Flexible and Low-cost Interface Circuit for Electrochemical and Resistive Gas Sensors

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Gas Sensors on Plastic Foil with Reduced Power Consumption for Wireless Applications

Recently, there is a growing interest in developing so-called "smart" RFID tags for logistic applications. These smart tags incorporate sensing devices to monitor environmental parameters such as humidity and temperature throughout the supply chain. To fulfill these requirements cost-effectively, RFID tags were produced on plastic foil through large scale manufacturing techniques. To benefit from sensing capabilities on these systems, the integration of gas sensors directly produced on plastic foil was explored. Their gas sensing performances were investigated when fabricated on same polymeric substrates than the labels. To be compatible with wireless applications, all sensors were designed to operate in the sub-milliwatt power range. The integration of three different transducers on plastic foil for the detection of different gaseous species was investigated. First, the direct use of the PET or PEN foil as an optical waveguide for the fabrication of a selective colorimetric ammonia gas sensor was carried out. It led to a simplified processing based on additive fabrication techniques compatible with large scale manufacturing. Second, the impact of miniaturization on drop-coated metal-oxide gas sensors when fabricated on polyimide foil on their sensing performances was investigated. They took advantage from the low thermal conductivity of the substrate to reduce the power consumption with a simplified processing. The detection of oxidizing and reducing gases was achieved at low power consumption when pulsing the sensors. Lastly, the benefits brought by the gas absorption in a polyimide foil were exploited with the design of a simple capacitive structure. By operating it in a differential mode with a second functionalized capacitor, the discrimination between low-concentrations of volatile organic compounds and humidity was achieved. The design and fabrication of these sensors were developed with a vision of their future production performed by large scale manufacturing techniques. The gas sensing performances of all three transducers were assessed and revealed sensitivities comparable to standard devices made on silicon. Each sensor was associated with low-power electronics targeting an integration on wireless systems. The concept of a smart gas sensing system was demonstrated with the interfacing of a capacitive humidity sensor on a passive RFID label

Overview of Gas Sensors Focusing on Chemoresistive Ones for Cancer Detection

The necessity of detecting and recognizing gases is crucial in many research and application fields, boosting, in the last years, their continuously evolving technology. The basic detection principle of gas sensors relies on the conversion of gas concentration changes into a readable signal that can be analyzed to calibrate sensors to detect specific gases or mixtures. The large variety of gas sensor types is here examined in detail, along with an accurate description of their fundamental characteristics and functioning principles, classified based on their working mechanisms (electrochemical, resonant, optical, chemoresistive, capacitive, and catalytic). This review is particularly focused on chemoresistive sensors, whose electrical resistance changes because of chemical reactions between the gas and the sensor surface, and, in particular, we focus on the ones developed by us and their applications in the medical field as an example of the technological transfer of this technology to medicine. Nowadays, chemoresistive sensors are, in fact, strong candidates for the implementation of devices for the screening and monitoring of tumors (the second worldwide cause of death, with ~9 million deaths) and other pathologies, with promising future perspectives that are briefly discussed as well

Artificial olfactory system for multi-component analysis of gas mixtures.

Gas analysis is an important part of our world and gas sensing technology is becoming more essential for various aspects of our life. A novel approach for gas mixture analysis by using portable gas chromatography in combination with an array of highly integrated and selective metal oxide (MOX) sensors has been studied. We developed a system with small size (7 x 13 x 16 inches), low power consumption (~10 W) and absence of special carrier gases designed for portable field analysis (assuming apriori calibration). Low ppb and even sub-ppb level of detection for some VOCs was achieved during the analysis of 50 ml of gas samples. A detailed description of our innovative design of multi-sensory platforms based on MOX sensors for multidimensional portable gas chromatography is provided in detail in this work. As a part of this effort, we successfully synthesized nanocomposite gas sensors based on SnO2 for selective detection of hydrogen sulfide, mercaptans, alcohols, ketones and heavy hydrocarbons. The morphology of the prepared sensors was closely studied by scanning electron microscopy (SEM), atomic force microscopy (AFM), transition electron microscopy (TEM) and X-Ray diffraction (XRD). Optical and electrical properties of polycrystalline SnO2 were investigated by using UV-Vis spectroscopy, transmission line measurement (TLM) and four probe resistance measurement techniques. Furthermore, more advanced gas sensing performance for detection of benzene, toluene, ethylbenzene, and O-xylene (BTEX) of polycrystalline SnO2 film (30 nm) coated with bimetal Au:Pd (9:1 molar ratio) nanoclusters was measured. Finally, besides the experimental result, the theoretical validation of the detector’s performance was provided based on high catalytic activity of nanocomposite materials and its superior electronic structure for gas detection compared to the polycrystalline SnO2. The theoretical background of gas chemisorption process at the surface of polycrystalline SnO2 was reviewed in this work. Furthermore, one dimensional Poisson equation relates surface energy states ( and ) and the bulk electronic structure ( and ) of polycrystalline SnO2. The main theory of electronic processes on the surface of semiconductors during the gas chemisorption was further applied in a case of nanocomposite materials

