Diffusion, super-diffusion and coalescence from single step

From the exact single step evolution equation of the two-point correlation function of a particle distribution subjected to a stochastic displacement field \bu(\bx), we derive different dynamical regimes when \bu(\bx) is iterated to build a velocity field. First we show that spatially uncorrelated fields \bu(\bx) lead to both standard and anomalous diffusion equation. When the field \bu(\bx) is spatially correlated each particle performs a simple free Brownian motion, but the trajectories of different particles result to be mutually correlated. The two-point statistical properties of the field \bu(\bx) induce two-point spatial correlations in the particle distribution satisfying a simple but non-trivial diffusion-like equation. These displacement-displacement correlations lead the system to three possible regimes: coalescence, simple clustering and a combination of the two. The existence of these different regimes, in the one-dimensional system, is shown through computer simulations and a simple theoretical argument.Comment: RevTeX (iopstyle) 19 pages, 5 eps-figure

Diffusion on a stepped substrate

We present results for collective diffusion of adatoms on a stepped substrate with a submonolayer coverage. We study the combined effect of the additional binding at step edge, the Schwoebel barrier, the enhanced diffusion along step edges, and the finite coverage on diffusion as a function of step density. In particular, we examine the crossover from step--dominated diffusion at high step density to terrace-dominated behavior at low step density in a lattice-gas model using analytical Green's function techniques and Monte Carlo simulations. The influence of steps on diffusion is shown to be more pronounced than previously anticipated.Comment: 4 pages, RevTeX, 3 Postscript figure

Quaternionic Diffusion by a Potential Step

In looking for qualitative differences between quaternionic and complex formulations of quantum physical theories, we provide a detailed discussion of the behavior of a wave packet in presence of a quaternionic time-independent potential step. In this paper, we restrict our attention to diffusion phenomena. For the group velocity of the wave packet moving in the potential region and for the reflection and transmission times, the study shows a striking difference between the complex and quaternionic formulations which could be matter of further theoretical discussions and could represent the starting point for a possible experimental investigation.Comment: 10 pages, 1 figur

Drift-Induced Step Instabilities Due to the Gap in the Diffusion Coefficient

On a Si(111) vicinal face near the structural transition temperature, the $1 \times 1$ structure and the $7 \times 7$ structure coexist in a terrace: the $1 \times 1$ structure is in the lower side of the step edge and the $7 \times 7$ structure in the upper side. The diffusion coefficient of adatoms is different in the two structures. Taking account of the gap in the diffusion coefficient at the step, we study the possibility of step wandering induced by drift of adatoms. A linear stability analysis shows that the step wandering always occurs with step-down drift if the diffusion coefficient has a gap at the step. Formation of straight grooves by the step wandering is expected from a nonlinear analysis. The stability analysis also shows that step bunching occurs irrespective of the drift direction if the diffusion in the lower side of the step is faster. The step bunching disturbs the formation of grooves. If step-step repulsion is strong, however, the step bunching is suppressed and the straight grooves appear. Monte Carlo simulation confirms these predictions.Comment: 5 pages, 6 figure

A Two-Region Diffusion Model for Current-Induced Instabilities of Step Patterns on Vicinal Si(111) Surfaces

We study current-induced step bunching and wandering instabilities with subsequent pattern formations on vicinal surfaces. A novel two-region diffusion model is developed, where we assume that there are different diffusion rates on terraces and in a small region around a step, generally arising from local differences in surface reconstruction. We determine the steady state solutions for a uniform train of straight steps, from which step bunching and in-phase wandering instabilities are deduced. The physically suggestive parameters of the two-region model are then mapped to the effective parameters in the usual sharp step models. Interestingly, a negative kinetic coefficient results when the diffusion in the step region is faster than on terraces. A consistent physical picture of current-induced instabilities on Si(111) is suggested based on the results of linear stability analysis. In this picture the step wandering instability is driven by step edge diffusion and is not of the Mullins-Sekerka type. Step bunching and wandering patterns at longer times are determined numerically by solving a set of coupled equations relating the velocity of a step to local properties of the step and its neighbors. We use a geometric representation of the step to derive a nonlinear evolution equation describing step wandering, which can explain experimental results where the peaks of the wandering steps align with the direction of the driving field.Comment: 11 pages, 10 figure

Evaporation and Step Edge Diffusion in MBE

Using kinetic Monte-Carlo simulations of a Solid-on-Solid model we investigate the influence of step edge diffusion (SED) and evaporation on Molecular Beam Epitaxy (MBE). Based on these investigations we propose two strategies to optimize MBE-growth. The strategies are applicable in different growth regimes: during layer-by-layer growth one can reduce the desorption rate using a pulsed flux. In three-dimensional (3D) growth the SED can help to grow large, smooth structures. For this purpose the flux has to be reduced with time according to a power law.Comment: 5 pages, 2 figures, latex2e (packages: elsevier,psfig,latexsym

Step Bunching with Alternation of Structural Parameters

By taking account of the alternation of structural parameters, we study bunching of impermeable steps induced by drift of adatoms on a vicinal face of Si(001). With the alternation of diffusion coefficient, the step bunching occurs irrespective of the direction of the drift if the step distance is large. Like the bunching of permeable steps, the type of large terraces is determined by the drift direction. With step-down drift, step bunches grows faster than those with step-up drift. The ratio of the growth rates is larger than the ratio of the diffusion coefficients. Evaporation of adatoms, which does not cause the step bunching, decreases the difference. If only the alternation of kinetic coefficient is taken into account, the step bunching occurs with step-down drift. In an early stage, the initial fluctuation of the step distance determines the type of large terraces, but in a late stage, the type of large terraces is opposite to the case of alternating diffusion coefficient.Comment: 8pages, 16 figure