30,345 research outputs found
Mechanically fractionated flour isolated from green plantains (M. cavendishii var. nanica) as a tool to increase the dietary fiber and phytochemical bioactivity of layer and sponge cakes
This article describes the effect of mechanically fractionated flours from green bananas on the
nutritional, physical and sensory attributes of two types of cakes (sponge and layer). A plausible
30% replacement of banana flour in the formulation of layer cakes is demonstrated, finding only
a small decline in the sensory perception. On the contrary, sponge cakes were noticeable
worsened with the use of banana flours (lower specific volume, worse sensory attributes and
higher hardness), which was minimized when using fine flour. Both layer and sponge cakes
exhibited an enhancement of the resistant starch and dietary fiber content with the replacement
of green banana flour (up to a five-fold improvement in RS performance). Moreover, sponge
cakes yielded more polyphenols and antioxidant capacity with banana flours, especially with the
coarse fraction. Therefore, results showed that a mechanical fractionation allowed a feasible
nutritional enhancement of cakes with the use of banana flours
Spiral Growth and Step Edge Barriers
The growth of spiral mounds containing a screw dislocation is compared to the
growth of wedding cakes by two-dimensional nucleation. Using phase field
simulations and homoepitaxial growth experiments on the Pt(111) surface we show
that both structures attain the same characteristic large scale shape when a
significant step edge barrier suppresses interlayer transport. The higher
vertical growth rate observed for the spiral mounds on Pt(111) reflects the
different incorporation mechanisms for atoms in the top region and can be
formally represented by an enhanced apparent step edge barrier.Comment: 11 pages, 4 figures, partly in colo
Spiral Growth and Step Edge Barriers
The growth of spiral mounds containing a screw dislocation is compared to the
growth of wedding cakes by two-dimensional nucleation. Using phase field
simulations and homoepitaxial growth experiments on the Pt(111) surface we show
that both structures attain the same characteristic large scale shape when a
significant step edge barrier suppresses interlayer transport. The higher
vertical growth rate observed for the spiral mounds on Pt(111) reflects the
different incorporation mechanisms for atoms in the top region and can be
formally represented by an enhanced apparent step edge barrier.Comment: 11 pages, 4 figures, partly in colo
From colloidal dispersions to colloidal pastesthrough solid–liquid separation processes
Solid–liquid separation is an operation that starts with a dispersion of solid particles in a liquid and removes some of the liquid from the particles, producing a concentrated
solid paste and a clean liquid phase. It is similar to thermodynamic processes where pressure is applied to a system in order to reduce its volume. In dispersions, the resistance to this osmotic compression depends on interactions between the dispersed particles.
The first part of this work deals with dispersions of repelling particles, which are either silica nanoparticles or synthetic clay platelets, dispersed in aqueous solutions. In these conditions, each particle is surrounded by an ionic layer, which repels other ionic layers. This results in a structure with strong short-range order. At high particle volume fractions, the overlap
of ionic layers generates large osmotic pressures; these pressures may be calculated, through the cell model, as the cost of reducing the volume of each cell. The variation of osmotic pressure with volume fraction is the equation of state of the dispersion.
The second part of this work deals with dispersions of aggregated particles, which are silica nanoparticles, dispersed in water and flocculated by multivalent cations. This produces large bushy aggregates, with fractal structures that are maintained through interparticle surface– surface bonds. As the paste is submitted to osmotic pressures, small relative displacements
of the aggregated particles lead to structural collapse. The final structure is made of a dense skeleton immersed in a nearly homogeneous matrix of aggregated particles. The variation of osmotic resistance with volume fraction is the compression law of the paste; it may be calculated through a numerical model that takes into account the noncentral interparticle forces. According to this model, the response of aggregated pastes to applied stress may be
controlled through the manipulation of interparticle adhesion
The origin ofhigh hydraulic resistance for filter cakes ofdef ormable particles: cell-bed deformation or surface-layer effect?
This study reports a numerical approach for modeling the hydraulic resistance ofa filter cake ofdef ormable cells. First, a mechanical and osmotic model that describes the volume fraction ofsolids in a bed ofyeast cells as a function ofthe compressive pressure it experiences
is presented. The effects ofpressure on the compressibility ofyeast cells beds were further investigated both by filtration experiments and by centrifugal experiments based on the multiple speed equilibrium sediment height technique. When comparing the latter measurements
with compression model calculations, we observed that the method based on centrifugal experiments suffers from rapid relaxation of the compressed bed. Concerning the filtration experiments, specific resistance ofwell-defined bed ofcells were calculated by a combination of
the compression model with a formulation for hydraulic resistivity developed using the Lattice Boltzmann method. We further explain the experimental values observed for the hydraulic resistance ofcell beds, assuming that the first layer ofcells in contact with the membrane partially blocks the membrane area open to flow. In such a case, the blocked area seems to be a constant fraction of the normal cell–cell
contact area
Drying and cracking mechanisms in a starch slurry
Starch-water slurries are commonly used to study fracture dynamics. Drying
starch-cakes benefit from being simple, economical, and reproducible systems,
and have been used to model desiccation fracture in soils, thin film fracture
in paint, and columnar joints in lava. In this paper, the physical properties
of starch-water mixtures are studied, and used to interpret and develop a
multiphase transport model of drying. Starch-cakes are observed to have a
nonlinear elastic modulus, and a desiccation strain that is comparable to that
generated by their maximum achievable capillary pressure. It is shown that a
large material porosity is divided between pore spaces between starch grains,
and pores within starch grains. This division of pore space leads to two
distinct drying regimes, controlled by liquid and vapor transport of water,
respectively. The relatively unique ability for drying starch to generate
columnar fracture patterns is shown to be linked to the unusually strong
separation of these two transport mechanisms.Comment: 9 pages, 8 figures [revised in response to reviewer comments
Drying and cracking mechanisms in a starch slurry
Starch-water slurries are commonly used to study fracture dynamics. Drying
starch-cakes benefit from being simple, economical, and reproducible systems,
and have been used to model desiccation fracture in soils, thin film fracture
in paint, and columnar joints in lava. In this paper, the physical properties
of starch-water mixtures are studied, and used to interpret and develop a
multiphase transport model of drying. Starch-cakes are observed to have a
nonlinear elastic modulus, and a desiccation strain that is comparable to that
generated by their maximum achievable capillary pressure. It is shown that a
large material porosity is divided between pore spaces between starch grains,
and pores within starch grains. This division of pore space leads to two
distinct drying regimes, controlled by liquid and vapor transport of water,
respectively. The relatively unique ability for drying starch to generate
columnar fracture patterns is shown to be linked to the unusually strong
separation of these two transport mechanisms.Comment: 9 pages, 8 figures [revised in response to reviewer comments
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