Recent Advances in Model-Based Fault Diagnosis for Lithium-Ion Batteries: A Comprehensive Review

Lithium-ion batteries (LIBs) have found wide applications in a variety of fields such as electrified transportation, stationary storage and portable electronics devices. A battery management system (BMS) is critical to ensure the reliability, efficiency and longevity of LIBs. Recent research has witnessed the emergence of model-based fault diagnosis methods in advanced BMSs. This paper provides a comprehensive review on the model-based fault diagnosis methods for LIBs. First, the widely explored battery models in the existing literature are classified into physics-based electrochemical models and electrical equivalent circuit models. Second, a general state-space representation that describes electrical dynamics of a faulty battery is presented. The formulation of the state vectors and the identification of the parameter matrices are then elaborated. Third, the fault mechanisms of both battery faults (incl. overcharege/overdischarge faults, connection faults, short circuit faults) and sensor faults (incl. voltage sensor faults and current sensor faults) are discussed. Furthermore, different types of modeling uncertainties, such as modeling errors and measurement noises, aging effects, measurement outliers, are elaborated. An emphasis is then placed on the observer design (incl. online state observers and offline state observers). The algorithm implementation of typical state observers for battery fault diagnosis is also put forward. Finally, discussion and outlook are offered to envision some possible future research directions.Comment: Submitted to Renewable and Sustainable Energy Reviews on 09-Jan-202

Comparison of methodologies to estimate state-of-health of commercial Li-ion cells from electrochemical frequency response data

Various impedance-based and nonlinear frequency response-based methods for determining the state-of-health (SOH) of commercial lithium-ion cells are evaluated. Frequency response-based measurements provide a spectral representation of dynamics of underlying physicochemical processes in the cell, giving evidence about its internal physical state. The investigated methods can be carried out more rapidly than controlled full discharge and thus constitute prospectively more efficient measurement procedures to determine the SOH of aged lithium-ion cells. We systematically investigate direct use of electrochemical impedance spectroscopy (EIS) data, equivalent circuit fits to EIS, distribution of relaxation times analysis on EIS, and nonlinear frequency response analysis. SOH prediction models are developed by correlating key parameters of each method with conventional capacity measurement (i.e., current integration). The practical feasibility, reliability and uncertainty of each of the established SOH models are considered: all models show average RMS error in the range 0.75%–1.5% SOH units, attributable principally to cell-to-cell variation. Methods based on processed data (equivalent circuit, distribution of relaxation times) are more experimentally and numerically demanding but show lower average uncertainties and may offer more flexibility for future application

Reduce state of charge estimation errors with an extended Kalman filter algorithm

Li-ion batteries (LiBs) are accurately estimated under varying operating conditions and external influences using extended Kalman filtering (EKF). Estimating the state of charge (SOC) is essential for enhancing battery efficiency, though complexities and unpredictability present obstacles. To address this issue, the paper proposes a second-order resistance-capacitance (RC) battery model and derives the EKF algorithm from it. The EKF approach is chosen for its ability to handle complex battery behaviors. Through extensive evaluation using a Simulink MATLAB program, the proposed EKF algorithm demonstrates remarkable accuracy and robustness in SOC estimation. The root mean square error (RMSE) analysis shows that SOC estimation errors range from only 0.30% to 2.47%, indicating substantial improvement over conventional methods. These results demonstrate the effectiveness of an EKF-based approach in overcoming external influences and providing precise SOC estimations to optimize battery management. In addition to enhancing battery performance, the results of the study may lead to the development of more reliable energy storage systems in the future. This will contribute to the wider adoption of LiBs in various applications

