112 research outputs found

    Gate oxide failure in MOS devices

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    The thesis presents an experimental and theoretical investigation of gate oxide breakdown in MOS networks, with a particular emphasis on constant voltage overstress failure. It begins with a literature search on gate oxide failure mechanisms, particularly time-dependent dielectric breakdown, in MOS devices. The experimental procedure is then reported for the study of gate oxide breakdown under constant voltage stress. The experiments were carried out on MOSFETs and MOS capacitor structures, recording the characteristics of the devices before and after the stress. The effects of gate oxide breakdown in one of the transistors in an nMOS inverter were investigated and several parameters were found to have changed. A mathematical model for oxide breakdown, based on physical mechanisms, is proposed. Both electron and hole trapping occurred during the constant voltage stress. Breakdown appears to take place when the trapped hole density reach a critical value. PSPICE simulations were performed for the MOSFETs, nMOS inverter and CMOS logic circuits. Two models of MOSFET with gate oxide short were validated. A good agreement between experiments and simulations was achieved

    ์ฐจ์„ธ๋Œ€ ๋ฐ˜๋„์ฒด ๋ฐฐ์„ ์„ ์œ„ํ•œ ์ฝ”๋ฐœํŠธ ํ•ฉ๊ธˆ ์ž๊ฐ€ํ˜•์„ฑ ํ™•์‚ฐ๋ฐฉ์ง€๋ง‰ ์žฌ๋ฃŒ ์„ค๊ณ„ ๋ฐ ์ „๊ธฐ์  ์‹ ๋ขฐ์„ฑ์— ๋Œ€ํ•œ ์—ฐ๊ตฌ

