Measurements of surface river Doppler velocities with along-track InSAR using a single antenna

Nowadays, a worldwide database containing the historical and reliable data concerning the water surface speed of rivers is not available and would be highly desirable. In order to meet this requirement, the present work is aimed at the design of an estimation procedure for water flow velocity by means of synthetic aperture radar (SAR) data. The main technical aspect of the proposed procedure is that an along-track geometry is synthesized using a single antenna and a single image. This is achieved by exploiting a multichromatic analysis in the Doppler domain. The application of this approach allows us to obtain along-track interferometry equivalent virtual baselines much lower than the equivalent baseline corresponding to the decorrelation time of raw data preserving data coherence. The performance analysis, conducted on live airborne full-polarimetric SAR data, highlights the effectiveness of the proposed approach in providing reliable river surface velocity estimates without the need of multiple passes on the observed scene

Retrieval of Ocean Surface Currents and Winds Using Satellite SAR backscatter and Doppler frequency shift

Ocean surface winds and currents play an important role for weather, climate, marine life, ship navigation, oil spill drift and search and rescue. In-situ observations of the ocean are sparse and costly. Satellites provide a useful complement to these observations. Synthetic aperture radar (SAR) is particularly attractive due to its high spatial resolution and its capability to extract both sea surface winds and currents day and night and almost independent of weather.The work in this thesis involves processing of along-track interferometric SAR (ATI-SAR) data, analysis of the backscatter and Doppler frequency shift, and development of wind and current retrieval algorithms. Analysis of the Doppler frequency shift showed a systematic bias. A calibration method was proposed and implemented to correct for this bias. Doppler analysis also showed that the wave contribution to the SAR Doppler centroid often dominates over the current contribution. This wave contribution is estimated using existing theoretical and empirical Doppler models. For wind and current retrieval, two methods were developed and implemented.The first method, called the direct method, consists of retrieval of the wind speed from SAR backscatter using an empirical backscatter model. In order to retrieve the radial current, the retrieved wind speed is used to correct for the wave contribution. The current retrieval was assessed using two different (theoretical and empirical) Doppler models and wind inputs (model and SAR-derived). It was found that the results obtained by combining the Doppler empirical model with the SAR-derived wind speed were more consistent with ocean models.The second method, called Bayesian method, consists of blending the SAR observables (backscatter and Doppler shift) with an atmospheric and an oceanic model to retrieve the total wind and current vector fields. It was shown that this method yields more accurate estimates, i.e. reduces the models biases against in-situ measurements. Moreover, the method introduces small scale features, e.g. fronts and meandering, which are weakly resolved by the models.The correlation between the surface wind vectors and the SAR Doppler shift was demonstrated empirically using the Doppler shift estimated from over 300 TanDEM-X interferograms and ECMWF reanalysis wind vectors. Analysis of polarimetric data showed that theoretical models such as Bragg and composite surface models over-estimate the backscatter polarization ratio and Doppler shift polarization difference. A combination of a theoretical Doppler model and an empirical modulation transfer function was proposed. It was found that this model is more consistent with the analyzed data than the pure theoretical models.The results of this thesis will be useful for integrating SAR retrievals in ocean current products and assimilating SAR observables in the atmospheric, oceanic or coupled models. The results are also relevant for preparation studies of future satellite missions

Crystal Cartography: Mapping Nanostructure with Scanning Electron Diffraction

Nanostructure describes the network of defective and distorted atomic structure existing on the nanoscale within materials. This nanostructure bridges the gap between idealised crys- talline structure and real materials, playing a deterministic role in tailoring physico-chemical properties, as well as providing a basis for mechanistic understanding of complex processes such as mechanical deformation and phase transformation. Characterising nanostructure, to develop understanding of materials, requires experimental techniques capable of probing the structure with spatial resolution on the order of nanometres and across regions of interest up to micrometres. Recent developments in electron microscopy, enabling the acquisition of numerous diffraction patterns in a spatially resolved manner, combined with modern computational power, provides a route to meet this need as developed in this work. Scanning electron diffraction (SED) involves the acquisition of a two-dimensional elec- tron diffraction pattern at each probe position in a two-dimensional scan of a specimen. An information rich 4-dimensional (4D-SED) dataset is obtained that can be analysed extensively post-facto using a wide-range of computational methods. The acquisition of such 4D-SED data from the specimen at numerous orientations may also enable the reconstruction of nanostructure in three-dimensions via tomographic methods. In this work, methods for the acquisition and analysis of 4D-SED data are developed and applied to reveal nanostructure in two and three-dimensions. These methods are applied to various prototypical characterisation challenges in materials science, particularly: strain mapping in two and three dimensions, revealing inter-phase crystallographic relationships, mapping grains in two-dimensional materials, and probing nanostructure in polyethylene