Modelling and estimation in lithium-ion batteries: a literature review

Lithium-ion batteries are widely recognised as the leading technology for electrochemical energy storage. Their applications in the automotive industry and integration with renewable energy grids highlight their current significance and anticipate their substantial future impact. However, battery management systems, which are in charge of the monitoring and control of batteries, need to consider several states, like the state of charge and the state of health, which cannot be directly measured. To estimate these indicators, algorithms utilising mathematical models of the battery and basic measurements like voltage, current or temperature are employed. This review focuses on a comprehensive examination of various models, from complex but close to the physicochemical phenomena to computationally simpler but ignorant of the physics; the estimation problem and a formal basis for the development of algorithms; and algorithms used in Li-ion battery monitoring. The objective is to provide a practical guide that elucidates the different models and helps to navigate the different existing estimation techniques, simplifying the process for the development of new Li-ion battery applications.This research received support from the Spanish Ministry of Science and Innovation under projects MAFALDA (PID2021-126001OB-C31 funded by MCIN/AEI/10.13039/501100011033/ ERDF,EU) and MASHED (TED2021-129927B-I00), and by FI Joan Oró grant (code 2023 FI-1 00827), cofinanced by the European Union.Peer ReviewedPostprint (published version

SoC estimation for lithium-ion batteries : review and future challenges

ABSTRACT: Energy storage emerged as a top concern for the modern cities, and the choice of the lithium-ion chemistry battery technology as an effective solution for storage applications proved to be a highly efficient option. State of charge (SoC) represents the available battery capacity and is one of the most important states that need to be monitored to optimize the performance and extend the lifetime of batteries. This review summarizes the methods for SoC estimation for lithium-ion batteries (LiBs). The SoC estimation methods are presented focusing on the description of the techniques and the elaboration of their weaknesses for the use in on-line battery management systems (BMS) applications. SoC estimation is a challenging task hindered by considerable changes in battery characteristics over its lifetime due to aging and to the distinct nonlinear behavior. This has led scholars to propose different methods that clearly raised the challenge of establishing a relationship between the accuracy and robustness of the methods, and their low complexity to be implemented. This paper publishes an exhaustive review of the works presented during the last five years, where the tendency of the estimation techniques has been oriented toward a mixture of probabilistic techniques and some artificial intelligence

Remaining Useful Life Prediction for Lithium-ion Batteries Based on Capacity Estimation and Box-Cox Transformation

IEEE Remaining useful life (RUL) prediction of lithium-ion batteries plays an important role in intelligent battery management systems (BMSs). The current RUL prediction methods are mainly developed based on offline training, which are limited by sufficiency and reliability of available data. To address this problem, this paper presents a method for RUL prediction based on the capacity estimation and the Box-Cox transformation (BCT). Firstly, the effective aging features (AFs) are extracted from electrical and thermal characteristics of lithium-ion batteries and the variation in terms of the cyclic discharging voltage profiles. The random forest regression (RFR) is then employed to achieve dependable capacity estimation based on only one cells degradation data for model training. Secondly, the BCT is exploited to transform the estimated capacity data and to construct a linear model between the transformed capacities and cycles. Next, the ridge regression algorithm (RRA) is adopted to identify the parameters of the linear model. Finally, the identified linear model based on the BCT is employed to predict the battery RUL, and the prediction uncertainties are investigated and the probability density function (PDF) is calculated through the Monte Carlo (MC) simulation. The experimental results demonstrate that the proposed method can not only estimate capacity with errors of less than 2%, but also accurately predict the battery RUL with the maximum error of 127 cycles and the maximum spans of 95% confidence of 37 cycles in the whole cycle life

Influence of Battery Parametric Uncertainties on the State-of-Charge Estimation of Lithium Titanate Oxide-Based Batteries

State of charge (SOC) is one of the most important parameters in battery management systems, as it indicates the available battery capacity at every moment. There are numerous battery model-based methods used for SOC estimation, the accuracy of which depends on the accuracy of the model considered to describe the battery dynamics. The SOC estimation method proposed in this paper is based on an Extended Kalman Filter (EKF) and nonlinear battery model which was parameterized using extended laboratory tests performed on several 13 Ah lithium titanate oxide (LTO)-based lithium-ion batteries. The developed SOC estimation algorithm was successfully verified for a step discharge profile at five different temperatures and considering various initial SOC initialization values, showing a maximum SOC estimation error of 1.16% and a maximum voltage estimation error of 44 mV. Furthermore, by carrying out a sensitivity analysis it was showed that the SOC and voltage estimation error are only slightly dependent on the variation of the battery model parameters with the SOC