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    ํ•™์œ„๋…ผ๋ฌธ(๋ฐ•์‚ฌ) -- ์„œ์šธ๋Œ€ํ•™๊ต๋Œ€ํ•™์› : ๊ณต๊ณผ๋Œ€ํ•™ ์žฌ๋ฃŒ๊ณตํ•™๋ถ€, 2022.2. ์ฃผ์˜์ฐฝ.Recently, the resistance-capacitance (RC) delay of the Cu interconnects in metal 1 (M1) level has been increased rapidly due to the reduction of the interconnect linewidth along with the transistor scaling down, and the interconnect reliability becomes a severe issue again. In order to overcome interconnect performance problems and move forward to the next-generation interconnects system, study on low resistivity (ฯo) and low electron mean free path (ฮป) metals was conducted. Generally, metals such as Cobalt (Co), Ruthenium (Ru), and Molybdenum (Mo) are mentioned as candidates for next-generation interconnect materials, and since they have a low ฯo ร— ฮป value, it is expected that the influence of interface scatterings and surface scattering can be minimized. However, harsh operating environments such as high electric fields, critical Joule heating, and reduction of the pitch size are severely deteriorating the performance of electronic devices as well as device reliability. For example, since time dependent dielectric breakdown (TDDB) problems for next-generation interconnect system have been reported recently, it is necessary to study alternative barrier materials and processes to improve the interconnect reliability. Specifically, extrinsic dielectric breakdown due to penetration of Co metal ions in high electric fields has been reported as a reliability problem to be solved in Co interconnect systems. Therefore, there is a need for new material system design and research on a robust diffusion barrier that prevents metal ions from penetrating into the dielectric, thereby improving the reliability of Co interconnects. Moreover, in order to lower the resistance of the interconnect, it is necessary to develop an ultra-thin barrier. This is because even a barrier with good reliability characteristics will degrade chip performance if it takes up a lot of volume in the interconnect. The recommended thickness for a single diffusion barrier layer is currently reported to be less than 2.5 nm. As a result, it is essential to develop materials that comprehensively consider performance and reliability. In this study, we designed a Co alloy self-forming barrier (SFB) material that can make sure of low resistance and high reliability for Co interconnects, which is attracting attention as a next-generation interconnect system. The self-forming barrier methodology induces diffusion of an alloy dopant at the interface between the metal and the dielectric during the annealing process. And the diffused dopant reacts with the dielectric to form an ultra-thin diffusion barrier. Through this methodology, it is possible to improve reliability by preventing the movement of metal ions. First of all, material design rules were established to screen the appropriate alloy dopants and all CMOS-compatible metals were investigated. Dopant resistivity, intermetallic compound formation, solubility in Co, activity coefficient in Co, and oxidation tendency is considered as the criteria for the dopant to escape from the Co matrix and react at the Co/SiO2 interface. In addition, thermodynamic calculations were performed to predict which phases would be formed after the annealing process. Based on thermodynamic calculations, 5 dopant metals were selected, prioritized for self-forming behavior. And the self-forming material was finally selected through thin film and device analysis. We confirmed that Cr, Zn, and Mn out-diffused to the surface of the thin film structure using X-ray photoelectron spectroscopy (XPS) depth profile and investigated the chemical state of out-diffused dopants through the analysis of a binding energy. Cr shows the most ideal self-forming behavior with the SiO2 dielectric and reacted with oxygen to form a Cr2O3 barrier. In metal-insulator-semiconductor (MIS) structure, out-diffused Cr reacts with SiO2 at the interface and forms a self-formed single layer. It was confirmed that the thickness of the diffusion barrier layer is about 1.2 nm, which is an ultra-thin layer capable of minimizing the total effective resistance. Through voltage-ramping dielectric breakdown (VRDB) tests, Co-Cr alloy showed highest breakdown voltage (VBD) up to 200 % than pure Co. The effect of Cr doping concentration and heat treatment condition applicable to the interconnect process was confirmed. When Cr was doped less than 1 at%, the robust electrical reliability was exhibited. Also, it was found that a Cr2O3 interfacial layer was formed when annealing process was