Chiral charge-density-waves

We discovered the chirality of charge density waves (CDW) in 1T-TiSe$_2$ by using scanning tunnelling microscopy (STM) and optical ellipsometry. We found that the CDW intensity becomes $I{a_1}:I{a_2}:I{a_3} = 1:0.7 \pm 0.1:0.5 \pm 0.1$, where $Ia_i$ (i =1, 2, 3) is the amplitude of the tunnelling current contributed by the CDWs. There were two states, in which the three intensity peaks of the CDW decrease \textit{clockwise} and \textit{anticlockwise} when we index each nesting vector in order of intensity in the Fourier transformation of the STM images. The chirality in CDW results in the three-fold symmetry breaking. Macroscopically, two-fold symmetry was indeed observed in optical measurement. We propose the new generalized CDW chirality H_{CDW} \equiv {\boldmath q_1} \cdot ({\boldmath q_2}\times {\boldmath q_3}), where {\boldmath q_i} are the nesting vectors, which is independent of the symmetry of components. The nonzero $H_{CDW}$ - the triple-{\boldmath q} vectors do not exist in an identical plane in the reciprocal space - should induce a real-space chirality in CDW system.Comment: 12 pages, 4 figure

Holographic Charge Density Waves

We discuss a gravity dual of a charge density wave consisting of a U(1) gauge field and two scalar fields in the background of an AdS$_4$ Schwarzschild black hole together with an antisymmetric field (probe limit). Interactions drive the system to a phase transition below a critical temperature. We numerically compute the ground states characterized by modulated solutions for the gauge potential corresponding to a dynamically generated unidirectional charge density wave in the conformal field theory. Signatures of the holographic density waves are retrieved by studying the dynamical response to an external electric field. We find that this novel holographic state shares many common features with the standard condensed matter version of charge density wave systems.Comment: 5 pages, 2 figures; improved discussion, published versio

Charge Density Wave Ratchet

We propose to operate a locally-gated charge density wave as an electron pump. Applying an oscillating gate potential with frequency $f$ causes equally spaced plateaux in the sliding charge density wave current separated by $\Delta I=2eNf,$ where $N$ is the number of parallel chains. The effects of thermal noise are investigated.Comment: To be published in Applied Physics Letter

Charge Density of the Neutron

A model-independent analysis of the infinite-momentum-frame charge density of partons in the transverse plane is presented for the nucleon. We find that the neutron parton charge density is negative at the center, so that the square of the transverse charge radius is positive, in contrast with many expectations. Additionally, the proton's central u quark charge density is larger than that of the d quark by about 70 %. The proton (neutron) charge density has a long range positively (negatively) charged component.Comment: 7 pages, three figures The replacement mainly concerns correcting an error made in computing the proton up and down quark densities from the correctly computed proton and neutron charge densities. The proton central u quark density is now larger than that of the d quar

Polyelectrolytes with high charge density

Polymers can be used as flocculants to clarify residential and industrial water supplies and as bactericidal and fungicidal agents. They can be used in preparation of electroconductive photocopy papers, to improve living cell adhesion to glass or plastic, and as anticancer agents

Electrostatic interactions in host-guest complexes 2

In this article the quantum chemically calculated charge density distribution of 18-crown-6 and the K+ 18-crown-6 complex are compared with the charge density distribution of smaller molecules and corresponding complexes which can be considered as fragments of the 18-crown-6 molecule. An analysis of the charge density distribution in terms of atomic charge distribution according to the stockholder recipe gives accurate rules for the transferability of the charge density distribution. This gives us the possibility to construct the charge density distribution of large molecules out of accurate large basis set results on small molecules

Charge density wave in hidden order state of URu2_2Si2_2

We argue that the hidden order state in URu$_2$Si$_2$ will induce a charge density wave. The modulation vector of the charge density wave will be twice that of the hidden order state, $Q_{CDW} = 2Q_{HO}$. To illustrate how the charge density wave arises we use a Ginzburg-Landau theory that contains a coupling of the charge density wave amplitude to the square of the HO order parameter $\Delta_{HO}$. This simple analysis allows us to predict the intensity and temperature dependence of the charge density wave order parameter in terms of the susceptibilities and coupling constants used in the Ginzburg-Landau analysis.Comment: 8 pages, 4 figure

Quantum crystallographic charge density of urea

Standard X-ray crystallography methods use free-atom models to calculate mean unit cell charge densities. Real molecules, however, have shared charge that is not captured accurately using free-atom models. To address this limitation, a charge density model of crystalline urea was calculated using high-level quantum theory and was refined against publicly available ultra high-resolution experimental Bragg data, including the effects of atomic displacement parameters. The resulting quantum crystallographic model was compared to models obtained using spherical atom or multipole methods. Despite using only the same number of free parameters as the spherical atom model, the agreement of the quantum model with the data is comparable to the multipole model. The static, theoretical crystalline charge density of the quantum model is distinct from the multipole model, indicating the quantum model provides substantially new information. Hydrogen thermal ellipsoids in the quantum model were very similar to those obtained using neutron crystallography, indicating that quantum crystallography can increase the accuracy of the X-ray crystallographic atomic displacement parameters. The results demonstrate the feasibility and benefits of integrating fully periodic quantum charge density calculations into ultra high-resolution X-ray crystallographic model building and refinement.Comment: 40 pages, 4 figures, 6 table