Photonic Technology for Precision Metrology

Photonics has had a decisive influence on recent scientific and technological achievements. It includes aspects of photon generation and photon–matter interaction. Although it finds many applications in the whole optical range of the wavelengths, most solutions operate in the visible and infrared range. Since the invention of the laser, a source of highly coherent optical radiation, optical measurements have become the perfect tool for highly precise and accurate measurements. Such measurements have the additional advantages of requiring no contact and a fast rate suitable for in-process metrology. However, their extreme precision is ultimately limited by, e.g., the noise of both lasers and photodetectors. The Special Issue of the Applied Science is devoted to the cutting-edge uses of optical sources, detectors, and optoelectronics systems in numerous fields of science and technology (e.g., industry, environment, healthcare, telecommunication, security, and space). The aim is to provide detail on state-of-the-art photonic technology for precision metrology and identify future developmental directions. This issue focuses on metrology principles and measurement instrumentation in optical technology to solve challenging engineering problems

A Flexible, Highly Integrated, Low Power pH Readout

Medical devices are widely employed in everyday life as wearable and implantable technologies make more and more technological breakthroughs. Implantable biosensors can be implanted into the human body for monitoring of relevant physiological parameters, such as pH value, glucose, lactate, CO2 [carbon dioxide], etc. For these applications the implantable unit needs a whole functional set of blocks such as micro- or nano-sensors, sensor signal processing and data generation units, wireless data transmitters etc., which require a well-designed implantable unit.Microelectronics technology with biosensors has caused more and more interest from both academic and industrial areas. With the advancement of microelectronics and microfabrication, it makes possible to fabricate a complete solution on an integrated chip with miniaturized size and low power consumption.This work presents a monolithic pH measurement system with power conditioning system for supply power derived from harvested energy. The proposed system includes a low-power, high linearity pH readout circuits with wide pH values (0-14) and a power conditioning unit based on low drop-out (LDO) voltage regulator. The readout circuit provides square-wave output with frequency being highly linear corresponding to the input pH values. To overcome the process variations, a simple calibration method is employed in the design which makes the output frequency stay constant over process, supply voltage and temperature variations. The prototype circuit is designed and fabricated in a standard 0.13-μm [micro-meter] CMOS process and shows good linearity to cover the entire pH value range from 0-14 while the voltage regulator provides a stable supply voltage for the system

A Review Of Implementing Adc In Rfid Sensor

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)The general considerations to design a sensor interface for passive RFID tags are discussed. This way, power and timing constraints imposed by ISO/IEC 15693 and ISO/IEC 14443 standards to HF RFID tags are explored. A generic multisensor interface is proposed and a survey analysis on the most suitable analog-to-digital converters for passive RFID sensing applications is reported. The most appropriate converter type and architecture are suggested. At the end, a specific sensor interface for carbon nanotube gas sensors is proposed and a brief discussion about its implemented circuits and preliminary results is made.Region Rhone-Alpes (France)CNPq (Brazil)INCT/NAMITEC (Brazil)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq

A Review Of Implementing Adc In Rfid Sensor

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)The general considerations to design a sensor interface for passive RFID tags are discussed. This way, power and timing constraints imposed by ISO/IEC 15693 and ISO/IEC 14443 standards to HF RFID tags are explored. A generic multisensor interface is proposed and a survey analysis on the most suitable analog-to-digital converters for passive RFID sensing applications is reported. The most appropriate converter type and architecture are suggested. At the end, a specific sensor interface for carbon nanotube gas sensors is proposed and a brief discussion about its implemented circuits and preliminary results is made.Region Rhone-Alpes (France)CNPq (Brazil)INCT/NAMITEC (Brazil)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq

A Review of Implementing ADC in RFID Sensor

The general considerations to design a sensor interface for passive RFID tags are discussed. This way, power and timing constraints imposed by ISO/IEC 15693 and ISO/IEC 14443 standards to HF RFID tags are explored. A generic multisensor interface is proposed and a survey analysis on the most suitable analog-to-digital converters for passive RFID sensing applications is reported. The most appropriate converter type and architecture are suggested. At the end, a specific sensor interface for carbon nanotube gas sensors is proposed and a brief discussion about its implemented circuits and preliminary results is made

Low-cost, multimodal environmental monitoring based on the Internet of Things

Monitoring Indoor Environmental Quality (IEQ) is of growing interest for health and wellbeing. New building standards, climate targets and adoption of homeworking strategies are creating needs for scalable, monitoring solutions with onward Cloud connectivity. Low-cost Micro-Electromechanical Systems (MEMS) sensors have potential to address these needs, enabling development of bespoke multimodal devices. Here, we present insights into the development of a MEMS-based Internet of things (IoT) enabled multimodal device for IEQ monitoring. A study was conducted to establish the inter-device variability and validity to reference standard sensors/devices. For the multimodal, IEQ monitor, intraclass correlations and Bland-Altman analyses indicated good inter-sensor reliability and good-to-excellent agreement for most sensors. All low-cost sensors were found to respond to environmental changes. Many sensors reported low accuracy but high precision meaning they could be calibrated against reference sensors to increase accuracy. The multimodal device developed here was identified as being fit-for-purpose, providing general indicators of environmental changes for continuous IEQ monitoring