Biomass-supported catalysts on Desulfovibrio desulfuricans and Rhodobacter sphaeroides

A Rhodobacter sphaeroides-supported dried, ground palladium catalyst (‘‘Rs-Pd(0)’’) was compared with a Desulfovibrio desulfuricans-supported catalyst (‘‘Dd-Pd(0)’’)and with unsupported palladium metal particles made by reduction under H2 (‘‘Chem-Pd(0)’’). Cell surface-located clusters of Pd(0) nanoparticles were detected on both D. desulfuricans and R. sphaeroides but the size and location of deposits differed among comparably loaded preparations.\ud \ud These differences may underlie the observation of different activities of Dd-Pd(0) and Rs-Pd(0) when compared with respect to their ability to promote hydrogen release from hypophosphite and to catalyze chloride release from chlorinated aromatic compounds. Dd-Pd(0) was more effective in the reductive dehalogenation of polychlorinated biphenyls (PCBs), whereas Rs-Pd(0) was more effective in the initial dehalogenation of pentachlorophenol (PCP) although the rate of chloride release from PCP was comparable with both preparations after 2 h

EXAFS studies on the reduction of palladium(II) in X zeolites

Palladium tetraammine ion exchange into zeolite, temperature treatments under different atmospheres, and hydrogen reduction have been studied by EXAFS at the Pd Κ edge. Complete autoreduction is found to take place between 473 and 623 Κ under vacuum. Α bidisperse Pd metal phase is formed which agglomerates at the expense of the small particles upon prolonged heating at 623 Κ. In contrast, a similar treatment under oxygen suppresses autoreduction , and the Pd cations remain in zeolite coordination sites. Additional small amounts of palladium oxide are observed under these conditions. If hydrogen is admitted to the dehydrated, ionic system at 295 K. the oxygen coordination of the Pd disappears and evidence is obtained for the formation of Pd(0) dimers that interact with the framework via a long Pd-0 bond

Dynamics of 1S0^{1}S_0 diproton formation in the pd→{pp}snpd\to \{pp\}_sn and pN→{pp}sπpN\to \{pp\}_s\pi reactions in the GeV region

Mechanisms for the production of $^1S_0$ diproton pairs, ${pp}_s$, in the $pd\to {pp}_s n$ reaction are studied at proton beam energies 0.5 -- 2 GeV in kinematics similar to those of backward elastic $pd$ scattering. This reaction provides valuable information on the short-range $NN$ and $pd$ interactions that is complementary to that investigated in the well known $pd\to dp$ and $dp\to p(0^\circ)X$ processes. The $pd\to {pp}_sn$ reaction is related to the subprocesses $\pi^0 d\to pn$ and $pN\to {pp}_s \pi$ using two different one--pion--exchange (OPE) diagrams. Within both these models a reasonable agreement could be obtained with the data below 1GeV. The similar energy dependence of the $pd\to\{pp\}_s n$ and $pd\to dp$ cross sections and the small ratio of about 1.5% in the production of $\{pp\}_s$ to deuteron final states follow naturally within the OPE models.Comment: 10 pages, 7 figures, Late

Phase separation and valence instabilities in cuprate superconductors. Effective one-band model approach

We study the Cu-O valence instability (VI) and the related phase separation (PS) driven by Cu-O nearest-neighbor repulsion $U_{pd}$, using an effective extended one-band Hubbard model ($H_{eff}$) obtained from the extended three-bandHubbard model, through an appropriate low-energy reduction. $H_{eff}$ is solved by exact diagonalization of a square cluster with 10 unit cells and also within a slave-boson mean-field theory. Its parameters depend on doping for $U_{pd}\neq 0$ or on-site O repulsion $U_p\neq 0$. The results using both techniques coincide in that there is neither VI nor PS for doping levels $x<0.5$ if $U_{pd}\lesssim 2$ eV. The PS region begins for $U_{pd}\gtrsim 2$ eV at large doping $x>0.6$ and increases with increasing $U_{pd}$. The PS also increases with increasing on-site Cu repulsion $U_d$.Comment: 16 pages and 10 figures in postscript format, compressed with uufile

Pinning Down versus Density

The pinning down number ${pd}(X)$ of a topological space $X$ is the smallest cardinal $\kappa$ such that for any neighborhood assignment $U:X\to \tau_X$ there is a set $A\in [X]^\kappa$ with $A\cap U(x)\ne\emptyset$ for all $x\in X$. Clearly, c$(X) \le {pd}(X) \le {d}(X)$. Here we prove that the following statements are equivalent: (1) $2^\kappa<\kappa^{+\omega}$ for each cardinal $\kappa$; (2) ${d}(X)={pd}(X)$ for each Hausdorff space $X$; (3) ${d}(X)={pd}(X)$ for each 0-dimensional Hausdorff space $X$. This answers two questions of Banakh and Ravsky. The dispersion character $\Delta(X)$ of a space $X$ is the smallest cardinality of a non-empty open subset of $X$. We also show that if ${pd}(X)<{d}(X)$ then $X$ has an open subspace $Y$ with ${pd}(Y)<{d}(Y)$ and $|Y| = \Delta(Y)$, moreover the following three statements are equiconsistent: (i) There is a singular cardinal $\lambda$ with $pp(\lambda)>\lambda^+$, i.e. Shelah's Strong Hypothesis fails; (ii) there is a 0-dimensional Hausdorff space $X$ such that $|X|=\Delta(X)$ is a regular cardinal and ${pd}(X)<{d}(X)$; (iii) there is a topological space $X$ such that $|X|=\Delta(X)$ is a regular cardinal and ${pd}(X)<{d}(X)$. We also prove that $\bullet$ ${d}(X)={pd}(X)$ for any locally compact Hausdorff space $X$; $\bullet$ for every Hausdorff space $X$ we have $|X|\le 2^{2^{{pd}(X)}}$ and ${pd}(X)<{d}(X)$ implies $\Delta(X)< 2^{2^{{pd}(X)}}$; $\bullet$ for every regular space $X$ we have $\min\{\Delta(X),\, w(X)\}\le 2^{{pd}(X)}\,$ and ${d}(X)<2^{{pd}(X)},\,$ moreover ${pd}(X)<{d}(X)$ implies $\,\Delta(X)< {2^{{pd}(X)}}$

Exclusive Measurements of pd→3Heππpd\to ^3He \pi\pi : the ABCABC Effect Revisited

Exclusive measurements of the reactions $pd\to$ $^3He \pi^+ \pi^-$ and $pd\to$ $^3He \pi^0\pi^0$ have been carried out at $T_p=0.895$ GeV at the CELSIUS storage ring using the WASA detector. The $\pi^+\pi^-$ channel evidences a pronounced enhancement at low invariant $\pi\pi$ masses - as anticipated from previous inclusive measurements of the ABC effect. This enhancement is seen to be even much larger in the isoscalar $\pi^0\pi^0$ channel. The differential distributions prove this enhancement to be of scalar-isoscalar nature. $\Delta\Delta$ calculations give a good description of the data, if a boundstate condition is imposed for the intermediate $\Delta\Delta$ system.Comment: extended version, 8 pages, 7 figures, theoretical model calculations adde