Addition of urease inhibitor has no effect on ammonia volatilization following soil application of poultry litter or organomineral fertilizer, unlike urea.

Abstract: Quantification of ammonia volatilization after addition of animal residues and nitrogen (N) mineral fertilizers to the soil is important for N management in fertilization programs. The objective of this study was to evaluate the effect of adding a urease inhibitor to N fertilizers to minimize ammonia losses following soil application. The experiment was carried out in a laboratory with samples of a Brazilian Oxisol containing 790 g kg-1 clay and 23 g kg-1 organic matter. Treatments consisted of addition of poultry litter (PL), organic mineral fertilizer (OMF) and urea to the soil, with and without the urease inhibitor N-(n-butyl) thiophosphoric triamide (NBPT), plus a control with no fertilizer. We applied the fertilizers over the soil surface, with no soil incorporation, at a rate of 200 mg kg-1 N. Experimental units consisted of PVC tubes with a diameter of 0.15 m, containing 1.0 kg of soil (dry basis). Ammonia volatilization was measured for 56 days following fertilizer application to the soil using sponge discs impregnated with phosphoric acid and glycerin, which were fitted inside the tubes 0.15 m above the soil surface. Ammonia volatilization peaks varied according to the fertilizer, and most of them occurred in the first 15 days following application to the soil. Total ammonia volatilized from the soil treated with PL or OMF had no influence on the urease inhibitor, probably because the losses were small, attaining a maximum of 2.5 and 9 % of the total N applied, respectively. In the treatment that received urea, NBPT delayed the peak of volatilization by three weeks and decreased the loss of ammonia from 22 to 9 % of the N applied. Use of urease inhibitor does not always decrease ammonia volatilization, especially when mixed with fertilizers in which urea is not the only source of N

Life cycle modelling of environmental impacts of application of processed organic municipal solid waste on agricultural land (EASEWASTE)

A model capable of quantifying the potential environmental impacts of agricultural application of composted or anaerobically digested source-separated organic municipal solid waste (MSW) is presented. In addition to the direct impacts, the model accounts for savings by avoiding the production and use of commercial fertilizers. The model is part of a larger model, Environmental Assessment of Solid Waste Systems and Technology (EASEWASTE), developed as a decisionsupport model, focusing on assessment of alternative waste management options. The environmental impacts of the land application of processed organic waste are quantified by emission coefficients referring to the composition of the processed waste and related to specific crop rotation as well as soil type. The model contains several default parameters based on literature data, field experiments and modelling by the agro-ecosystem model, Daisy. All data can be modified by the user allowing application of the model to other situations. A case study including four scenarios was performed to illustrate the use of the model. One tonne of nitrogen in composted and anaerobically digested MSW was applied as fertilizer to loamy and sandy soil at a plant farm in western Denmark. Application of the processed organic waste mainly affected the environmental impact categories global warming (0.4–0.7 PE), acidification (–0.06 (saving)–1.6 PE), nutrient enrichment (–1.0 (saving)–3.1 PE), and toxicity. The main contributors to these categories were nitrous oxide formation (global warming), ammonia volatilization (acidification and nutrient enrichment), nitrate losses (nutrient enrichment and groundwater contamination), and heavy metal input to soil (toxicity potentials). The local agricultural conditions as well as the composition of the processed MSW showed large influence on the environmental impacts. A range of benefits, mainly related to improved soil quality from long-term application of the processed organic waste, could not be generally quantified with respect to the chosen life cycle assessment impact categories and were therefore not included in the model. These effects should be considered in conjunction with the results of the life cycle assessment

Nitrogen loss assessment and environmental consequences in the loess soil of China

Attention is focused on fertilizer nitrogen loss and the environmental consequences in Shaanxi Province in loess region of China, including N losses to the atmosphere via ammonia volatilization, nitrification and denitrification, N losses to groundwater by leaching, and crop uptake by roots. Three soils were selected, Entisol, Anthrosol and Luvisol from north, central and south Shaanxi, respectively. Nitrification and NH4+ fixation were measured using a closed chamber method in the laboratory. Denitrification was tested in the laboratory with intact soil cores, C2H2 inhibition techniques. N2O emission was assessed via in situ measurement of N2O in the soil profile and at the soil surface in field experiments. Fertilizer use and crop yields obtained by the farmers were investigated on a large scale in Shaanxi Province. Transformation of fertilizer NH4+ to NO3- was within nine days in the Entisol and Anthrosols, but it took 40 days in Luvisol due to NH4+ fixation by clay minerals. In the pot experiment open to the wind and sunshine with different water content, applied N fertilizer recovery was 74.2% for the Luvisol and 61.3% for the Entisol. The results for the Luvisol showed lower nitrogen recovery as initial soil water content increased. When the fertilizer was incorporated, the recovery was 91.6% at 8% and 68.9% at 28% water content. Recovery increased with increasing soil clay content. Large amount of nitrate was accumulated at 200-400 cm depth in the soil profile and accounted for 362-543, 144-677 and 165-569 kg N ha-1 in terrace and bottom land in north Shaanxi, terrace land in Guanzhong and south Shaanxi, respectively. N2O measurements also showed that N2O spatial variation in the profile could be ranked as, 10 cm < 30 cm < 150 cm < 90 cm < 60 cm. Temporal variation was correlated with rainfall or irrigation. Closed chamber measurements or calculations from profile concentrations resulted in N2O emission of less than 1 kg N2O ha-1 y-1. An investigation showed that soil fertility in the Guanzhong area is high, but yield has not increased with increasing N fertilizer application during the last five years. Over-application of N fertilizer was very common in the Guanzhong area and ranged from 100 to 382 kg N ha-1 for wheat and from 106 to 530 kg N ha-1 for maize. The results of the experiments indicate that the N fertilizer recovery efficiency is about 30% and the consequences of N losses are seriously threatening the environment by leaching to the groundwater and by denitrification to the atmosphere

