Lactobacillusassisted synthesis of titanium nanoparticles

An eco-friendlylactobacillussp. (microbe) assisted synthesis of titanium nanoparticles is reported. The synthesis is performed at room temperature. X-ray and transmission electron microscopy analyses are performed to ascertain the formation of Ti nanoparticles. Individual nanoparticles as well as a number of aggregates almost spherical in shape having a size of 40–60 nm are found

Voids in kesterites and the influence of lamellae preparation by focused ion beam for transmission electron microscopy analyses

Kesterite solar cells based in Cu2ZnSnS4 and Cu2ZnSnSe4 are potential future candidates to be used in thin film solar cells. The technology still has to be developed to a great extent and for this to happen, high levels of confidence in the characterization methods are required so that improvements can be made on solid interpretations. In this study we show that the interpretations of one of the most used characterization techniques in kesterites, scanning transmission electron microscopy (STEM), might be affected by its specimen preparation when using focused ion beam (FIB). Using complementary measurements based on scanning electron microscopy and Raman scattering spectroscopy, compelling evidences show that secondary phases of ZnSe mixed in the bulk of Cu2ZnSnSe4 are the likely cause of the appearance of voids in the STEM lamellae. Sputtering simulations support this interpretation by showing that Zn in a ZnSe matrix is preferentially sputtered compared with any metal atom in a Cu2ZnSnSe4 matrix.publishe

Magnetofossil Spike During the Paleocene-Eocene Thermal Maximum: Ferromagnetic Resonance, Rock Magnetic, and Electron Microscopy Evidence from Ancora, New Jersey, USA

Previous workers identified a magnetically anomalous clay layer deposited on the northern United States Atlantic Coastal Plain during the Paleocene-Eocene Thermal Maximum (PETM). The finding inspired the highly controversial hypothesis that a cometary impact triggered the PETM. Here we present ferromagnetic resonance (FMR), isothermal and anhysteretic remanent magnetization, first order reversal curve, and transmission electron microscopy analyses of late Paleocene and early Eocene sediments in drillcore from Ancora, New Jersey. A novel paleogeographic analysis applying a recent paleomagnetic pole from the Faeroe Islands indicates that New Jersey during the initial Eocene had a ~6-9 degrees lower paleolatitude (~27.3 degrees for Ancora) and a more zonal shoreline trace than in conventional reconstructions. Our investigations of the PETM clay from Ancora reveal abundant magnetite nanoparticles bearing signature traits of crystals produced by magnetotactic bacteria. This result, the first identification of ancient biogenic magnetite using FMR, argues that the anomalous magnetic properties of the PETM sediments are not produced by an impact. They instead reflect environmental changes along the eastern margin of North America during the PETM that led to enhanced production and/or preservation of magnetofossils

Catalytic properties of Co3O4 nanoparticles for rechargeable Li/air batteries

Three types of Co3O4 nanoparticles are synthesized and characterized as a catalyst for the air electrode of a Li/air battery. The shape and size of the nanoparticles are observed using scanning electron microscopy and transmission electron microscopy analyses. The formation of the Co3O4 phase is confirmed by X-ray diffraction. The electrochemical property of the air electrodes containing Co3O4 nanoparticles is significantly associated with the shape and size of the nanoparticles. It appears that the capacity of electrodes containing villiform-type Co3O4 nanoparticles is superior to that of electrodes containing cube- and flower-type Co3O4 nanoparticles. This is probably due to the sufficient pore spaces of the villiform-type Co3O4 nanoparticles

Electrical and structural properties of MgB2 films prepared by sequential deposition of B and Mg on the NbN buffered Si(100) substrate

We introduce a simple method of an MgB2 film preparation using sequential electron-beam evaporation of B-Mg two-layer (followed by in-situ annealing) on the NbN buffered Si(100) substrate. The Transmission Electron Microscopy analyses confirm a growth of homogeneous nanogranular MgB2 films without the presence of crystalline MgO. A sensitive measurement of temperature dependence of microwave losses shows a presence of intergranular weak links close the superconducting transition only. The MgB2 films obtained, about 200 nm thick, exhibit a maximum zero resistance critical temperature of 36 K and critical current density of 3x10^7 A/cm^2 at 13.2 KComment: 11 pages, 6 figures, submitted to Appl. Phys. Let

Structure of the carbon layers deposited on the toroidal pump limiter of Tore Supra

International audienceScanning and transmission electron microscopy analyses have been performed for tiles extracted from the toroidal pump limiter of Tore Supra for erosion- and deposition-dominated zones. Deposit thicknesses have been estimated for the plasma-facing top and the gap side lateral surfaces. Deposit thickness profiles have been measured inside gaps, showing that deposition mainly occurs in the first millimetre and that both poloidal and toroidal gap deposition is asymmetric. Quantitative information on the deposit volume and on D-retention are thus obtained from these measurements. Carbon probed at the tile top surfaces is mainly amorphous carbon, due either to the amorphization induced by ion bombardment in the erosion dominated zone, or to deposit formation processes in the deposition-dominated zones. Deposits are tip-shaped and are oriented, which should give information on transport processes

Hydrogen induced optically-active defects in silicon photonic nanocavities

This work was supported by Era-NET NanoSci LECSIN project coordinated by F. Priolo, by the Italian Ministry of University and Research, FIRB contract No. RBAP06L4S5 and by the EPSRC UKSp project. Partial financial support by the Norwegian Research Council is also acknowledged.We demonstrate intense room temperature photoluminescence (PL) from optically active hydrogen- related defects incorporated into crystalline silicon. Hydrogen was incorporated into the device layer of a silicon on insulator (SOI) wafer by two methods: hydrogen plasma treatment and ion implantation. The room temperature PL spectra show two broad PL bands centered at 1300 and 1500 nm wavelengths: the first one relates to implanted defects while the other band mainly relates to the plasma treatment. Structural characterization reveals the presence of nanometric platelets and bubbles and we attribute different features of the emission spectrum to the presence of these different kind of defects. The emission is further enhanced by introducing defects into photonic crystal (PhC) nanocavities. Transmission electron microscopy analyses revealed that the isotropicity of plasma treatment causes the formation of a higher defects density around the whole cavity compared to the ion implantation technique, while ion implantation creates a lower density of defects embedded in the Si layer, resulting in a higher PL enhancement. These results further increase the understanding of the nature of optically active hydrogen defects and their relation with the observed photoluminescence, which will ultimately lead to the development of intense and tunable crystalline silicon light sources at room temperature.Publisher PDFPeer reviewe

Ultrabroadband mid-infrared emission from Cr 2+ -doped infrared transparent chalcogenide glass ceramics embedded with thermally grown ZnS nanorods

We report, for the first time to our knowledge, an ultrabroadband mid-infrared (MIR) emission in the range of 1800–2800 nm at room temperature from a Cr2+-doped chalcogenide glass ceramic embedded with pure hexagonal (wurtzite) β-ZnS nanorods and study the emission-dependent properties on the doping concentration of Cr2+. A new family of chalcogenide glasses based on (100 − x) Ge1.5As2S6.5 – x ZnSe (in mol.%) was prepared by melt-quenching method. The Cr2+: β-ZnS nanorods of ˜150 nm in diameter and ˜1 μm in length were grown in the Cr2+-doped glass after thermal annealing. The compositional variations of glass structures and optical properties were studied. The crystalline phase, morphology of the thermally grown nanorods, and the microscopic elemental distributions were characterized using advanced nanoscale transmission electron microscopy analyses