performed at 250 ยฐC or higher for 30 minutes or longer. In other words, Co-Cr alloy is well suited for the interconnect process because current interconnect process temperature is below 400 ยฐC. And when the film thickness was lowered from 150 nm to 20 nm, excellent VBD values were confirmed even at high Cr doping concentration (~7.5 at%). It seems that the amount of Cr present at the Co/SiO2 interface plays a very important role in improving the Cr oxide SFB quality. Physical modeling is necessary to understand the amount of Cr at the interface according to the interconnect volumes and the reliability of the Cr oxide self-forming barrier. TDDB lifetime test also performed and Co-Cr alloy interconnect shows a highly reliable diffusion barrier property of self-formed interfacial layer. The DFT analysis also confirmed that Cr2O3 is a very promising barrier material because it showed a higher energy barrier value than the TiN diffusion barrier currently being studied. A Co-based self-forming barrier was designed through thermodynamic calculations that take performance and reliability into account in interconnect material system. A Co interconnect system with an ultra-thin Cr2O3 diffusion barrier with excellent reliability is proposed. Through this design, it is expected that high-performance interconnects based on robust reliability in the advanced interconnect can be implemented in the near future.์ตœ๊ทผ ๋ฐ˜๋„์ฒด ์†Œ์ž ์Šค์ผ€์ผ๋ง์— ๋”ฐ๋ฅธ ๋ฐฐ์„  ์„ ํญ ๊ฐ์†Œ๋กœ M0, M1์˜์—ญ์—์„œ์˜ metal ๋น„์ €ํ•ญ์ด ๊ธ‰๊ฒฉํžˆ ์ฆ๊ฐ€ํ•˜์—ฌ ๋ฐฐ์„ ์—์„œ์˜ RC delay๊ฐ€ ๋‹ค์‹œ ํ•œ๋ฒˆ ํฌ๊ฒŒ ๋ฌธ์ œ๊ฐ€ ๋˜๊ณ  ์žˆ๋‹ค. ์ด๋ฅผ ํ•ด๊ฒฐํ•˜๊ธฐ ์œ„ํ•ด์„œ ์ฐจ์„ธ๋Œ€ ๋ฐฐ์„  ์‹œ์Šคํ…œ์—์„œ๋Š” ๋‚ฎ์€ ๋น„์ €ํ•ญ๊ณผ electron mean free path (EMFP)์„ ๊ฐ€์ง€๋Š” ๋ฌผ์งˆ ์—ฐ๊ตฌ๊ฐ€ ์ง„ํ–‰๋˜์—ˆ๋‹ค. ๋Œ€ํ‘œ์ ์œผ๋กœ Co, Ru, Mo์™€ ๊ฐ™์€ ๊ธˆ์†๋“ค์ด ์ฐจ์„ธ๋Œ€ ๋ฐฐ์„  ์žฌ๋ฃŒ ํ›„๋ณด๋กœ ์–ธ๊ธ‰๋˜๊ณ  ์žˆ์œผ๋ฉฐ ๋‚ฎ์€ ฯ0 ร— ฮป ๊ฐ’์„ ๊ฐ–๊ธฐ ๋•Œ๋ฌธ์— interface (surface) scattering๊ณผ grain boundary scattering ์˜ํ–ฅ์„ ์ตœ์†Œํ™”ํ•  ์ˆ˜ ์žˆ์„ ๊ฒƒ์œผ๋กœ ๋ณด๊ณ  ์žˆ๋‹ค. ํ•˜์ง€๋งŒ ๊ฐ€ํ˜นํ•œ electrical field์™€ ๋†’์€ Joule heating์ด ๋ฐœ์ƒํ•˜๋Š” ๋™์ž‘ ํ™˜๊ฒฝ์œผ๋กœ ์ธํ•ด performance๋ฟ๋งŒ ์•„๋‹ˆ๋ผ ์†Œ์ž ์‹ ๋ขฐ์„ฑ์ด ๋” ์—ด์•…ํ•œ ์ƒํ™ฉ์— ๋†“์—ฌ์žˆ๋‹ค. ์˜ˆ๋ฅผ ๋“ค์–ด ์ฐจ์„ธ๋Œ€ ๊ธˆ์†์— ๋Œ€ํ•œ time dependent dielectric breakdown (TDDB) ์‹ ๋ขฐ์„ฑ ๋ฌธ์ œ๊ฐ€ ๋ณด๊ณ ๋˜๊ณ  ์žˆ๊ธฐ ๋•Œ๋ฌธ์— ์ด๋ฅผ ๋ณด์•ˆํ•  ํ™•์‚ฐ๋ฐฉ์ง€๋ง‰ ๋ฌผ์งˆ ๋ฐ ๊ณต์ •์—ฐ๊ตฌ๊ฐ€ ํ•„์š”ํ•˜๋‹ค. ํŠนํžˆ ๋†’์€ ์ „๊ธฐ์žฅ์—์„œ Co ion์ด ์œ ์ „์ฒด๋กœ ์นจํˆฌํ•˜์—ฌ extrinsic dielectric breakdown ์‹ ๋ขฐ์„ฑ ๋ฌธ์ œ๊ฐ€ ์ตœ๊ทผ ๋ณด๊ณ ๋˜๊ณ  ์žˆ๋‹ค. ๋”ฐ๋ผ์„œ ๊ธˆ์† ์ด์˜จ์ด ์œ ์ „์ฒด ๋‚ด๋ถ€๋กœ ์นจํˆฌํ•˜๋Š” ๊ฒƒ์„ ๋ฐฉ์ง€ํ•˜์—ฌ, Co ๋ฐฐ์„ ์˜ ์‹ ๋ขฐ์„ฑ์„ ํ–ฅ์ƒ์‹œํ‚ฌ ์ˆ˜ ๊ฒฌ๊ณ ํ•œ ํ™•์‚ฐ๋ฐฉ์ง€๋ง‰ ๊ฐœ๋ฐœ ๋ฐ ์ƒˆ๋กœ์šด ๋ฐฐ์„  ์‹œ์Šคํ…œ ์„ค๊ณ„๊ฐ€ ํ•„์š”ํ•œ ์‹œ์ ์ด๋‹ค. ๋˜ํ•œ, ๋ฐฐ์„  ์ €ํ•ญ์„ ๋‚ฎ์ถ”๊ธฐ ์œ„ํ•ด์„œ๋Š” ๋งค์šฐ ์–‡์€ ํ™•์‚ฐ๋ฐฉ์ง€๋ง‰ ๊ฐœ๋ฐœ์ด ํ•„์š”ํ•˜๋‹ค. ์‹ ๋ขฐ์„ฑ์ด ์ข‹์€ ํ™•์‚ฐ๋ฐฉ์ง€๋ง‰์ด๋ผ๋„ ๋ฐฐ์„ ์—์„œ ๋งŽ์€ ์˜์—ญ์„ ์ฐจ์ง€ํ•  ๊ฒฝ์šฐ ์ „์ฒด ์„ฑ๋Šฅ์ด ์ €ํ•˜๋˜๊ธฐ ๋•Œ๋ฌธ์ด๋‹ค. Cu ํ™•์‚ฐ๋ฐฉ์ง€๋ง‰์œผ๋กœ ์‚ฌ์šฉ๋˜๊ณ  ์žˆ๋Š” TaN ์ธต์€ 2.5 nm ๋ณด๋‹ค ์–‡์„ ๊ฒฝ์šฐ ์‹ ๋ขฐ์„ฑ์ด ๊ธ‰๊ฒฉํžˆ ๋‚˜๋น ์ง€๋ฏ€๋กœ 2.5 nm๋ณด๋‹ค ์–‡์€ ๋‘๊ป˜์˜ ๊ฒฌ๊ณ ํ•œ ํ™•์‚ฐ๋ฐฉ์ง€๋ง‰ ๊ฐœ๋ฐœ์ด ํ•„์š”ํ•˜๋‹ค. ๋ณธ ์—ฐ๊ตฌ๋Š” ์ฐจ์„ธ๋Œ€ ๋ฐ˜๋„์ฒด ๋ฐฐ์„  ๋ฌผ์งˆ๋กœ ์ฃผ๋ชฉ๋ฐ›๊ณ  ์žˆ๋Š” Co ๊ธˆ์†์— ๋Œ€ํ•˜์—ฌ ์ €์ €ํ•ญยท๊ณ ์‹ ๋ขฐ์„ฑ์„ ํ™•๋ณดํ•  ์ˆ˜ ์žˆ๋Š” Co alloy ์ž๊ฐ€ํ˜•์„ฑ ํ™•์‚ฐ๋ฐฉ์ง€๋ง‰ (Co alloy self-forming barrier, SFB) ์†Œ์žฌ ๋””์ž์ธํ•˜์˜€๋‹ค. ์ž๊ฐ€ํ˜•์„ฑ ํ™•์‚ฐ๋ฐฉ์ง€๋ง‰ ๋ฐฉ๋ฒ•๋ก ์€ ์—ด์ฒ˜๋ฆฌ ๊ณผ์ •์—์„œ ๊ธˆ์†๊ณผ ์œ ์ „์ฒด ๊ณ„๋ฉด์—์„œ ๋„ํŽ€ํŠธ๊ฐ€ ํ™•์‚ฐํ•˜๊ฒŒ ๋œ๋‹ค. ๊ทธ๋ฆฌ๊ณ  ํ™•์‚ฐ๋˜๋‹ˆ ๋„ํŽ€ํŠธ๋Š” ์–‡์€ ํ™•์‚ฐ๋ฐฉ์ง€๋ง‰์„ ํ˜•์„ฑํ•˜๋Š” ๋ฐฉ๋ฒ•๋ก ์ด๋‹ค. ์ด ๋ฐฉ๋ฒ•๋ก ์„ ํ†ตํ•ด ๊ธˆ์† ์ด์˜จ์˜ ์ด๋™์„ ๋ฐฉ์ง€ํ•˜์—ฌ Co ๋ฐฐ์„  ์‹ ๋ขฐ์„ฑ์„ ํ–ฅ์ƒ์‹œํ‚ฌ ์ˆ˜ ์žˆ์„ ๊ฒƒ์œผ๋กœ ์˜ˆ์ƒํ•˜์˜€๋‹ค. ์šฐ์„ , Co ํ•ฉ๊ธˆ์ƒ์—์„œ ์ ์ ˆํ•œ ๋„ํŽ€ํŠธ๋ฅผ ์ฐพ๊ธฐ ์œ„ํ•ด์„œ CMOS ๊ณต์ •์— ์ ์šฉ ๊ฐ€๋Šฅํ•œ ๊ธˆ์†๋“ค์„ ์„ ๋ณ„ํ•˜์˜€๋‹ค. ๋„ํŽ€ํŠธ ์ €ํ•ญ, ๊ธˆ์†๊ฐ„ ํ™”ํ•ฉ๋ฌผ ํ˜•์„ฑ ์—ฌ๋ถ€, Co๋‚ด ๊ณ ์šฉ๋„, Co alloy์—์„œ์˜ ํ™œ์„ฑ๊ณ„์ˆ˜, ์‚ฐํ™”๋„, Co/SiO2 ๊ณ„๋ฉด์—์„œ์˜ ์•ˆ์ •์ƒ์„ ์—ด์—ญํ•™์  ๊ณ„์‚ฐ์„ ํ†ตํ•ด์„œ ๋ฌผ์งˆ ์„ ์ • ๊ธฐ์ค€์œผ๋กœ ์„ธ์› ๋‹ค. ์—ด์—ญํ•™์  ๊ณ„์‚ฐ์„ ๊ธฐ๋ฐ˜์œผ๋กœ 9๊ฐœ์˜ ๋„ํŽ€ํŠธ ๊ธˆ์†์ด ์„ ํƒ๋˜์—ˆ์œผ๋ฉฐ, Co ํ•ฉ๊ธˆ ์ž๊ฐ€ํ˜•์„ฑ ํ™•์‚ฐ๋ฐฉ์ง€๋ง‰ ๊ธฐ์ค€์— ๋”ฐ๋ผ์„œ ์šฐ์„  ์ˆœ์œ„๋ฅผ ์ง€์ •ํ•˜์˜€๋‹ค. ๊ทธ๋ฆฌ๊ณ  ์ตœ์ข…์ ์œผ๋กœ ๋ฐ•๋ง‰๊ณผ ์†Œ์ž ์‹ ๋ขฐ์„ฑ ํ‰๊ฐ€๋ฅผ ํ†ตํ•ด์„œ ๊ฐ€์žฅ ์ ํ•ฉํ•œ ์ž๊ฐ€ํ˜•์„ฑ ํ™•์‚ฐ๋ฐฉ์ง€๋ง‰ ๋ฌผ์งˆ์„ ์„ ์ •ํ•˜์˜€๋‹ค. X-ray photoelectron spectroscopy (XPS) ๋ถ„์„์„ ์ด์šฉํ•˜์—ฌ Cr, Zn, Mn์ด ๋ฐ•๋ง‰ ๊ตฌ์กฐ์˜ ํ‘œ๋ฉด์œผ๋กœ ์™ธ๋ถ€ ํ™•์‚ฐ ์—ฌ๋ถ€๋ฅผ ํ™•์ธํ•˜๊ณ  ๊ฒฐํ•ฉ ์—๋„ˆ์ง€ ๋ถ„์„์„ ํ†ตํ•ด ์™ธ๋ถ€๋กœ ํ™•์‚ฐ๋œ ๋„ํŽ€ํŠธ์˜ ํ™”ํ•™์  ์ƒํƒœ๋ฅผ ์กฐ์‚ฌํ•˜์˜€๋‹ค. ๋ถ„์„ ๊ฒฐ๊ณผ Cr, Zn, Mn์ด ์œ ์ „์ฒด ๊ณ„๋ฉด์œผ๋กœ ํ™•์‚ฐ๋˜์–ด ์‚ฐ์†Œ์™€ ๋ฐ˜์‘ํ•˜์—ฌoxide/silicate ํ™•์‚ฐ ๋ฐฉ์ง€๋ง‰ (e.g. Cr2O3, Zn2SiO4, MnSiO3)์„ ํ˜•์„ฑํ•œ ๊ฒƒ์„ ํ™•์ธํ•˜์˜€๋‹ค. ๊ทธ ์ค‘ Cr์€ SiO2 ์œ ์ „์ฒด์™€ ํ•จ๊ป˜ ๊ฐ€์žฅ ์ด์ƒ์ ์ธ ์ž๊ธฐ ํ˜•์„ฑ ๊ฑฐ๋™์„ ๋‚˜ํƒ€๋‚ด๋ฉฐ ์‚ฐ์†Œ์™€ ๋ฐ˜์‘ํ•˜์—ฌ Cr2O3 ์ธต์„ ํ˜•์„ฑํ•˜๋Š” ๊ฒƒ์„ ํ™•์ธํ•˜์˜€๋‹ค. MIS (Metal-Insulator-Semiconductor) ๊ตฌ์กฐ์—์„œ๋„ ์™ธ๋ถ€๋กœ ํ™•์‚ฐ๋œ Cr์€ ๊ณ„๋ฉด์—์„œ SiO2์™€ ๋ฐ˜์‘ํ•˜์—ฌ Cr2O3 ์ž๊ฐ€ํ˜•์„ฑ ํ™•์‚ฐ๋ฐฉ์ง€๋ง‰์ด ํ˜•์„ฑ๋˜์—ˆ๋‹ค. ํ™•์‚ฐ๋ฐฉ์ง€์ธต์˜ ๋‘๊ป˜๋Š” ์•ฝ 1.2nm๋กœ ์ „์ฒด ์œ ํšจ์ €ํ•ญ์„ ์ตœ์†Œํ™”ํ•  ์ˆ˜ ์žˆ๋Š” ์ถฉ๋ถ„ํžˆ ์–‡์€ ๋‘๊ป˜๋ฅผ ํ™•๋ณดํ•˜์˜€๋‹ค. VRDB (Voltage-Ramping Dielectric Breakdown) ํ…Œ์ŠคํŠธ๋ฅผ ํ†ตํ•ด Co-Cr ํ•ฉ๊ธˆ์€ ์ˆœ์ˆ˜ Co๋ณด๋‹ค ์ตœ๋Œ€ 200% ๋†’์€ ํ•ญ๋ณต ์ „์•• (breakdown voltage)์„ ๋ณด์˜€๋‹ค. ๋ฐ˜๋„์ฒด ๋ฐฐ์„  ๊ณต์ •์— ์ ์šฉํ•  ์ˆ˜ ์žˆ๋Š” Cr ๋„ํ•‘ ๋†๋„์™€ ์—ด์ฒ˜๋ฆฌ ์กฐ๊ฑด์˜ ์˜ํ–ฅ์„ ํ™•์ธํ•˜์˜€๋‹ค. Cr์ด 1at% ๋ฏธ๋งŒ์œผ๋กœ ๋„ํ•‘๋˜์—ˆ์„ ๋•Œ ์šฐ์ˆ˜ํ•œ ์ „๊ธฐ์  ์‹ ๋ขฐ์„ฑ์„ ๋‚˜ํƒ€๋‚ด์—ˆ๋‹ค. ๋˜ํ•œ, 250โ„ƒ ์ด์ƒ์—์„œ 30๋ถ„ ์ด์ƒ ์—ด์ฒ˜๋ฆฌ๋ฅผ ํ•˜์˜€์„ ๋•Œ Cr2O3 ๊ณ„๋ฉด์ธต์ด ํ˜•์„ฑ๋จ์„ ์•Œ ์ˆ˜ ์žˆ์—ˆ๋‹ค. ์ฆ‰, ํ˜„์žฌ ๋ฐฐ์„  ๊ณต์ • ์˜จ๋„๊ฐ€ 400ยฐC ๋ฏธ๋งŒ์ด๊ธฐ ๋•Œ๋ฌธ์— Co-Cr ํ•ฉ๊ธˆ์ด ๋ฐฐ์„  ๊ณต์ •์— ์ ์šฉ ๊ฐ€๋Šฅํ•จ์„ ํ™•์ธํ•˜์˜€๋‹ค. TDDB ์ˆ˜๋ช… ํ…Œ์ŠคํŠธ๋„ ์ˆ˜ํ–‰๋˜์—ˆ์œผ๋ฉฐ Co-Cr ํ•ฉ๊ธˆ ๋ฐฐ์„ ์€ ์ž์ฒด ํ˜•์„ฑ๋œ ๊ณ„๋ฉด์ธต์˜ ๋งค์šฐ ์•ˆ์ •์ ์ธ ํ™•์‚ฐ ์žฅ๋ฒฝ ํŠน์„ฑ์„ ๋ณด์—ฌ์ฃผ์—ˆ๋‹ค. DFT ๋ถ„์„์€ Cr2O3์ž๊ฐ€ํ˜•์„ฑ ํ™•์‚ฐ๋ฐฉ์ง€๋ง‰์ด ํ˜„์žฌ ์—ฐ๊ตฌ๋˜๊ณ  ์žˆ๋Š” TiN ํ™•์‚ฐ ์žฅ๋ฒฝ๋ณด๋‹ค ๋” ๋†’์€ ์—๋„ˆ์ง€ ์žฅ๋ฒฝ ๊ฐ’์„ ๋ณด์—ฌ์ฃผ๊ธฐ ๋•Œ๋ฌธ์— ๋งค์šฐ ์œ ๋งํ•œ ํ™•์‚ฐ๋ฐฉ์ง€๋ง‰์ž„์„ ๋ณด์—ฌ์ฃผ์—ˆ๋‹ค. ๋ณธ ์—ฐ๊ตฌ๋Š” ๋ฐ˜๋„์ฑ„ ๋ฐฐ์„  ๋ฌผ์งˆ ์‹œ์Šคํ…œ์—์„œ ์„ฑ๋Šฅ๊ณผ ์‹ ๋ขฐ์„ฑ์„ ๊ณ ๋ คํ•œ ์—ด์—ญํ•™์  ๊ณ„์‚ฐ์„ ํ†ตํ•ด Co ๊ธฐ๋ฐ˜ ์ž๊ฐ€ํ˜•์„ฑ ํ™•์‚ฐ๋ฐฉ์ง€๋ง‰์„ ์„ค๊ณ„ํ•˜์˜€๋‹ค. ์‹คํ—˜ ๊ฒฐ๊ณผ ์‹ ๋ขฐ์„ฑ์ด ์šฐ์ˆ˜ํ•˜๊ณ  ์•„์ฃผ ์–‡์€ Cr2O3 ํ™•์‚ฐ๋ฐฉ์ง€๋ง‰์ด ์žˆ๋Š” Co-Cr ํ•ฉ๊ธˆ์ด ์ œ์•ˆํ•˜์˜€๋‹ค. ๋ฌผ์งˆ ์„ค๊ณ„์™€ ์ „๊ธฐ์  ์‹ ๋ขฐ์„ฑ ๊ฒ€์ฆ์„ Co/Cr2O3/SiO2 ๋ฌผ์งˆ ์‹œ์Šคํ…œ์„ ์ œ์•ˆํ•˜์˜€๊ณ  ์•ž์œผ๋กœ์˜ ๋‹ค๊ฐ€์˜ฌ ์ฐจ์„ธ๋Œ€ ๋ฐฐ์„ ์—์„œ ๊ตฌํ˜„๋  ์ˆ˜ ์žˆ์„ ๊ฒƒ์œผ๋กœ ๊ธฐ๋Œ€๋œ๋‹ค.Abstract i Table of Contents v List of Tables ix List of Figures xii Chapter 1. Introduction 1 1.1. Scaling down of VLSI systems 1 1.2. Driving force of interconnect system evolution 7 1.3. Driving force of beyond Cu interconnects 11 1.4. Objective of the thesis 18 1.5. Organization of the thesis 21 Chapter 2. Theoretical Background 22 2.1. Evolution of interconnect systems 22 2.1.1. Cu/barrier/low-k interconnect system 22 2.1.2. Process developments for interconnect reliability 27 2.1.3. 3rd generation of interconnect system 31 2.2 Thermodynamic tools for Co self-forming barrier 42 2.2.1 Binary phase diagram 42 2.2.2 Ellingham diagram 42 2.2.3 Activity coefficient 43 2.3. Reliability of Interconnects 45 2.3.1. Current conduction mechanisms in dielectrics 45 2.3.2. Reliability test vehicles 50 2.3.3. Dielectric breakdown assessment 52 2.3.4. Dielectric breakdown mechanisms 55 2.3.5. Reliability test: VRDB and TDDB 56 2.3.6. Lifetime models 57 Chapter 3. Experimental Procedures 60 3.1. Thin film deposition 60 3.1.1. Substrate preparation 60 3.1.2. Oxidation 61 3.1.3. Co alloy deposition using DC magnetron sputtering 61 3.1.4. Annealing process 65 3.2. Thin film characterization 67 3.2.1. Sheet resistance 67 3.2.2. X-ray photoelectron spectroscopy (XPS) 68 3.3. Metal-Insulator-Semiconductor (MIS) device fabrication 70 3.3.1. Patterning using lift-off process 70 3.3.2. TDDB packaging 72 3.4. Reliability analysis 74 3.4.1. Electrical reliability analysis 74 3.4.2. Transmission electron microscopy (TEM) analysis 75 3.5. Computation 76 3.5.1 FactsageTM calculation 76 3.5.2. Density Functional Theory (DFT) calculation 77 Chapter 4. Co Alloy Design for Advanced Interconnects 78 4.1. Material design of Co alloy self-forming barrier 78 4.1.1. Rule of thumb of Co-X alloy 78 4.1.2. Co alloy phase 80 4.1.3. Out-diffusion stage 81 4.1.4. Reaction step with SiO2 dielectric 89 4.1.5. Comparison criteria 94 4.2. Comparison of Co alloy candidates 97 4.2.1. Thin film resistivity evaluation 97 4.2.2. Self-forming behavior using XPS depth profile analysis 102 4.2.3. MIS device reliability test 110 4.3 Summary 115 Chapter 5. Co-Cr Alloy Interconnect with Robust Self-Forming Barrier 117 5.1. Compatibility of Co-Cr alloy SFB process 117 5.1.1. Effect of Cr doping concentration 117 5.1.2. Annealing process condition optimization 119 5.2. Reliability of Co-Cr interconnects 122 5.2.1. VRDB quality test with Co-Cr alloys 122 5.2.2. Lifetime evaluation using TDDB method 141 5.2.3. Barrier mechanism using DFT 142 5.3. Summary 145 Chapter 6. Conclusion 148 6.1. Summary of results 148 6.2. Research perspectives 150 References 151 Abstract (In Korean) 166 Curriculum Vitae 169๋ฐ•