Application of processed organic municipal solid waste on agricultural land - a scenario analysis

Source separation, composting and anaerobic digestion, with associated land application, are increasingly being considered as alternative waste management strategies to landfilling and incineration of municipal solid waste (MSW). Environmental life cycle assessments are a useful tool in political decision-making about waste management strategies. However, due to the diversity of processed organic MSW and the situations in which it can be applied, the environmental impacts of land application are very hard to determine by experimental means. In the current study, we used the agroecosystem model Daisy to simulate a range of different scenarios representing different geographical areas, farm and soil types under Danish conditions and legislation. Generally, the application of processed organic MSW resulted in increased emissions compared with the corresponding standard scenarios, but with large differences between scenarios. Emission coefficients for nitrogen leaching to the groundwater ranged from 0.03 to 0.87, while those for nitrogen lost to surface waters through tile drains ranged from 0 to 0.30. Emission coefficients for N2O formation ranged from 0.013 to 0.022 and for ammonia volatilization from 0.016 to 0.11. These estimates are within reasonable range of observed values under similar conditions. Furthermore, a sensitivity analysis showed that the estimates were not very sensitive to the mineralization dynamics of the processed organic MSW. The results show that agroecosystem models can be powerful tools to estimate the environmental impacts of land application of processed MSW under different conditions. Despite this, agroecosystem models have only been used to a very limited degree for this purpose

Nitrogen and sulphur management: challenges for organic sources in temperate agricultural systems

A current global trend towards intensification or specialization of agricultural enterprises has been accompanied by increasing public awareness of associated environmental consequences. Air and water pollution from losses of nutrients, such as nitrogen (N) and sulphur (S), are a major concern. Governments have initiated extensive regulatory frameworks, including various land use policies, in an attempt to control or reduce the losses. This paper presents an overview of critical input and loss processes affecting N and S for temperate climates, and provides some background to the discussion in subsequent papers evaluating specific farming systems. Management effects on potential gaseous and leaching losses, the lack of synchrony between supply of nutrients and plant demand, and options for optimizing the efficiency of N and S use are reviewed. Integration of inorganic and organic fertilizer inputs and the equitable re-distribution of nutrients from manure are discussed. The paper concludes by highlighting a need for innovative research that is also targeted to practical approaches for reducing N and S losses, and improving the overall synchrony between supply and demand

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A low environmental impact system for fertirrigation of maize with cattle slurry

The applicability of an alternative system for managing and distributing cattle slurry during irrigation on maize was evaluated. An experiment was carried out by equipping a traveller boom with drop tubes and fed from a hose-reel machine. The new system was used for the distribution of the liquid separated fraction of slurry mixed with irrigation water (fertigation) on the soil surface between the rows of the crop. This system was compared with the conventional management system, utilizing a tank wagon equipped with splash plate for slurry application and a fixed irrigation system for irrigation. Analysis on leaching water samples indicate that the quality of percolation water is better due to a reduction in nitrate nitrogen losses. Besides, this alternative technique reduces the emissions of ammonia in the air and consequently the diffusion of ammonia in the atmosphere

Global-scale modeling of nitrogen balances at the soil surface

This paper provides global terrestrial surface balances of nitrogen (N) at a resolution of 0.5 by 0.5 degree for the years 1961, 1995 and 2050 as simulated by the model WaterGAP-N. The terms livestock N excretion (Nanm), synthetic N fertilizer (Nfert), atmospheric N deposition (Ndep) and biological N fixation (Nfix) are considered as input while N export by plant uptake (Nexp) and ammonia volatilization (Nvol) are taken into account as output terms. The different terms in the balance are compared to results of other global models and uncertainties are described. Total global surface N surplus increased from 161 Tg N yr-1 in 1961 to 230 Tg N yr-1 in 1995. Using assumptions for the scenario A1B of the Special Report on Emission Scenarios (SRES) of the International Panel on Climate Change (IPCC) as quantified by the IMAGE model, total global surface N surplus is estimated to be 229 Tg N yr-1 in 2050. However, the implementation of these scenario assumptions leads to negative surface balances in many agricultural areas on the globe, which indicates that the assumptions about N fertilizer use and crop production changes are not consistent. Recommendations are made on how to change the assumptions about N fertilizer use to receive a more consistent scenario, which would lead to higher N surpluses in 2050 as compared to 1995

Ammonia volatilization, nitrogen in soil, and growth of barley after application of peat manure and pig slurry

Peat is added to manure, because its low pH and capacity to adsorb ammonia (NH3) give it potential to reduce nitrogen (N) loss. Peat manure was prepared by mixing pig slurry with moderately humified Sphagnum peat. Less than 1% of applied ammoniacal N was volatilized as NH3 from peat manure and pig slurry within 8 h of surface application on clay loam soil according to JTI method. Incorporated manures showed even smaller N loss. The low volatilization was due to the adsorption of manure ammoniacal N by peat, and the infiltration of slurry into harrowed, moist clay soil. In another experiment, peat manure was applied on polypropylene fabric without soil contact. Within the first 3 days there was only 9% reduction in the ammoniacal N of peat manure, but the major part of it was lost during several weeks of dry and warm weather. Peat manure did not cause any major improvements on the growth and N uptake of spring barley in spring and early summer as compared with slurry. Moisture deficit limited the availability of ammoniacal N of manures. As compared with surface application, incorporation of manures increased nitrification of ammonium in the soil, and dry matter mass (19–73%) and N uptake of barley. Supplementing manures with inorganic NPK fertilizer increased both dry matter mass (40–98%) and N concentration of barley stand