that the lower part of the UAS profile was sampled before the start of the strongest transition, resulted in a seemingly wrong shape of the vertical profiles. This finding highlights the relevance of non-stationarity and the importance of additional reference systems for the correct interpretation of UAS sampled turbulence profiles. Paper V explores the potential of a new method to estimate profiles of turbulence variables in the SBL. In this method we apply a gradient-based scaling scheme for SBL turbulence to multicopter profiles of temperature and wind, sampled during ISOBAR18. We first validate this method by scaling turbulence observations from three levels on a 10-m mast with the corresponding scaling parameters, and comparing the resulting non- dimensional parameters to the semi-empirical stability functions proposed for this scheme. The scaled data from the three levels largely collapse to the predicted curves, however, minor differences between the three levels are evident. We attribute this discrepancy to the non-ideal observation heights for the determination of vertical gradients at the upper turbulence observation level. After the successful validation we apply this method to UAS profiles, by computing profiles of the gradient Richardson number to which we then apply the stability functions to derive turbulence variables. We demonstrate this approach based on three case studies covering a broad range of SBL conditions and boundary layer heights. Since the application of this scaling scheme is only valid within the SBL, we estimate the boundary layer height from the sodar and two different methods based on UAS data. Comparisons at the lowest levels against turbulence variables from the 10-m mast and at higher levels against a Doppler wind lidar, which also provides estimates of some turbulence variables, indicate broad agreement and physical meaningful results of this method. Supplementing the findings from the five scientific papers, this thesis also provides the detailed description on the methodology and data processing procedures, I applied for the synthesis of observations from UAS, micrometeorological masts and boundary layer remote-sensing systems. Furthermore, I present results on the validation of the different wind observation methods, using lidar wind observations as the common reference. Finally, I provide an outlook on future perspectives of SBL and UAS-based boundary-layer research, and how further developments in SBL observation strategies may benefit from recent and future developments.Doktorgradsavhandlin

    Non-Destructive Techniques for the Condition and Structural Health Monitoring of Wind Turbines: A Literature Review of the Last 20 Years

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    A complete surveillance strategy for wind turbines requires both the condition monitoring (CM) of their mechanical components and the structural health monitoring (SHM) of their load-bearing structural elements (foundations, tower, and blades). Therefore, it spans both the civil and mechanical engineering fields. Several traditional and advanced non-destructive techniques (NDTs) have been proposed for both areas of application throughout the last years. These include visual inspection (VI), acoustic emissions (AEs), ultrasonic testing (UT), infrared thermography (IRT), radiographic testing (RT), electromagnetic testing (ET), oil monitoring, and many other methods. These NDTs can be performed by human personnel, robots, or unmanned aerial vehicles (UAVs); they can also be applied both for isolated wind turbines or systematically for whole onshore or offshore wind farms. These non-destructive approaches have been extensively reviewed here; more than 300 scientific articles, technical reports, and other documents are included in this review, encompassing all the main aspects of these survey strategies. Particular attention was dedicated to the latest developments in the last two decades (2000–2021). Highly influential research works, which received major attention from the scientific community, are highlighted and commented upon. Furthermore, for each strategy, a selection of relevant applications is reported by way of example, including newer and less developed strategies as well

    Understanding and Predicting Vadose Zone Processes

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    Vadose zone hydrologic and biogeochemical processes play a significant role in the capture, storage and distribution of contaminants between the land surface and groundwater. One major issue facing geoscientists in dealing with investigations of the unsaturated zone flow and transport processes is the evaluation of heterogeneity of subsurface media. This chapter presents a summary of approaches for monitoring and modeling of vadose zone dynamics in the presence of heterogeneities and complex features, as well as incorporating transient conditions. Modeling results can then be used to provide early warning of soil and groundwater contamination before problems arise, provide scientific and regulatory credibility to environmental management decision-making process to enhance protection of human health and the environment. We recommend that future studies target the use of RTMs to identify and quantify critical interfaces that control large-scale biogeochemical reaction rates and ecosystem functioning. Improvements also need to be made in devising scaling approaches to reduce the disconnect between measured data and the scale at which processes occur

