The tilting hygrometer: A new form of absorption hygrometer

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Resistivity of Zinc Crystals

The resistivity at 20°C of zinc crystals made of Kahlbaum\u27s purest and of Spectroscopically Pure zinc (from New. Jersey Zinc Company) is given as a function of direction of current flow relative to the orientation of the crystal lattice. For the Kahlbaum crystals the results are very much more consistent than have previously been obtained and point to a higher ratio of p11/p1 than that obtained by Bridgman. The Spectroscopically Pure crystals agree in the main with the Kahlbaum, but there are a few exceptional cases which tend to confirm Bridgman\u27s strain theory. It seems more probable, however, that an explanation can be given in terms of the conditions governing the growth of the crystals

Adhesion Between Surfaces Separated by Molecularly Thin Perfluoropolyether Films

The relationship between the adhesion of surfaces separated by a molecularly thin liquid film and the surface energy of the film was investigated. AFM-based force–distance curves were measured on a series of carbon surfaces coated with hydroxyl-terminated perfluoropolyether (PFPE) films. The surface energy of the PFPE films was varied by altering either the total film thickness or the bonding ratio of the film by changing the concentration of the PFPE film in the solution and/or the pull-rate during dip-coating. A linear relationship between adhesion force and surface energy was observed. Adhesion was found to vanish at non-zero values of surface energy. The experimental results indicate that the adhesive force between macroscopic bodies separated by molecularly thin liquid films is linearly proportional to the excess surface energy of the film

Rapid formation of isoprene photo-oxidation products observed in Amazonia

Isoprene represents the single most important reactive hydrocarbon for atmospheric chemistry in the tropical atmosphere. It plays a central role in global and regional atmospheric chemistry and possible climate feedbacks. Photo-oxidation of primary hydrocarbons (e.g. isoprene) leads to the formation of oxygenated VOCs (OVOCs). The evolution of these intermediates affects the oxidative capacity of the atmosphere (by reacting with OH) and can contribute to secondary aerosol formation, a poorly understood process. An accurate and quantitative understanding of VOC oxidation processes is needed for model simulations of regional air quality and global climate. Based on field measurements conducted during the Amazonian Aerosol Characterization Experiment (AMAZE-08) we show that the production of certain OVOCs (e.g. hydroxyacetone) from isoprene photo-oxidation in the lower atmosphere is significantly underpredicted by standard chemistry schemes. Recently reported fast secondary production could explain 50% of the observed discrepancy with the remaining part possibly produced via a novel primary production channel, which has been proposed theoretically. The observations of OVOCs are also used to test a recently proposed HO<sub>x</sub> recycling mechanism via degradation of isoprene peroxy radicals. If generalized our observations suggest that prompt photochemical formation of OVOCs and other uncertainties in VOC oxidation schemes could result in uncertainties of modelled OH reactivity, potentially explaining a fraction of the missing OH sink over forests which has previously been largely attributed to a missing source of primary biogenic VOCs

The State of the System and Steps Toward Resilience of Disturbancedependent Oak Forests

Current ecological, economic, and social conditions present unique challenges to natural resource managers seeking to maintain the resilience of disturbance-dependent ecosystems, such as oak (Quercus spp.) forests. Oak-dominated ecosystems throughout the U.S. have historically been perpetuated through periodic disturbance, such as fire, but more recently show decline given shifting disturbance regimes associated with human land management decisions. We characterized the state of the social-ecological oak forest ecosystem in the midwestern U.S. through the perspectives of 32 natural resource professionals. Data from interviews with these change agents provided an integrative understanding of key system components, cross-scale interactions, dependencies, and feedbacks. Foremost, private landowner management decisions figured prominently in influencing oak regeneration success and were directly and indirectly shaped by a suite of interdependent ecological, e.g., deer herbivory, invasive shrub occurrence; economic, e.g., the cost of oak regeneration practices, the stumpage value of maple as compared to oak; and social forces, e.g., forestland parcelization, and personal relationships. Interviewees envisioned, and often preferred, a decline in oak dominance throughout the region, pointing to issues related to general landowner unwillingness to restore oak, the current trajectory of forest change, the threat of forest loss due to parcelization and housing development, and a combination of ecological and social factors that decrease the economic feasibility of restoration efforts. However, a decline in oak dominance may result in ecological communities that have no compositional equivalent on record and may not offer a desirable endpoint. Increasing social support offers the potential to enhance system capacity to manage for oak