Determinação de coeficientes de cultura para o milho durante um experimento de evapotranspiração em um oxisol do Brasil

Soil water balance components were measured during two periods (from 1989 to 1991) on a Dark Red Latosol (oxisol) in Piracicaba,SP, Brazil. The change in soil water storage and the soil water fluxes at the lower limit of the rooting zone were calculated for a transect of 25 observation plots. Hydraulic head gradients were determined by tensiometer measurements. Soil water flux densities were estimated through Darcy's equation. The actual evapotranspiration of the crops and weeds and the actual evaporation of bare soil were obtained from the water balance equation and this for two periods under different crop rotations. For the first period the sequence was bare soil-corn-weeds and for the second period it was stubble mulch-weeds-corn. For assessing the crop coefficients the potential evapotranspiration was calculated according to two different methods. The first method was based on the modified Penman equation with grass as a reference crop, to obtain this way reference coefficients, and the second method was based on the pan "A" evaporation data in order to obtain pan coefficients. These coefficients were compared with the tabulated crop coefficients. In general when there was no shortage of water during the corn growth, the crop coefficients k c"A" and k c ref were very close to the k c values.Os componentes do balanço hídrico foram medidos durante dois períodos (de 1989 a 1991) em terra roxa estruturada, em Piracicaba,SP, Brasil. As variações de armazenamento de água e os fluxos de água no solo no limite inferior da zona radicular foram calculados para uma transeção de 25 parcelas experimentais. Gradientes hidráulicos foram determinados por meio de medidas tensiométricas. Densidades de fluxo de água foram estimadas através da equação de Darcy. A evapotranspiração atual das culturas e das ervas daninhas e a evaporação atual do solo nú foram obtidas da equação do balanço hídrico, para dois períodos, sob diferentes rotações de cultura. Para o primeiro período a seqüência foi solo nú - milho - ervas daninhas e para o segundo cobertura morta - ervas daninhas - milho. Para determinar os coeficientes de cultura, a evapotranspiração potencial foi calculada por dois métodos. O primeiro foi baseado na equação de Penman modificada, com a grama como cobertura de referência, obtendo assim os coeficientes de referência, e o segundo baseado no tanque de evaporação tipo classe "A", obtendo os coeficientes de tanque. Estes coeficientes foram comparados com os coeficientes de cultura tabulados. De uma forma geral, em períodos sem falta de água para a cultura, os coeficientes de referência e de tanque se assemelharam bastante aos coeficientes de cultura

C−H Bond Activation by Iridium(III) and Iridium(IV) Oxo Complexes

Oxidation of an iridium(III) oxo precursor enabled the structural, spectroscopic, and quantum-chemical characterization of the first well-defined iridium(IV) oxo complex. Side-by-side examination of the proton-coupled electron transfer thermochemistry revealed similar driving forces for the isostructural oxo complexes in two redox states due to compensating contributions from H+ and e− transfer. However, C−H activation of dihydroanthracene revealed significant hydrogen tunneling for the distinctly more basic iridium(III) oxo complex. Our findings complement the growing body of data that relate tunneling to ground state properties as predictors for the selectivity of C−H bond activation.</p

The willingness of final year medical and dental students to perform bystander cardiopulmonary resuscitation in an Asian community

Background Despite the importance of early effective chest compressions to improve the chance of survival of an out-of-hospital cardiac arrest victim, it is still largely unknown how willing our Malaysian population is to perform bystander cardiopulmonary resuscitation (CPR). Aims We conducted a voluntary, anonymous self-administered questionnaire survey of a group of 164 final year medical students and 60 final year dental students to unravel their attitudes towards performing bystander CPR. Methods Using a 4-point Likert scale of “definitely yes,” “probably yes,” “probably no,” and “definitely no,” the students were asked to rate their willingness to perform bystander CPR under three categories: chest compressions with mouth-to-mouth ventilation (CC + MMV), chest compressions with mask-to-mouth ventilation (CC + PMV), and chest compressions only (CC). Under each category, the students were given ten hypothetical victim scenarios. Categorical data analysis was done using the McNemar test, chi-square test, and Fisher exact test where appropriate. For selected analysis, “definitely yes” and “probably yes” were recoded as a “positive response.” Results Generally, we found that only 51.4% of the medical and 45.5% of the dental students are willing to perform bystander CPR. When analyzed under different hypothetical scenarios, we found that, except for the scenario where the victim is their own family member, all other scenarios showed a dismally low rate of positive responses in the category of CC + MMV, but their willingness was significantly improved under the CC + PMV and CC categories. Conclusion This study shows that there are unique sociocultural factors that contribute to the reluctance of our students to perform CC + MMV. Keywords Cardiopulmonary resuscitation Mouth-to-mouth resuscitation Basic cardiac life support Asian communit