Visible and near infrared spectroscopy in soil science

This chapter provides a review on the state of soil visible–near infrared (vis–NIR) spectroscopy. Our intention is for the review to serve as a source of up-to date information on the past and current role of vis–NIR spectroscopy in soil science. It should also provide critical discussion on issues surrounding the use of vis–NIR for soil analysis and on future directions. To this end, we describe the fundamentals of visible and infrared diffuse reflectance spectroscopy and spectroscopic multivariate calibrations. A review of the past and current role of vis–NIR spectroscopy in soil analysis is provided, focusing on important soil attributes such as soil organic matter (SOM), minerals, texture, nutrients, water, pH, and heavy metals. We then discuss the performance and generalization capacity of vis–NIR calibrations, with particular attention on sample pre-tratments, co-variations in data sets, and mathematical data preprocessing. Field analyses and strategies for the practical use of vis–NIR are considered. We conclude that the technique is useful to measure soil water and mineral composition and to derive robust calibrations for SOM and clay content. Many studies show that we also can predict properties such as pH and nutrients, although their robustness may be questioned. For future work we recommend that research should focus on: (i) moving forward with more theoretical calibrations, (ii) better understanding of the complexity of soil and the physical basis for soil reflection, and (iii) applications and the use of spectra for soil mapping and monitoring, and for making inferences about soils quality, fertility and function. To do this, research in soil spectroscopy needs to be more collaborative and strategic. The development of the Global Soil Spectral Library might be a step in the right direction

Leaching and phytoavailability of zinc and cadmium in a contaminated soil treated with zero-valent iron

Immobilization of heavy metals by stabilization amendments is a promising method to restore contaminated soils. In our study, we investigated the efficiency of zero-valent iron (Fe0) added to the soil in the form of iron grit to reduce leaching and uptake of Zn and Cd by Lupinus albus L. Results of column leaching experiments show that metal leaching decreased proportionally to the rate of amendment application (1%, 2% or 5%: w/w) and that the reduction reached up to 98% and 83% for Zn and Cd respectively. An increase in pH and in the number of sorption sites which bind ionic free metals and organometal complexes are possible mechanisms for this attenuation. Moreover, a rhizobox experiment has demonstrated that phytoavailability of Zn and Cd was reduced by 63% and 45% respectively when soil was treated with 5% (w/w) iron grit, and that L. albus did not develop strategies to reduce Zn and Cd uptake in untreated soil. We conclude that covering contaminated soil with L. albus could be used in association with immobilization techniques for soil remediation. However, it is crucial that the amendment and the soil be thoroughly homogenized in order to ensure the maximum reduction of metal uptake

Talking soil science with farmers

When agricultural researchers visit farms in order to gather information for their research programmes, farmers rarely get proper feedback. Research information on scientific concepts such as soil fertility and nutrient balances is often considered too abstract for them. Researchers in Kenya returned to farmers to discuss their results in the context of Farmer Field Schools. Through the workshops that ensued, they managed to find a common language to bridge the communication gap

Permanent Agriculture: Precursor to Organic Farming

The concept of Permanent Agriculture predates Organic Agriculture by thirty years. Following a clash with the USDA over the theory of soil fertility, American soil scientist Franklin King wrote "Farmers of Forty Centuries or Permanent Agriculture in China, Korea and Japan" (1911). Permanent Agriculture and Organic Agriculture share many ideas. The founder of Organic Agriculture described Franklin's work as a "classic" which "no student of farming or social science can afford to ignore"

BLACK POLYPROPYLENE MULCH TEXTILE IN ORGANIC AGRICULTURE

Black polyethylene mulch is used for weed control in a range of crops under the organic system. The use of black polypropylene mulch is usually restricted to perennial crops. The trial was conducted at Experimental station of Department of Crop Production of the Czech University of Life Science Prague-Uhříněves in Czech Republic. For the experiments were used black polypropylene woven mulch (comparison wit bare soil), two varieties of early potatoes Finka and Katka. Black polypropylene textile was used in potatoes by organic agriculture and it had positive effect on soil temperature (in the depth of 100 mm). Slightly higher soil temperatures under black polypropylene mulch in the vegetation period after planting had favourable influence on earlier stands emergence. The soil water potential (in the depth of 250 mm) and also the soil water content have been beneficial for black polypropylene mulch. Significantly lower values of the soil water potentials have been found in the period after planting and at the end of vegetation. Black polypropylene mulch provided favourable temperatures and soil moisture. Post harvest analyses were focused on the determination of the yield and quality tubers from each variant

Increase in soil organic carbon by agricultural intensification in northern China

Acknowledgements. This research was supported by National Natural Science Foundation of China (no. 31370527 and 31261140367) and the National Science and Technology Support Program of China (no. 2012BAD14B01-2). The authors gratefully thank the Huantai Agricultural Station for providing of the Soil Fertility Survey data. We also thank Zheng Liang from China Agricultural University for the soil sampling and analysis in 2011. Thanks are extended to Jessica Bellarby for helpful discussion and suggestions.Peer reviewedPublisher PD

Impacts of model calibration on high-latitude land-surface processes: PILPS 2(e) calibration/validation experiments

In the PILPS 2(e) experiment, the Snow Atmosphere Soil Transfer (SAST) land-surface scheme developed from the Biosphere-Atmosphere Transfer Scheme (BATS) showed difficulty in accurately simulating the patterns and quantities of runoff resulting from heavy snowmelt in the high-latitude Torne-Kalix River basin (shared by Sweden and Finland). This difficulty exposes the model deficiency in runoff formations. After representing subsurface runoff and calibrating the parameters, the accuracy of hydrograph prediction improved substantially. However, even with the accurate precipitation and runoff, the predicted soil moisture and its variation were highly "model-dependent". Knowledge obtained from the experiment is discussed. © 2003 Elsevier Science B.V. All rights reserved

Conceptual designs for in situ analysis of Mars soil

A goal of this research is to develop conceptual designs for instrumentation to perform in situ measurements of the Martian soil in order to determine the existence and nature of any reactive chemicals. Our approach involves assessment and critical review of the Viking biology results which indicated the presence of a soil oxidant, an investigation of the possible application of standard soil science techniques to the analysis of Martian soil, and a preliminary consideration of non-standard methods that may be necessary for use in the highly oxidizing Martian soil. Based on our preliminary analysis, we have developed strawman concepts for standard soil analysis on Mars, including pH, suitable for use on a Mars rover mission. In addition, we have devised a method for the determination of the possible strong oxidants on Mars