66,318 research outputs found

    Predicting participation in group parenting education in an Australian sample: The role of attitudes, norms, and control factors

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    We examined the theory of planned behavior (TPB) in predicting intentions to participate in group parenting education. One hundred and seventy-six parents (138 mothers and 38 fathers) with a child under 12 years completed TPB items assessing attitude, subjective norms, perceived behavioral control (PBC), and two additional social influence variables (self-identity and group norm). Regression analyses supported the TPB predictors of participation intentions with self-identity and group norm also significantly predicting intentions. These findings offer preliminary support for the TPB, along with additional sources of social influence, as a useful predictive model of participation in parenting education

    VUV-Vis optical characterization of Tetraphenyl-butadiene films on glass and specular reflector substrates from room to liquid Argon temperature

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    The use of efficient wavelength-shifters from the vacuum-ultraviolet to the photosensor's range of sensitivity is a key feature in detectors for Dark Matter search and neutrino physics based on liquid argon scintillation detection. Thin film of Tetraphenyl-butadiene (TPB) deposited onto the surface delimiting the active volume of the detector and/or onto the photosensor optical window is the most common solution in current and planned experiments. Detector design and response can be evaluated and correctly simulated only when the properties of the optical system in use (TPB film + substrate) are fully understood. Characterization of the optical system requires specific, sometimes sophisticated optical methodologies. In this paper the main features of TPB coatings on different, commonly used substrates is reported, as a result of two independent campaigns of measurements at the specialized optical metrology labs of ENEA and University of Tor Vergata. Measured features include TPB emission spectra with lineshape and relative intensity variation recorded as a function of the film thickness and for the first time down to LAr temperature, as well as optical reflectance and transmittance spectra of the TPB coated substrates in the wavelength range of the TPB emission

    N_2 Functionalization at Iron Metallaboratranes

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    The reactivity of the anionic dinitrogen complex [(TPB)Fe(N_2)]^− (TPB = tris[2-(diisopropylphosphino)phenyl]borane) toward silicon electrophiles has been examined. [(TPB)Fe(N_2)]^− reacts with trimethylsilyl chloride to yield the silyldiazenido complex (TPB)Fe(NNSiMe_3), which is reduced by Na/Hg in THF to yield the corresponding sodium-bound anion [(TPB)Fe(NNSiMe_3)]Na(THF). The use of 1,2-bis(chlorodimethylsilyl)ethane in the presence of excess Na/Hg results in the disilylation of the bound N_2 molecule to yield the disilylhydrazido(2−) complex (TPB)Fe≡NR (R = 2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopentyl). One of the phosphine arms of TPB in (TPB)Fe≡NR can be substituted by CO or ^tBuNC to yield crystalline adducts (TPB)(L)Fe≡NR (L = CO, ^tBuNC). The N–N bond in (TPB)(^tBuNC)Fe≡NR is cleaved upon standing at room temperature to yield a phosphoraniminato/disilylamido iron(II) complex. The flexibility of the Fe–B linkage is thought to play a key role in these transformations of Fe-bound dinitrogen

    Scintillation of thin tetraphenyl butadiene films under alpha particle excitation

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    The alpha induced scintillation of the wavelength shifter 1,1,4,4-tetraphenyl-1,3-butadiene (TPB) was studied to improve the understanding of possible surface alpha backgrounds in the DEAP dark matter search experiment. We found that vacuum deposited thin TPB films emit 882 +/-210 photons per MeV under alpha particle excitation. The scintillation pulse shape consists of a double exponential decay with lifetimes of 11 +/-5 ns and 275 +/-10ns.Comment: paper submitted to Nuclear Physics

    Unethical consumers: Deshopping behaviour using the qualitative analysis of theory of planned behaviour and accompanied (de)shopping