    Atmospheric Instrument Systems and Technology in the Goddard Earth Sciences Division

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    Studies of the Earths atmosphere require a comprehensive set of observations that rely on instruments flown on spacecraft, aircraft, and balloons as well as those deployed on the surface. Within NASAs Goddard Space Flight Center (GSFC) Earth Sciences Division-Atmospheres, laboratories and offices maintain an active program of instrument system development and observational studies that provide: 1) information leading to a basic understanding of atmospheric processes and their relationships with the Earths climate system, 2) prototypes for future flight instruments, 3) instruments to serve as calibration references for satellite missions, and 4) instruments for future field validation campaigns that support ongoing space missions. Our scientists participate in all aspects of instrument activity, including component and system design, calibration techniques, retrieval algorithm development, and data processing systems. The Atmospheres Program has well-equipped labs and test equipment to support the development and testing of instrument systems, such as a radiometric calibration and development facility to support the calibration of ultraviolet and visible (UV/VIS), space-borne solar backscatter instruments. This document summarizes the features and characteristics of 46 instrument systems that currently exist or are under development. The report is organized according to active, passive, or in situ remote sensing across the electromagnetic spectrum. Most of the systems are considered operational in that they have demonstrated performance in the field and are capable of being deployed on relatively short notice. Other systems are under study or of low technical readiness level (TRL). The systems described herein are designed mainly for surface or airborne platforms. However, two Cubesat systems also have been developed through collaborative efforts. The Solar Disk Sextant (SDS) is the single balloon-borne instrument. The lidar systems described herein are designed to retrieve clouds, aerosols, methane, water vapor pressure, temperature, and winds. Most of the lasers operate at some wavelength combination of 355, 532, and 1064 nm. The various systems provide high sensitivity measurements based on returns from backscatter or Raman scattering including intensity and polarization. Measurements of the frequency (Doppler) shift of light scattered from various atmospheric constitutes can also be made. Microwave sensors consist of both active (radar) and passive (radiometer) systems. These systems are important for studying processes involving water in various forms. The dielectric properties of water affect microwave brightness temperatures, which are used to retrieve atmospheric parameters such as rainfall rate and other key elements of the hydrological cycle. Atmosphere radar systems operate in the range from 9.6 GHz to 94 GHz and have measurement accuracies from -5 to 1 dBZ; radiometers operate in the 50 GHz to 874 GHz range with accuracies from 0.5 to 1 degree K; conical and cross-track scan modes are used. Our passive optical sensors, consisting of radiometers and spectrometers, collectively operate from the UV into the infrared. These systems measure energy fluxes and atmospheric parameters such as trace gases, aerosols, cloud properties, or altitude profiles of various species. Imager spatial resolution varies from 37 m to 400 m depending on altitude; spectral resolution is as small as 0.5 nm. Many of the airborne systems have been developed to fly on multiple aircraft

    MOSAiC Implementation Plan

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    This document is the second version of the Implementation Plan for the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) initiative and lays out a vision of how associated observational, modeling, synthesis, and programmatic objectives can be manifested. The document was drafted during an international workshop in Potsdam in July 2015, and further developed during two additional workshops at AWI Potsdam in December 2015 and February 2016. Support for this planning activity has been provided by the IASC-ICARPIII process, the Alfred Wegener Institute Helmholtz Centre for Polar- and Marine Research, and the University of Colorado/ NOAA-ESRL-PSD. This document provides a framework for planning the logistics of the project, developing scientific observing teams, organizing scientific contributions, coordinating the use of resources, and ensuring MOSAiC’s legacy of data and products. A brief overview and summaries of key science questions are provided in Section 1. Section 2 includes an overview of specific observational requirements, while Section 3 describes the coordination and design of specific field assets. Practical logistics plans are outlined in Section 4. Links with current and future satellite programs and model activities are given in Sections 5 and 6. The MOSAiC data management strategy is given in Section 7. Links to other programs are outlined in Section 8. The appendix (Section 9) lists the parameters to be measured and the participating groups
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