    TiN/HfO2/SiO2/Si gate stacks reliability : Contribution of HfO2 and interfacial SiO2 layer

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    Hafnium Oxide based gate stacks are considered to be the potential candidates to replace SiO2 in complementary metal-oxide-semiconductor (CMOS), as they reduce the gate leakage by over 100 times while keeping the device performance intact. Even though considerable performance improvement has been achieved, reliability of high-ฮบ devices for the next generation of transistors (45nm and beyond) which has an interfacial layer (IL: typically SiO2) between high-ฮบ and the substrate, needs to be investigated. To understand the breakdown mechanism of high-ฮบ/SiO2 gate stack completely, it is important to study this multi-layer structure extensively. For example, (i) the role of SiO2 interfacial layers and bulk high-ฮบ gate dielectrics without any interfacial layer can be investigated separately while maintaining same growth conditions; (ii) the evolution of breakdown process can be studied through stress induced leakage current (SILC); (iii) relationship of various degradation mechanisms such as negative bias temperature instability (NBTI) with that of the dielectric breakdown; and (iv) a fast evaluation process to estimate statistical breakdown distribution. In this dissertation a comparative study was conducted to investigate individual breakdown characteristics of high-ฮบ/IL (ISSG SiO2)/metal gate stacks, in-situ steam generated (ISSG)-SiO2 MOS structures and HfO2-only metal-insulator-metal (MIM) capacitors. Experimental results indicate that after constant voltage stress (CVS) identical degradation for progressive breakdown and SILC were observed in high-ฮบ/IL and SiO2-only MOS devices, but HfO2-only MIM capacitors showed insignificant SILC and progressive breakdown until it went into hard breakdown. Based on the observed SILC behavior and charge-to-breakdown (QBD), it was inferred that interfacial layer initiates progressive breakdown of metal gate/high-ฮบ gate stacks at room temperature. From normalized SILC (ฮ”Jg/Jg0) at accelerated temperature and activation energy of the timeto- breakdown (TBD), it was observed that IL initiates the gate stack breakdown at higher temperatures as well. A quantitative agreement was observed for key parameters of NBTI and time dependent dielectric breakdown (TDDB) such as the activation energies of threshold voltage change and SILC. The quality and thickness variation of the IL causes similar degradation on both NBTI and TDDB indicating that mechanism of these two reliability issues are related due to creation of identical defect types in the IL. CVS was used to investigate the statistical distribution of TBD, defined as soft or first breakdown where small sample size was considered. As TBD followed Weibull distribution, large sample size was not required. Since the failure process in static random access memory (SRAM) is typically predicted by the realistic TDDB model based on gate leakage current (IFAIL) rather than the conventional first breakdown criterion, the relevant failure distributions at IFAIL are non-Weibull including the progressive breakdown (PBD) phase for high-ฮบ/metal gate dielectrics. A new methodology using hybrid two-stage stresses has been developed to study progressive breakdown phase further for high-ฮบ and SiO2. It is demonstrated that VRS can be used effectively for quantitative reliability studies of progressive breakdown phase and final breakdown of high-ฮบ and other dielectric materials; thus it can replace the time-consuming CVS measurements as an efficient methodology and reduce the resources manufacturing cost