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    Purpose Previous research indicates that deshopping is a prevalent and growing consumer behaviour. This paper examines deshopping from a consumer perspective, and applies the Theory of Planned Behaviour (TPB) to demonstrate how this behaviour can be managed and prevented. An accompanied (de)shop is also conducted. This paper also places deshopping within a legal and ethical context, in relation to the established literature in this field. Methodology approach This paper tests the TPB variables in a qualitative way by conducting in-depth interviews with deshoppers, who had completed a quantitative questionnaire. The results further support and enhance the quantitative TPB results collected previously with 535 consumers. An accompanied (de)shop is also reviewed, as this qualitative research technique, enables an enhanced understanding and evidence of the deshopping process, which has not been demonstrated previously. The findings demonstrate support for these qualitative research tool, which enable a deeper understanding of the deshopping process and its management. Findings The findings demonstrate important use of the TPB as a qualitative research technique. The model is also expanded and redesigned by adding additional variables as a result of this research. The accompanied (de)shop findings demonstrate support for this qualitative research tool, which also enables a deeper understanding of the deshopping process and its management. Practical implications The research concludes with the implications of deshopping for the industry and makes recommendations as how to reduce deshopping, as well as recommending the qualitative research techniques utilised to future researchers. Originality This paper has identified the key variables that influence deshopping, and demonstrates that procedures can be designed to reduce this behaviour by manipulating the TPB variables. This paper has also added additional variables to the TPB model, which have proved to be influential in deshopping behaviour, thereby developing theoretical knowledge of TPB. The use of the TPB has also provided a theoretical underpinning to utilising a consumer education program to prevent problem behaviours. This research demonstrates that this could alter deshoppers’ attitudes and subjective norms. This is also the first paper to place deshopping in a legal framework which highlights the legal loopholes in a retailer’s returns policy and the implications of new directives which will influence retailer’s abilities to refuse a return. This paper is also the first to explore deshopping within an ethical framework that has created new knowledge on the unethical consumer in relation to deshopping behaviour. This study also incorporates an accompanied (de)shop methodology; this form of research has never been undertaken in relation to deshopping activity and has generated completely new knowledge of what is happening when the actual behaviour is taking place

    The attitudes and behaviour of adolescent road users : an application of the theory of planned behaviour

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    The Theory of Planned Behaviour (TPB) was used as a framework to study the attitudes of adolescent road users towards four target behaviours: (1) cycle helmet use, (2) using nearby crossings, (3) crossing from between parked cars, and (4) challenging traffic. Four questionnaires, one for each of the behaviours, were designed based on pilot work. Each questionnaire contained items to measure the TPB variables, self-reported behaviour, and general exposure and demographic characteristics (e.g. age and gender). A total of 2,457 children aged 11-16 completed the questionnaires; 564 respondents completed the 'cycle helmet use' questionnaire; 657 respondents completed the 'using nearby crossings' questionnaire; 619 respondents completed the 'crossing from between parked cars' questionnaire; and 617 completed the 'challenging traffic' questionnaire. Multivariate analyses were conducted for each of the behaviours to explore how adolescents' attitudes, subjective norms, perceived control, behavioural intentions and self-reported behaviour differed as a function of demographic variables. Correlation and multiple regression analyses were then conducted to test the relationships in the TPB and to identify beliefs underpinning adolescents' attitudes that could be targeted in road safety interventions. This report describes all aspects of the study and discusses the theoretical and practical implications

    A Split-Stem Lesion on Young Hybrid \u3ci\u3ePopulus\u3c/i\u3e Trees Caused by the Tarnished Plant Bug, \u3ci\u3eLygus Lineolaris\u3c/i\u3e (Hemiptera: [Heteroptera]: Miridae)

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    The tarnished plant bug, known principally as an agricultural pest, injures young hybrid Populus by feeding on the stems and meristems. Tarnished plant bug eggs, fungi associated with some lesions, and simple mechanical stimuli alone from feeding appeared not to cause lesion formation. Of 20 Populus hybrids tested in a clonal trial, four appeared to be consistently susceptible to lesion injury, with Populus nigra var. betulifolia x trichocarpa the most susceptible. Several clones showed high resistance in the trial but a few were susceptible in other plantings and in host preference tests when caged with tarnished plant bugs. Lesions diminished tenfold on Populus where horseweed, the insect\u27s principal wild host, grew along with susceptible poplars. The tarnished plant bug can be suppressed by ultra-low volume pesticides and cultural manipulation of understory vegetation
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