High-accuracy digital elevation model generation and ship monitoring from synthetic aperture radar images: innovative techniques and experimental results.

In this Thesis several state-of-the-art and innovative techniques for Digital Elevation Model (DEM) generation from Synthetic Aperture Radar (SAR) images are deeply analyzed, with a special focus on the methods which allow the improvement of the accuracy of the DEM product, which is directly related to the geolocation accuracy of geocoded images and is considered as an enabling factor for a large series of civilian and Defence applications. Furthermore, some of the proposed techniques, which are based both on phase and amplitude information, are experimented on real data, i.e. COSMO-SkyMed (CSK) data, assessing the achievable performances compared with the state-of-the-art, and pointing out and quantitatively highlighting the acquisition and processing strategies which would allow to maximize the quality of the results. Moreover, a critical analysis is performed about the main errors affecting the applied techniques, as well as the limitations of the orbital configurations, identifying several complementary techniques which would allow to overcome or mitigate the observed drawbacks. An innovative procedure for on-demand DEM production from CSK SAR data is elaborated and proposed, as well as an auto-validation technique which would enable the validation of the produced DEM also where vertical ground truths are not available. Based on the obtained results and on the consequent critical analysis, several interferometric specifications for new generation SAR satellites are identified. Finally, a literature review is proposed about the main state-of-the-art ship monitoring techniques, considered as one of the main fields of application which takes benefit from SAR data, based on single/multi-platform multi-channel SAR data, with a focus on TanDEM-X (TDX). In particular, in Chapter 1 the main concepts concerning SAR operating principles are introduced and the main characteristics and performances of CSK and TDX satellite systems are described; in Chapter 2 a review is proposed about the state-of-the-art SAR interferometric techniques for DEM generation, analyzing all the relevant processing steps and deepening the study of the main solutions recently proposed in the literature to increase the accuracy of the interferometric processing; in Chapter 3 complementary and innovative techniques respect to the interferometric processing are analyzed to mitigate disadvantages and to improve performances; in Chapter 4 experimental results are presented, obtained in the generation of high accuracy DEM by applying to a dataset of CSK images properly selected state-of-the-art interferometric techniques and innovative methods to improve DEM accuracy, exploring relevant limitations, and pointing out innovative acquisition and processing strategies. In Chapter 5, the basic principles of Ground Moving Target Indication (GMTI) are described, focusing on Displaced Phase Center Antenna (DPCA) and Along-Track Interferometry (ATI) techniques

Measuring ocean surface velocities with the KuROS and KaRADOC airborne near-nadir Doppler radars: a multi-scale analysis in preparation of the SKIM mission, Submitted to Ocean SCience, July 2019

