583 research outputs found
A laminar roughness boundary condition
A modified slip boundary condition is obtained to represent the effects of small roughness-like perturbations to an otherwise-plane fixed wall which is acting as a boundary to steady laminar flow of a viscous fluid. In its simplest form, for low local Reynolds number and small roughness slope, this boundary condition involves a constant apparent backflow at the mean surface or, equivalently, represents a shift of the apparent plane boundary toward the flow domain. Extensions of the theory are also made to include finite local Reynolds number and finite roughness slope.E. O. Tuck and A. Kouzoubo
Exact and semiclassical approach to a class of singular integral operators arising in fluid mechanics and quantum field theory
A class of singular integral operators, encompassing two physically relevant
cases arising in perturbative QCD and in classical fluid dynamics, is presented
and analyzed. It is shown that three special values of the parameters allow for
an exact eigenfunction expansion; these can be associated to Riemannian
symmetric spaces of rank one with positive, negative or vanishing curvature.
For all other cases an accurate semiclassical approximation is derived, based
on the identification of the operators with a peculiar Schroedinger-like
operator.Comment: 12 pages, 1 figure, amslatex, bibtex (added missing label eq.11
On open venturis
Flow through an open converging-diverging channel, aimed at achieving maximum velocity at the throat.E. O. Tuc
Towards a systematic understanding of the influence of temperature on glycosylation reactions
Glycosidic bond formation is a continual challenge for practitioners. Aiming to enhance the reproducibility and efficiency of oligosaccharide synthesis, we studied the relationship between glycosyl donor activation and reaction temperature. A novel semi-automated assay revealed diverse responses of members of a panel of thioglycosides to activation at various temperatures. The patterns of protecting groups and the thiol aglycon combine to cause remarkable differences in temperature sensitivity among glycosylating agents. We introduce the concept of donor activation temperature to capture experimental insights, reasoning that glycosylations performed below this reference temperature evade deleterious side reactions. Activation temperatures enable a simplified temperature treatment and facilitate optimization of glycosylating agent (building block) usage. Isothermal glycosylation below the activation temperature halved the equivalents of building block required in comparison to the standard ârampâ regime used in solution- and solid-phase oligosaccharide synthesis to-date
Free-surface pressure distributions with minimum wave resistance
The wave resistance of distributions of excess pressure over a rectangular region on the surface of a steady stream is minimised by choice of spatial variation in pressure. Both unconstrained and constrained (non-negative) pressures are studied. Results with impressive resistance reductions are provided, both via discretisation to a large number of step pressures, and via optimisation within a low-order continuous family
Steady two dimensional free-surface flow over semi-infinite and finite-length corrugations in an open channel
Free-surface flow past a semi-infinite or a finite length corrugation in an otherwise flat and horizontal open channel is considered. Numerical solutions for the steady flow problem are computed using both a weakly nonlinear and fully nonlinear model. The new solutions are classified in terms of a depth-based Froude number and the four classical flow types (supercritical, subcritical, generalised hydraulic rise and hydraulic rise) for flow over a small bump. While there is no hydraulic fall solution for semi-infinite topography, we provide strong numerical evidence that such a solution does exist in the case of a finite length corrugation. Numerical solutions are also found for the other flow types for either semi-infinite or finite length corrugation. For subcritical flow over a semi-infinite corrugation, the free-surface profile is found to be quasiperiodic in nature. A discussion of the new results is made with reference to the classical problem of flow over a bump
Conformal Mapping on Rough Boundaries II: Applications to bi-harmonic problems
We use a conformal mapping method introduced in a companion paper to study
the properties of bi-harmonic fields in the vicinity of rough boundaries. We
focus our analysis on two different situations where such bi-harmonic problems
are encountered: a Stokes flow near a rough wall and the stress distribution on
the rough interface of a material in uni-axial tension. We perform a complete
numerical solution of these two-dimensional problems for any univalued rough
surfaces. We present results for sinusoidal and self-affine surface whose slope
can locally reach 2.5. Beyond the numerical solution we present perturbative
solutions of these problems. We show in particular that at first order in
roughness amplitude, the surface stress of a material in uni-axial tension can
be directly obtained from the Hilbert transform of the local slope. In case of
self-affine surfaces, we show that the stress distribution presents, for large
stresses, a power law tail whose exponent continuously depends on the roughness
amplitude
Structural relaxation in a system of dumbbell molecules
The interaction-site-density-fluctuation correlators, the dipole-relaxation
functions, and the mean-squared displacements of a system of symmetric
dumbbells of fused hard spheres are calculated for two representative
elongations of the molecules within the mode-coupling theory for the evolution
of glassy dynamics. For large elongations, universal relaxation laws for states
near the glass transition are valid for parameters and time intervals similar
to the ones found for the hard-sphere system. Rotation-translation coupling
leads to an enlarged crossover interval for the mean-squared displacement of
the constituent atoms between the end of the von Schweidler regime and the
beginning of the diffusion process. For small elongations, the superposition
principle for the reorientational -process is violated for parameters
and time intervals of interest for data analysis, and there is a strong
breaking of the coupling of the -relaxation scale for the diffusion
process with that for representative density fluctuations and for dipole
reorientations.Comment: 15 pages, 14 figures, Phys. Rev. E in pres
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