The influence of the shape of a saw-cut notch in quasi-brittle 3PB specimens on the critical applied force

Values of fracture parameters of quasi-brittle building materials are usually determined from results of tests performed on notched testing specimens. The contribution deals with the influence of various shapes of tips of notches prepared by a diamond saw in three point bending (3PB) specimens. The influence of the notch tip shape on the applied force corresponding to a failure initiation at the notch tip and also on the critical applied force appropriate to the maximal load-bearing capacity of the specimen is studied. Calculations are performed in two finite element method (FEM) systems (ATENA, ANSYS) based on two different approaches to fracture description (Cohesive crack models and LEFM, respectively). The numerical results obtained by both FEM systems are compared. The influence of notch shapes and width is quantified

Modelling reversibility of Central European mountain lakes from acidification: Part I - the Bohemian forest

International audienceA dynamic, process-based acidification model, MAGIC7, has been applied to three small, strongly acidified lakes in the Bohemian Forest, the Czech Republic. The model was calibrated for a set of experimental records on lake water composition over the 1984?2000 period, and produced hindcast concentrations that compared well, even with older (40-year) irregular determinations of nitrate, chloride and pH. Water and soil chemistry forecasts up to 2050 were based on reductions in S and N emissions presupposed by the Gothenburg Protocol. Modelled sulphate and chloride concentrations were predicted to decrease to the levels at the beginning of the 20th century by 2050. The lake water carbonate buffering system is predicted to be re-established in only two lakes (Cerné and Ple?né), with current soil base saturations of 12-15%. Concentrations of ionic aluminium species decreased sharply, from 110 ?eq l-1 in the mid-1980s to the current ~40 ?eq l-1, and were predicted to decrease below 10 ?eq l-1 in the 2020s. Diatom-inferred pH in pre-industrial times was substantially lower than modelled pH. It is suggested that the diatom pH, based almost entirely on non-planktonic species, is biased by inwash of diatoms from more acidic tributaries into the sediment of these small lakes. Generally significant results can be summarised as follows: (1) Simulated sulphate levels agree well with observations during acidification progress and retreat only for values of soil SO42- adsorption capacity three to six times (20 to 40 ?eq kg-1) higher than those found experimentally. This implies a further mechanism of S retention and release in addition to physical sulphate adsorption to Fe and Al oxides of soils. (2) The catchments' ability to retain deposited N appeared to decline after ~1950 but this was not connected with a sufficient change in the C:N ratio of the soils. Agreement between modelled and observed concentrations of nitrate was therefore achieved by empirical restriction of N retention in the soils. Based on their current ability to retain N, the catchments will remain N-saturated and could, temporarily, produce more inorganic N than they receive due to additional nitrate production from soil N-organic pools. This situation has occurred already in the Cerné Lake catchment. (3) Differences in responses of individual lakes can be attributed to different land usages over the past several centuries as well as to differences in geology and primary production. Keywords: MAGIC, atmospheric deposition, N retention, diatom-inferred pH, sulphate, nitrate, base cations, aluminium, Czech Republi

Hydrogen or Soot?: Partial Oxidation of High-boiling Hydrocarbon Wastes

This paper is focused on researching the influence of process parameters of partial oxidation, such as quality of hydrocarbon raw materials that differ in their stock properties (especially boiling point and viscosity) on the composition of output gas (selectivity of the process), and also on the formation extent of soot which could be used as an excellent and valued sorbent CHEZACARB® and/or filler in the rubber industry, e.g. for automotive tires. The effects of steam flow rate and the oxygen to raw material feed rate ratio is discussed as well. In addition, sensitivity of POX product composition depending on properties of different raw materials and reaction conditions were analysed in this study

