7,361 research outputs found
Finding NHIM in 2 and 3 degrees-of-freedom with H\'enon-Heiles type potential
We present the capability of Lagrangian descriptors for revealing the high
dimensional phase space structures that are of interest in nonlinear
Hamiltonian systems with index-1 saddle. These phase space structures include
normally hyperbolic invariant manifolds and their stable and unstable
manifolds, and act as codimenision-1 barriers to phase space transport. The
method is applied to classical two and three degrees-of-freedom Hamiltonian
systems which have implications for myriad applications in physics and
chemistry.Comment: 15 pages, 6 figures. This manuscript is better served as dessert to
the main course: arXiv:1903.1026
Wigner's Dynamical Transition State Theory in Phase Space: Classical and Quantum
A quantum version of transition state theory based on a quantum normal form
(QNF) expansion about a saddle-centre-...-centre equilibrium point is
presented. A general algorithm is provided which allows one to explictly
compute QNF to any desired order. This leads to an efficient procedure to
compute quantum reaction rates and the associated Gamov-Siegert resonances. In
the classical limit the QNF reduces to the classical normal form which leads to
the recently developed phase space realisation of Wigner's transition state
theory. It is shown that the phase space structures that govern the classical
reaction d ynamicsform a skeleton for the quantum scattering and resonance
wavefunctions which can also be computed from the QNF. Several examples are
worked out explicitly to illustrate the efficiency of the procedure presented.Comment: 132 pages, 31 figures, corrected version, Nonlinearity, 21 (2008)
R1-R11
Green's functions for multiply connected domains via conformal mapping
A method is described for the computation of the Green's function in the complex plane corresponding to a set of K symmetrically placed polygons along the real axis. An important special case is a set of K real intervals. The method is based on a Schwarz-Christoffel conformal map of the part of the upper half-plane exterior to the problem domain onto a semi-infinite strip whose end contains K-1 slits. From the Green's function one can obtain a great deal of information about polynomial approximations, with applications in digital filters and matrix iteration. By making the end of the strip jagged, the method can be generalised to weighted Green's functions and weighted approximations
Stochastic perturbations in open chaotic systems: random versus noisy maps
We investigate the effects of random perturbations on fully chaotic open
systems. Perturbations can be applied to each trajectory independently (white
noise) or simultaneously to all trajectories (random map). We compare these two
scenarios by generalizing the theory of open chaotic systems and introducing a
time-dependent conditionally-map-invariant measure. For the same perturbation
strength we show that the escape rate of the random map is always larger than
that of the noisy map. In random maps we show that the escape rate and
dimensions of the relevant fractal sets often depend nonmonotonically on
the intensity of the random perturbation. We discuss the accuracy (bias) and
precision (variance) of finite-size estimators of and , and show
that the improvement of the precision of the estimations with the number of
trajectories is extremely slow (). We also argue that the
finite-size estimators are typically biased. General theoretical results
are combined with analytical calculations and numerical simulations in
area-preserving baker maps.Comment: 12 pages, 3 figures, 1 table, manuscript submitted to Physical Review
Discrete embedded solitons
We address the existence and properties of discrete embedded solitons (ESs),
i.e., localized waves existing inside the phonon band in a nonlinear
dynamical-lattice model. The model describes a one-dimensional array of optical
waveguides with both the quadratic (second-harmonic generation) and cubic
nonlinearities. A rich family of ESs was previously known in the continuum
limit of the model. First, a simple motivating problem is considered, in which
the cubic nonlinearity acts in a single waveguide. An explicit solution is
constructed asymptotically in the large-wavenumber limit. The general problem
is then shown to be equivalent to the existence of a homoclinic orbit in a
four-dimensional reversible map. From properties of such maps, it is shown that
(unlike ordinary gap solitons), discrete ESs have the same codimension as their
continuum counterparts. A specific numerical method is developed to compute
homoclinic solutions of the map, that are symmetric under a specific reversing
transformation. Existence is then studied in the full parameter space of the
problem. Numerical results agree with the asymptotic results in the appropriate
limit and suggest that the discrete ESs may be semi-stable as in the continuous
case.Comment: A revtex4 text file and 51 eps figure files. To appear in
Nonlinearit
Quantum Theory of Reactive Scattering in Phase Space
We review recent results on quantum reactive scattering from a phase space
perspective. The approach uses classical and quantum versions of normal form
theory and the perspective of dynamical systems theory. Over the past ten years
the classical normal form theory has provided a method for realizing the phase
space structures that are responsible for determining reactions in high
dimensional Hamiltonian systems. This has led to the understanding that a new
(to reaction dynamics) type of phase space structure, a {\em normally
hyperbolic invariant manifold} (or, NHIM) is the "anchor" on which the phase
space structures governing reaction dynamics are built. The quantum normal form
theory provides a method for quantizing these phase space structures through
the use of the Weyl quantization procedure. We show that this approach provides
a solution of the time-independent Schr\"odinger equation leading to a (local)
S-matrix in a neighborhood of the saddle point governing the reaction. It
follows easily that the quantization of the directional flux through the
dividing surface with the properties noted above is a flux operator that can be
expressed in a "closed form". Moreover, from the local S-matrix we easily
obtain an expression for the cumulative reactio probability (CRP).
Significantly, the expression for the CRP can be evaluated without the need to
compute classical trajectories. The quantization of the NHIM is shown to lead
to the activated complex, and the lifetimes of quantum states initialized on
the NHIM correspond to the Gamov-Siegert resonances. We apply these results to
the collinear nitrogen exchange reaction and a three degree-of-freedom system
corresponding to an Eckart barrier coupled to two Morse oscillators.Comment: 59 pages, 13 figure
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