Surface currents are poorly known over most of the oceans. Satellite-borne Doppler Waves and Current Scatterom-eters (DWCS) can be used to fill this observation gap. The Sea surface KInematics Multiscale (SKIM) proposal, is the first satellite concept built on a DWCS design at near-nadir angles, and now one of the two candidates to become the 9th mission of the European Space Agency Earth Explorer program. As part of the detailed design and feasibility studies (phase A) funded by ESA, airborne measurements were carried out with both a Ku-Band and a Ka-Band Doppler radars looking at the sea surface at 5 near nadir-incidence in a real-aperture mode, i.e. in a geometry and mode similar to that of SKIM. The airborne radar KuROS was deployed to provide simultaneous measurements of the radar backscatter and Doppler velocity, in a side-looking configuration , with an horizontal resolution of about 5 to 10 m along the line of sight and integrated in the perpendicular direction over the real-aperture 3-dB footprint diameter (about 580 m). The KaRADOC system has a much narrower beam, with a circular footprint only 45 m in diameter. 10 The experiment took place in November 2018 off the French Atlantic coast, with sea states representative of the open ocean and a well known tide-dominated current regime. The data set is analyzed to explore the contribution of non-geophysical velocities to the measurement and how the geophysical part of the measured velocity combines wave-resolved and wave-averaged scales. We find that the measured Doppler velocity contains a characteristic wave phase speed, called here C 0 that is analogous to the Bragg phase speed of coastal High Frequency radars that use a grazing measurement geometry, with little 15 variations ∆ C associated to changes in sea state. The Ka-band measurements at an incidence of 12 • are 10% lower than the theoretical estimate C 0 2.4 m/s for typical oceanic conditions defined by a wind speed of 7 m/s and a significant wave height of 2 m. For Ku-band the measured data is 1 https://doi. 30% lower than the theoretical estimate 2.8 m/s. ∆ C is of the order of 0.2 m/s for a 1 m change in wave height, and cannot be confused with a 1 m/s change in tidal current. The actual measurement of the current velocity from an aircraft at 4 to 18 • incidence angle is, however, made difficult by uncertainties on the measurement geometry, which are much reduced in satellite measurements

Coulomb explosions dynamics

Chemical reaction dynamics studies emerged with the advent of quantum mechanical theories in 1920s which have the capability of predicting the atomic motions by calculating potential energy surfaces. Experimental studies in this field began to flourish with the advances in molecular beam generation and laser beam technologies many years later leading to the Nobel prize awarded to Herschbach, Lee, and Polanyi in 1986. Later in 1980s, advances in the production of frequency tunable ultrashort laser pulses with the temporal resolution of femtoseconds led to the birth of the field of femto-chemistry which is the study of molecular dynamics in real time. In the last few decades, various spectroscopic techniques exploiting ultrashort laser pulses have been developed to study the non-adiabatic dynamics of molecules in real time and space. Laser-induced Coulomb Explosion Imaging (CEI) is a powerful probe technique now emerging in this field, to unravel the structural changes of molecular systems in real time. Extracting structural information from CEI requires imaging of multiple fragments at each experimental cycle which allows us to obtain their relative velocity distribution. In this work, we successfully coupled a three-dimensional multi-mass coincidence detection technique with CEI to study the dissociation dynamics of complicated polyatomic molecules. Covariance imaging, which is a statistical technique yielding correlated information, was used to find the related momenta of various pairs of ions and reveal different dissociation channels of the parent multi-cation. Using the combination of these techniques, the strong field dissociative ionization of chlorocarbonylsulfenyl chloride (CCSC) and methoxycarbonylsulfenyl chloride (MCSC) (belonging to thioester family) were studied. The ultrafast electron diffraction (UED) technique is a complementary method to ultrafast laser spectroscopy, capable of directly resolving the electronic and nuclear dynamics in real time and space due to sensitivity to the spatial atomic distribution in the system. MeV UED facility is a newly developed apparatus at the SLAC National Accelerator Laboratory offering femtosecond time resolution and sub-Angstrom spatial resolution in the study of gas phase molecular systems. Using this facility, we performed a time-resolved UED experiment to study the UV photodissociation of oxalyl chloride. Previous theoretical and experimental studies have suggested non-consistent results for the UV dissociation of this molecule which results in four fragments upon absorption a single photon. Here, with the initial analysis of diffraction images, and comparison with the theory, we confirmed a concerted four-body dissociation channel as the main mechanism.Includes bibliographical references