    Electrical properties of ultra thin Al2O3 and HfO2 films as gate dielectrics in MOS technology

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    The rapidly evolving silicon industry demands devices with high-speed and low power consumption. This has led to aggressive scaling of the dimensions in metal oxide semiconductor field effect transistors (MOSFETs). The channel length has been reduced as a result of this scaling. The industry favorite, SlO2, has reached limitations in the thickness regime of 1-1.5 nm as a gate dielectric. High-ฮบ gate dielectrics such as Al203 and HfO2 and their silicates are some of the materials that may, probably, replace SlO2, as gate dielectric in the next four to five years. The present study is an attempt to understand the electrical characteristics of these exciting materials grown by atomic layer deposition (ALD) technique. The flat band voltages (VFB) were determined from C-V measurements on circularly patterned MOS capacitors. For phosphorous doped polysilicon electrodes and Al-oxide based dielectrics, positive shifts in VFB were observed, relative to a pure SlO2 control, ranging from 0.2 to 0.8V. It is believed that this is caused by fixed charges. Rapid thermal annealing at 1000ยฐC tends to decrease VFB relative to a 800ยฐC anneal. Changes in VFB UP to 0.35 V are observed for films deposited over SlO2 underlayers, while smaller changes, up to 0.05 V, are observed for films deposited directly on Si. Spike annealing is also observed to reduce oxide leakage. HfO2 showed large amount of leakage resulting in difficulty in performing capacitance measurements. ZrO2 was found to be reacting with polycrystalline silicon and thus high leakage current was observed