Increasing silicon concentrations in Bohemian Forest lakes

International audienceLong-term trends of dissolved silicon (Si) concentrations in five glacial lakes in the Bohemian Forest, Czech Republic, recovering from acidification show higher mobility of Si from the soil to surface waters despite lower atmospheric deposition of acids. Si increased by 0.95 to 1.95 µmol yr-1 (36 to 51%) from 1986-2004 and with increasing pH. A change in soil solution conditions because of a sharp decrease in acidic deposition has led to marked decline in Al mobility and to considerable decreases in dissolved Al, especially Al3+. The increase in Si may be related to: (1) unblocking of the inhibitory effect of dissolved Al on weathering of aluminosilicates, (2) biogenic opal (phytoliths) dissolving faster, and/or (3) lower Si precipitation as secondary aluminosilicates in soil. The change in Al speciation on the dissolution rate of biogenic silica is critical. A lack of change in Si at sites outside central Europe may be explained by small or no decline in mobility of dissolved Al. The effect of a long-term increase in temperature was probably minor

Estimation of the crack propagation direction in a mixed-mode geometry via multi-parameter fracture criteria

The presented work introduces a numerical parametric study on the crack propagation direction under mixed-mode conditions (mode I + II). It is conducted for the geometry of an eccentric asymmetric fourpoint bending of a single edge notched beam specimen; various levels of mode-mixity are ensured by modifications in the crack length and crack eccentricity. The direction of crack propagation is estimated semianalytically using both the maximum tangential stress criterion and the strain energy density criterion (implemented as a procedure within the used finite element computational code) as well as numerically (from verification reasons). Multi-parameter fracture mechanics is employed in the presented work for precise analytical evaluation of the stress field in the cracked specimen. This theory is based on description of the stress and deformation fields in the cracked body by means of their approximation using several initial terms of the Williams power series. Recent studies show that utilization of only first term of the series, which corresponds to the stress intensity factor (SIF), the single controlling parameter for the crack initiation and propagation assessment in brittle materials, is insufficient in many crack problems. It appears also in this study that the higher-order terms of the asymptotic crack-tip field are of great relevance for the conducted analysis, similarly to a number of other fracture phenomena (near-crack-tip stress field approximation, non-linear zone extent estimation, etc.)

Electrical resistivity and ultrasonic measurements during sequential fracture test of cementitious composite

Cracks in cover of reinforced and pre-stressed concrete structures significantly influence the ingress of deleterious species causing decrease in durability of these structures. The paper is focused on the effect of fracture process on two selected physical parameters of concrete – the electrical resistivity and the ultrasonic pulse passing time – which might be employed as the quality indicator of concrete cover within (nondestructive) procedure(s) of assessment of the structural durability. The concrete electrical resistivity and ultrasonic passing time were investigated here with respect to two variants of treatment of the test specimens’ surface (the pre-dried surface and the wet surface). Test configuration of three-point bending of notched beam was utilized to control the crack propagation; the fracture process passed through several loading–unloading sequences between which the electrical resistivity and ultrasonic passing time readings over the fractured region were performed. Equivalent elastic crack model was used for estimation of the fracture advance (described via the effective crack length) at the loading stages corresponding to the resistivity and ultrasonic measurements. Relationships between changes of both the concrete resistivity and ultrasonic pulse passing time and the effective crack length is determined and discussed

Vliv šířky zářezu na lomovou odezvu ohýbaných betonových vzorků

An influence of the test specimen’s preparation – shape and width of a stress concentrator – on the values of parameters of nonlinear fracture models of quasi-brittle cement-based composites is analyses in the paper presented. The parameters – e.g. effective crack extension, effective fracture toughness, and specific fracture energy – can be calculated from results of loading tests performed on notched three point bend specimens. The effects are investigated by means of a comparison of numerically simulated fracture process in the cracked specimen with the specimens with the double V-notch. The numerical simulations of the fracture according to the linear elastic fracture mechanics were performed by using finite element method programs (ANSYS, and FRANC2D). The influence on the load-carrying capacity and the initial compliance of the cracked specimen are introduced and discussed