Adhesion evaluation of asphalt-aggregate interface using surface free energy method

The influence of organic additives (Sasobit and RH) and water on the adhesion of the asphalt-aggregate interface was studied according to the surface free energy theory. Two asphalt binders (SK-70 and SK-90), and two aggregate types (limestone and basalt) were used in this study. The sessile drop method was employed to test surface free energy components of asphalt, organic additives and aggregates. The adhesion models of the asphalt-aggregate interface in dry and wet conditions were established, and the adhesion work was calculated subsequently. The energy ratios were built to evaluate the effect of organic additives and water on the adhesiveness of the asphalt-aggregate interface. The results indicate that the addition of organic additives can enhance the adhesion of the asphalt-aggregate interface in dry conditions, because organic additives reduced the surface free energy of asphalt. However, the organic additives have hydrophobic characteristics and are sensitive to water. As a result, the adhesiveness of the asphalt-aggregate interface of the asphalt containing organic additives in wet conditions sharply decreased due to water damage to asphalt and organic additives. Furthermore, the compatibility of asphalt, aggregate with organic additive was noted and discussed

A study of solid-propellant vaporization and diffusion processes Final technical report

Vaporization rate and diffusion coefficient determined for organic additives to polyurethane solid propellants - dioctyl adipate and ferrocen

The influence of additives on the current carrying capacity of bulk YBa2Cu3OX

We studied the influence of using different powders and several additives on the shaping process and critical current density of sintered bulk YBa2Cu3OX. It was found that all additives used facilitated the shaping process. Silver and most organic additives influenced the critical current density only little, Zinc reduced it to zero, but an ethylenebisstearoylamide compound doubled the critical current density as compared to samples without additives

Factors influence flexibility resistivity and zinc dendrite penetration rate of inorganic separators for alkaline batteries

Developmental work resulted in a formulation which can improve the flexibility of the inorganic-organic-type separator for silver-zinc and nickel-zinc alkaline batteries. The effects of various fillers and reactive organic additives on separator volume resistivity are described. The effects of various inert fillers on the zinc dendrite penetration rate of the separator are shown. Conclusions regarding the operating mechanism of the separator are presented

The size and polydispersity of silica nanoparticles under simulated hot spring conditions

The nucleation and growth of silica nanoparticles in supersaturated geothermal waters was simulated using a flow-through geothermal simulator system. The effect of silica concentration ([SiO2]), ionic strength (IS), temperature (T) and organic additives on the size and polydispersity of the forming silica nanoparticles was quantified. A decrease in temperature (58 to 33°C) and the addition of glucose restricted particle growth to sizes <20 nm, while varying [SiO2] or ISdid not affect the size (30-35 nm) and polydispersity (±9 nm) observed at 58°C. Conversely, the addition of xanthan gum induced the development of thin films that enhanced silica aggregation

Accumulators for the Capture of Heavy Metals in Thermal Conversion Systems

International audienceA clay ceramic with organic additives (biomass and biochar) was investigated for the development of highly porous accumulators to capture heavy metals in thermal conversion systems. The structure was characterized using X-ray pair distribution function analysis, differential scanning calorimetry, and scanning electron microscopy. It was found that the organic additives transformed into porosity during firing. The morphology of the pores also corresponded to the morphology of the organic additives. Hence, the clay ceramic with a 15-wt% addition of biochar had a porosity of 46 vol% with 20-μm interconnected pores after firing. The resulting accumulator was found to capture cadmium (a model for heavy metals with high volatility) via condensation of the cadmium vapor as 2-μm beads in the pores. The cadmium capture efficiency reached up to 57% using a 15-wt% addition of biochar. Furthermore, cadmium was captured at higher temperatures than the condensation temperature in the atmosphere. This means that heavy metals may be captured before they condense in fly ash to promote the recycling of this material

Applications of Direct Injection Soft Chemical Ionisation-Mass Spectrometry for the Detection of Pre-blast Smokeless Powder Organic Additives

Analysis of smokeless powders is of interest from forensics and security perspectives. This article reports the detection of smokeless powder organic additives (in their pre-detonation condition), namely the stabiliser diphenylamine and its derivatives 2-nitrodiphenylamine and 4-nitrodiphenylamine, and the additives (used both as stabilisers and plasticisers) methyl centralite and ethyl centralite, by means of swab sampling followed by thermal desorption and direct injection soft chemical ionisation-mass spectrometry. Investigations on the product ions resulting from the reactions of the reagent ions H3O+ and O2+ with additives as a function of reduced electric field are reported. The method was comprehensively evaluated in terms of linearity, sensitivity and precision. For H3O+, the limits of detection (LoD) are in the range of 41-88 pg of additive, for which the accuracy varied between 1.5 and 3.2%, precision varied between 3.7 and 7.3% and linearity showed R20.9991. For O2+, LoD are in the range of 72 to 1.4 ng, with an accuracy of between 2.8 and 4.9% and a precision between 4.5 and 8.6% and R20.9914. The validated methodology was applied to the analysis of commercial pre-blast gun powders from different manufacturers.(VLID)4826148Accepted versio

Organic compounds in hydraulic fracturing fluids and wastewaters: A review

High volume hydraulic fracturing (HVHF) of shale to stimulate the release of natural gas produces a large quantity of wastewater in the form of flowback fluids and produced water. These wastewaters are highly variable in their composition and contain a mixture of fracturing fluid additives, geogenic inorganic and organic substances, and transformation products. The qualitative and quantitative analyses of organic compounds identified in HVHF fluids, flowback fluids, and produced waters are reviewed here to communicate knowledge gaps that exist in the composition of HVHF wastewaters. In general, analyses of organic compounds have focused on those amenable to gas chromatography, focusing on volatile and semi-volatile oil and gas compounds. Studies of more polar and non-volatile organic compounds have been limited by a lack of knowledge of what compounds may be present as well as quantitative methods and standards available for analyzing these complex mixtures. Liquid chromatography paired with high-resolution mass spectrometry has been used to investigate a number of additives and will be a key tool to further research on transformation products that are increasingly solubilized through physical, chemical, and biological processes in situ and during environmental contamination events. Diverse treatments have been tested and applied to HVHF wastewaters but limited information has been published on the quantitative removal of individual organic compounds. This review focuses on recently published information on organic compounds identified in flowback fluids and produced waters from HVHF