    NEGATIVE BIAS TEMPERATURE INSTABILITY STUDIES FOR ANALOG SOC CIRCUITS

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    Negative Bias Temperature Instability (NBTI) is one of the recent reliability issues in sub threshold CMOS circuits. NBTI effect on analog circuits, which require matched device pairs and mismatches, will cause circuit failure. This work is to assess the NBTI effect considering the voltage and the temperature variations. It also provides a working knowledge of NBTI awareness to the circuit design community for reliable design of the SOC analog circuit. There have been numerous studies to date on the NBTI effect to analog circuits. However, other researchers did not study the implication of NBTI stress on analog circuits utilizing bandgap reference circuit. The reliability performance of all matched pair circuits, particularly the bandgap reference, is at the mercy of aging differential. Reliability simulation is mandatory to obtain realistic risk evaluation for circuit design reliability qualification. It is applicable to all circuit aging problems covering both analog and digital. Failure rate varies as a function of voltage and temperature. It is shown that PMOS is the reliabilitysusceptible device and NBTI is the most vital failure mechanism for analog circuit in sub-micrometer CMOS technology. This study provides a complete reliability simulation analysis of the on-die Thermal Sensor and the Digital Analog Converter (DAC) circuits and analyzes the effect of NBTI using reliability simulation tool. In order to check out the robustness of the NBTI-induced SOC circuit design, a bum-in experiment was conducted on the DAC circuits. The NBTI degradation observed in the reliability simulation analysis has given a clue that under a severe stress condition, a massive voltage threshold mismatch of beyond the 2mV limit was recorded. Bum-in experimental result on DAC proves the reliability sensitivity of NBTI to the DAC circuitry