Atomic imaging of complex molecular

One of the significant challenges of modern science is to track and image chemical reactions as they occur. The molecular movies, the precise spatiotemporal tracking of changes in their molecular dynamics, will provide a wealth of actionable insights into how nature works. Experimental techniques need to resolve the relevant molecular motions in atomic resolution, which includes (10^(-10) m) spatial dimensions and few- to hundreds of femtoseconds (10^(-15) s) temporal resolution. Laser-induced electron diffraction (LIED), a laser-based electron diffraction technique, images even singular molecular structures with combined sub-atomic picometre and femto-to attosecond spatiotemporal resolution. Here, a laser-driven attosecond electron wave packet scatters the parent’s ion after photoionization. The measured diffraction pattern of the electrons provides a unique fingerprint of molecular structure. Taking snapshots of molecular dynamics via the LIED technique is proved to be a potent tool to understand the intertwining of molecules and how they react, change, break, bend, etc. This thesis is especially interested in exploiting advanced LIED imaging techniques to retrieve large complex molecular structures. So far, LIED has successfully retrieved molecular information from small gas-phase molecules like oxygen (O2), nitrogen (N2), acetylene (C2H2), carbon disulfide (CS2), ammonia (NH3) and carbonyl sulfide (OCS). Nevertheless, most biology interesting organic molecules typically exist as liquid or solid at room temperature. In order to accomplish the final goal to extract these larger complex molecular structural information, we need to overcome two main challenges: delivering the liquid or solid samples as a gas-phase jet with sufficient gas density in the experiment and developing a new retrieval algorithm to extract the geometrical information from the diffraction pattern. We tested one of the most simple liquid molecules - water H2O in the reaction chamber as a primary step. We traced the variation of H2O+ cation structure under the different electric fields. To solve the problem of unsatisfactory gas density, we present a novel delivery system utilizing Tesla valves that generates more than an order-of-magnitude denser gaseous beam. Machine learning is well qualified to solve difficulties with manifold degrees of freedom. We use convolutional neural networks (CNNs) combined with LIED techniques to enable atomic-resolution imaging of the complex chiral molecule Fenchone (C10H16O).Uno de los desafíos importantes de la ciencia moderna es rastrear y obtener imágenes de las reacciones químicas a medida que ocurren. Las películas moleculares, el seguimiento espaciotemporal preciso de los cambios en su dinámica molecular, proporcionarán una gran cantidad de conocimientos prácticos sobre cómo funciona la naturaleza. Las técnicas experimentales necesitan resolver los movimientos moleculares relevantes en resolución atómica, que incluye ($10^{-10}$ m) dimensional espacial y resolución temporal de pocos a cientos de femtosegundos ($10^{-15}$ s). La difracción de electrones inducida por láser (LIED-Laser-induced electron diffraction), una técnica de difracción de electrones basada en láser, crea imágenes incluso de estructuras moleculares singulares con una resolución espaciotemporal subatómica combinada de picómetro y femto a attosegundo. Aquí, un paquete de ondas de electrones de attosegundos impulsado por láser dispersa el ion del padre después de la fotoionización. El patrón de difracción medido de los electrones proporciona una huella única de la estructura molecular. Se ha demostrado que tomar instantáneas de la dinámica molecular a través de la técnica LIED es una herramienta potente para comprender el entrelazamiento de las moléculas y cómo reaccionan, cambian, se rompen, se doblan, etc. Esta tesis está especialmente interesada en explotar técnicas avanzadas de imagen LIED para recuperar estructuras moleculares grandes y complejas. Hasta ahora, LIED ha recuperado con éxito información molecular de pequeñas moléculas en fase gaseosa como oxígeno (O2), nitrógeno (N2), acetileno (C2H2), disulfuro de carbono (CS2), amoníaco (NH3) y sulfuro de carbonilo (OCS). Sin embargo, la mayoría de las moléculas orgánicas interesantes para la biología suelen existir como líquidas o sólidas a temperatura ambiente. Para lograr el objetivo final de extraer esta información estructural molecular compleja más grande, debemos superar dos desafíos principales: entregar las muestras líquidas o sólidas como un chorro de fase gaseosa con suficiente densidad de gas en el experimento y desarrollar un nuevo algoritmo de recuperación para extraer la información geométrica del patrón de difracción. Probamos una de las moléculas líquidas más simples: agua H2O en la cámara de reacción como primer paso. Trazamos la variación de la estructura del catión H2O+ bajo los diferentes campos eléctricos. Para resolver el problema de la densidad de gas insatisfactoria, presentamos un novedoso sistema de suministro que utiliza válvulas Tesla que genera más de un haz gaseoso más denso en un orden de magnitud. El aprendizaje automático está bien calificado para resolver dificultades con múltiples grados de libertad. Utilizamos redes neuronales convolucionales (CNN-convolutional neural networks) combinadas con técnicas LIED para permitir imágenes de resolución atómica de la molécula quiral compleja Fenchone (C10H16OPostprint (published version