    Process development and reliability of thin gate oxides

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    The Semiconductor Industry Association\u27s (SIA) current National Technological Roadmap calls for the development of a suitable dielectric material for use in gate oxide for the 0.18|micrometers generation of chips and beyond. Some of the key challenges identified are resistance to oxide trapped charge generation from higher levels of tunneling currents and/or plasma processing, and formation of an effective barrier to dopant penetration during the gate processing. One promising material to meet these challenges is nitrided thermal oxide. Development of a growth process that yields high quality, lOnm thick, thermally grown Si02 films at RJT for use as a gate dielectric is described. Thin oxides (8nm - 20nm) were grown by thermal oxidation followed by inert anneals in Ar and N2. Nitrided oxides were created by implanting N2 (dose range: 5el3 - lei 5 /cm2) into the substrate prior to gate oxidation. Test equipment was setup to study Fowler Nordheim (FN) tunneling and dielectric breakdown. Test structures consisted of conventional and novel MOS capacitor structures with aluminum and poly-silicon gate electrodes. Scaling RJT\u27s existing, 20nm oxidation process to lOnm resulted in degradation of dielectric strength from \u3e lOMV/cm to ~6-7MV/cm for Al-gate MOS capacitors. Replacing the Al gate material with poly-silicon restored the dielectric strength to lOMV/cm. Performing an N2 implant through a screening oxide, prior to gate oxidation, was investigated as a means of obtaining a nitrided thermal oxide. For certain doses (5el3 - 5el4 /cm2), Al-gate MOS capacitors exhibited an improved dielectric strength as the mean value increased from 6- 7MV/cm to ~9MV/cm. Poly-Si gate MOS capacitors showed a similar improvement for the nitrided oxides, exhibiting mean dielectric strength values in the 10-12MV/cm range. Fowler- Nordheim (FN) tunnel current measurements showed that the nitrided films exhibit lower leakage levels and less charge trapping than their thermal Si02 counterparts. Results indicate that a 12nm nitrided oxide, for a certain dose (5el4/cm2), exhibited equivalent electrical performance to a 20nm thermally grown Si02 oxide. In conclusion, a process was developed for yielding reliable thin gate oxides (~10nm) in a university fab

    A Study of Nanometer Semiconductor Scaling Effects on Microelectronics Reliability

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    The desire to assess the reliability of emerging scaled microelectronics technologies through faster reliability trials and more accurate acceleration models is the precursor for further research and experimentation in this relevant field. The effect of semiconductor scaling on microelectronics product reliability is an important aspect to the high reliability application user. From the perspective of a customer or user, who in many cases must deal with very limited, if any, manufacturer's reliability data to assess the product for a highly-reliable application, product-level testing is critical in the characterization and reliability assessment of advanced nanometer semiconductor scaling effects on microelectronics reliability. This dissertation provides a methodology on how to accomplish this and provides techniques for deriving the expected product-level reliability on commercial memory products. Competing mechanism theory and the multiple failure mechanism model are applied to two separate experiments; scaled SRAM and SDRAM products. Accelerated stress testing at multiple conditions is applied at the product level of several scaled memory products to assess the performance degradation and product reliability. Acceleration models are derived for each case. For several scaled SDRAM products, retention time degradation is studied and two distinct soft error populations are observed with each technology generation: early breakdown, characterized by randomly distributed weak bits with Weibull slope Beta=1, and a main population breakdown with an increasing failure rate. Retention time soft error rates are calculated and a multiple failure mechanism acceleration model with parameters is derived for each technology. Defect densities are calculated and reflect a decreasing trend in the percentage of random defective bits for each successive product generation. A normalized soft error failure rate of the memory data retention time in FIT/Gb and FIT/cm2 for several scaled SDRAM generations is presented revealing a power relationship. General models describing the soft error rates across scaled product generations are presented. The analysis methodology may be applied to other scaled microelectronic products and key parameters

    Development of reliability testing automation for microwave radios

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    Diplomityรถssรคni tutkin, miten mikroaaltoradion ulkoyksikรถn luotettavuustestaus tehostuu automatisoinnin avulla. Olemassa olevaan automaatioon on tarkoitus liittรครค kaksi uutta mittausta, jolloin niitรค ei tarvitse erikseen tehdรค kรคsin. Tarkoituksena on nopeuttaa testausta ja vรคhentรครค siinรค tarvittavia resursseja. Radiolinkeissรค kรคytettรคvรคt mikroaaltoradiot on jaettu kahteen osaan, joista toista kutsutaan sisรคyksikรถksi ja toista ulkoyksikรถksi. Ulkoyksikรถn tรคytyy kestรครค vaihtelevia ulko-olosuhteita. Mikroaaltoradion ulkoyksikรถn suorituskykyรค voidaan tutkia erilaisilla mittauksilla. Nรคiden mittausten tarkoituksena on tarkastella laitteen suorituskykyyn vaikuttavia osatekijรถitรค erikseen, mikรค auttaa suorituskyvyssรค havaittujen ongelmien syiden paikallistamisessa rautatasolla. Mittaukset ovat luonteeltaan toistuvia ja varsin tyรถlรคitรค, jos ne tehdรครคn kรคsin. Uusien mittausten liittรคminen automaation lyhentรครค mikroaaltoradion testaukseen kuluvaa kokonaisaikaa ja vรคhentรครค tyรถn mรครคrรครค. Lisรคksi automatisoitujen mittausten etuja ovat mittausten hyvรค toistettavuus ja inhimillisten virheiden vรคhรคisyys.In my master's thesis I have studied how automation makes reliability testing of a microwave radio outdoor unit more efficient. Two new test cases, that are donemanually so far, will be added to an existing automation software. The goal is to speed up reliability testing and decrease resources needed for it. Microwave radios used in radio links are divided into two physical parts. One of them is indoor unit and the other is outdoor unit. The latter has to endure in outdoor conditions. Performance of the microwave radio outdoor unit can be investigated with several test cases. The scope of these test cases is to get detailed information about the radio. This helps locating malfunctioning unit or component in the hard ware. On one test run these test cases are repeated several times with different outdoor unit transmission settings and quite a lot of manual work is needed. Including new test cases in the existing automation software reduces time spent on testing and the amount of work needed for it. Also, benefits of automation are good reproducibility of measurements and the lack of human errors
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